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    • 2. 发明授权
    • Laminated multilayer structure
    • 层压多层结构
    • US4397916A
    • 1983-08-09
    • US237610
    • 1981-02-24
    • Riichiro Nagano
    • Riichiro Nagano
    • B32B27/32C08L23/04C08L51/06B32B15/08
    • C08L51/06B32B27/32C08L23/0815C08L2203/10Y10S428/91Y10T428/1352Y10T428/1355Y10T428/31692Y10T428/31696Y10T428/31743Y10T428/31746Y10T428/31757Y10T428/31797Y10T428/31913Y10T428/31928
    • In a laminated multilayer structure composed of (A) a layer of a graft-modified ethylene resin grafted with an unsaturated carboxylic acid or a functional derivative thereof and (B) an oxygen- or nitrogen-containing polar resin layer or a metal layer in contact with the layer (A); the improvement wherein (1) the layer (A) consists of (i) 1 to 100% by weight of said graft-modified ethylene resin derived from an ethylene polymer which contains 0 to 15 mole % of at least one alpha-olefin having 3 to 30 carbon atoms as a comonomer and has an MI.sub.2 /[.eta.].sup.-8.77 ratio in absolute value of not less than 15 and a density of 0.88 to 0.98 g/cm.sup.3, and (ii) 99 to 0% by weight of an unmodified ethylene polymer containing 0 to 50 mole % of at least one alpha-olefin having 3 to 30 carbon atoms as a comonomer and having an MI.sub.2 /[.eta.].sup.-8.77 ratio in absolute value of not less than 15 and a density of 0.86 to 0.96 g/cm.sup.3, and (2) the layer (A) has (a) an ethylene content of not less than 80 mole %, (b) a content of the carboxylic acid or the derivative thereof of 0.01 to 10% by weight based on the weight of the layer (A), (c) a density of 0.88 to 0.98 g/cm.sup.3, and (d) an MI.sub.10 /MI.sub.2 ratio of from 5 to 18.
    • 在由(A)接枝有不饱和羧酸或其官能衍生物的接枝改性乙烯树脂层和(B)含氧或含氮极性树脂层或接触金属层的层叠多层结构体 与层(A); 其改进在于(1)层(A)由(i)1至100重量%的衍生自乙烯聚合物的接枝改性乙烯树脂组成,所述乙烯聚合物含有0至15摩尔%的至少一种具有3个 至30个碳原子,MI2 /η-7877的绝对值不小于15,密度为0.88至0.98g / cm3,(ii)99至0重量%的未改性的 含有0〜50摩尔%的至少1种具有3〜30个碳原子的α-烯烃作为共聚单体且MI2 /η-7877的绝对值不小于15且密度为0.86〜0.96的乙烯聚合物 g / cm3,(2)层(A)的(a)乙烯含量为80摩尔%以上,(b)羧酸或其衍生物的含量为0.01〜10重量%,基于 层(A)的重量,(c)密度为0.88〜0.98g / cm 3,(d)MI10 / MI2比为5〜18。
    • 7. 发明授权
    • Production of thermoplastic olefin elastomers
    • 生产热塑性烯烃弹性体
    • US4134927A
    • 1979-01-16
    • US732194
    • 1976-10-14
    • Toru TomoshigeRiichiro NaganoTetsuo Imamura
    • Toru TomoshigeRiichiro NaganoTetsuo Imamura
    • C08L23/00C08F8/00C08F8/46C08F255/00C08F255/02C08F255/04C08K5/09C08L7/00C08L21/00C08L51/00C08L51/02C08L101/00
    • C08F255/02
    • A process for preparing thermoplastic olefin elastomers which comprises mixing and extruding in a screw extruder (A) an olefin rubber having a number average molecular weight of about 10,000 to 100,000 and composed of a copolymer of ethylene with an .alpha.-olefin containing at least 3 carbon atoms and (B) about 1 to 15 parts by weight, per 100 parts by weight of the olefin rubber (A), of a specified dicarboxylic acid monomer at about 200 to 320.degree. C in the presence of (C) 0.02 to 3 milliequivalents, per 100 grams of the olefin rubber (A), of an alkyl peroxide, and in the absence of molecular oxygen. The thermoplastic olefin elastomers have superior mechanical properties, thermal stability, processability and adhesiveness, and find a wide range of applications, for example, as extrusion or injection molding materials, adhesives, coating agents, and modifiers for plastics and rubbers.
    • 一种制备热塑性烯烃弹性体的方法,其包括在螺杆挤出机(A)中混合和挤出数均分子量为约10,000至100,000的烯烃橡胶,并由乙烯与含有至少3个碳的α-烯烃的共聚物组成 原子,(B)在(C)0.02〜3毫当量的存在下,在约200〜320℃下,相对于100重量份的烯烃橡胶(A),(B)约1〜15重量份的特定的二羧酸单体 ,每100克烯烃橡胶(A),烷基过氧化物,和不存在分子氧。 热塑性烯烃弹性体具有优异的机械性能,热稳定性,可加工性和粘合性,并且可用于塑料和橡胶的挤出或注射成型材料,粘合剂,涂层剂和改性剂等广泛应用。