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1. 发明授权

US4962254A Process for preparing alkyl-substituted aromatic hydrocarbons 失效
标题翻译：制备烷基取代芳烃的方法
公开(公告)号：US4962254A
公开(公告)日：1990-10-09
申请号：US391242
申请日：1989-08-09
申请人： Masami Fukao , Takuo Hibi , Kiyoshi Ikimi , Gohfu Suzukamo
发明人： Masami Fukao , Takuo Hibi , Kiyoshi Ikimi , Gohfu Suzukamo
IPC分类号： B01J23/04 , C07C2/72
CPC分类号： B01J23/04 , C07C2/72 , C07C2521/04 , C07C2523/04 , C07C2531/12
摘要： An alkyl-substituted hydrocarbon is prepared by alkylating an alkyl aromatic hydrocarbon having at least one hydrogen atom at an alpha-position in a side chain with an olefin in the presence of a solid base which is obtainable by heating an alumina, an alkali metal hydroxide and an alkali metal hydride or an alumina containing at least 1.3% by weight of water and an alkali metal hydride in an inert gas atmosphere at a temperature of 200.degree. to 800.degree. C. as a catalyst.

2. 发明授权

US5202515A Process for preparing alkyl-substituted aromatic hydrocarbons 失效
标题翻译：制备烷基取代芳烃的方法
公开(公告)号：US5202515A
公开(公告)日：1993-04-13
申请号：US699586
申请日：1991-05-14
申请人： Masami Fukao , Takuo Hibi , Kiyoshi Ikimi , Gohfu Suzukamo
发明人： Masami Fukao , Takuo Hibi , Kiyoshi Ikimi , Gohfu Suzukamo
IPC分类号： B01J23/04 , B01J27/232 , C07C2/72
CPC分类号： B01J27/232 , B01J23/04 , C07C2/72 , C07C2521/02 , C07C2523/04 , C07C2527/232 , C07C2531/12
摘要： An alkyl-substituted hydrocarbon is prepared by alkylating an alkyl aromatic hydrocarbon having at least one hydrogen atom at an alpha-position in a side chain with an olefin in the presence of a solid base which is obtainable by heating and reacting an alumina with at least one carbonate of an alkali metal and at least one material selected from the group consisting of potassium and alkali metal hydrides at a temperature of from 180.degree. to 800.degree. C. in an inert gas atmosphere, as a catalyst.
摘要翻译：烷基取代的烃是通过在固体碱的存在下，通过烷基化在侧链的α位具有至少一个氢原子的烷基芳烃来制备的，所述固体碱可以通过加热和使氧化铝与至少一种在惰性气体气氛中，在180℃至800℃的温度下，碱金属的碳酸盐和选自钾和碱金属氢化物的至少一种材料作为催化剂。

3. 发明授权

US5118895A Process for preparing alkyl-substituted aromatic hydrocarbon 失效
标题翻译：制备烷基取代芳香烃的方法
公开(公告)号：US5118895A
公开(公告)日：1992-06-02
申请号：US668787
申请日：1991-03-13
申请人： Takuo Hibi , Masami Fukao , Kiyoshi Ikimi , Gohfu Suzukamo
发明人： Takuo Hibi , Masami Fukao , Kiyoshi Ikimi , Gohfu Suzukamo
IPC分类号： B01J23/04 , C07B61/00 , C07C2/72 , C07C15/00
CPC分类号： C07C2/72 , C07C2523/02 , C07C2523/04 , C07C2531/12
摘要： An alkyl-substituted hydrocarbon is prepared effectively under mild conditions by alkylating an alkyl aromatic hydrocarbon having at least one hydrogen atom at an alpha-position in a side chain with an olefin in the presence of a solid base which is obtainable by treating a water-containing oxide of an alkaline earth metal with at least one material selected from the group consisting of alkali metals and alkali metal hydrides in an amount of 0.5 to 3.5 equivalents per one mole of water in said oxide in an inert gas atmosphere.
摘要翻译：在温和条件下通过在固体碱的存在下，通过烷基化在侧链的α位具有至少一个氢原子的烷基芳族烃与烯烃进行烷基取代的烃的制备，含有碱金属和碱金属氢化物的碱金属和碱金属氢化物中的至少一种材料的碱土金属的氧化物，其量为所述氧化物中惰性气体气氛中每1摩尔水的0.5-3.5当量。

4. 发明授权

US5043507A Process for preparing alkyl-substituted aromatic hydrocarbons 失效
标题翻译：制备烷基取代芳烃的方法
公开(公告)号：US5043507A
公开(公告)日：1991-08-27
申请号：US399974
申请日：1989-08-29
申请人： Masami Fukao , Takuo Hibi , Kiyoshi Ikimi , Gohfu Suzukamo
发明人： Masami Fukao , Takuo Hibi , Kiyoshi Ikimi , Gohfu Suzukamo
IPC分类号： B01J23/04 , B01J27/232 , C07C2/72
CPC分类号： B01J27/232 , B01J23/04 , C07C2/72 , C07C2521/02 , C07C2523/04 , C07C2527/232 , C07C2531/12
摘要： An alkyl-substituted hydrocarbon is prepared by alkylating an alkyl aromatic hydrocarbon having at least one hydrogen atom at an alpha-position in a side chain with an olefin in the presence of a solid base which is obtainable by reacting an alumina with an alkali metal carbonate and/or aluminate and an alkali metal amd/or its hydride in an inert gas atmosphere at a temperature of 180.degree. to 800.degree. C. as a catalyst.

5. 发明授权

US5097088A Process for preparing alkyl-substituted aromatic hydrocarbon 失效
标题翻译：制备烷基取代芳香烃的方法
公开(公告)号：US5097088A
公开(公告)日：1992-03-17
申请号：US586074
申请日：1990-09-21
申请人： Masami Fukao , Takuo Hibi , Kiyoshi Ikimi , Gohfu Suzukamo
发明人： Masami Fukao , Takuo Hibi , Kiyoshi Ikimi , Gohfu Suzukamo
IPC分类号： B01J23/04 , B01J31/12 , C07B61/00 , C07C2/72 , C07C15/00
CPC分类号： B01J23/04 , C07C2/72 , C07C2521/04 , C07C2523/04 , C07C2531/12
摘要： An alkyl-substituted hydrocarbon is prepared by alkylating an alkylaromatic hydrocarbon having at least one hydrogen atom on an alpha-carbon in a side chain with an olefin in the presence of a solid base which is obtainable by treating an alumina with at least one compound of an alkaline earth metal at a temperature of from 200.degree. to 800.degree. C. and then with at least one compound selected from the group consisting of an alkali metal and an alkali metal hydride in an inert gas at a temperature of from 200.degree. to 800.degree. C.

6. 发明授权

US4312717A Process for producing 2-(2'-methyl-1'-propenyl)-4-methyltetrahydropyran 失效
标题翻译： 2-（2'-甲基-1'-丙烯基）-4-甲基四氢吡喃的制备方法
公开(公告)号：US4312717A
公开(公告)日：1982-01-26
申请号：US158810
申请日：1980-06-12
申请人： Gohu Suzukamo , Tetsuo Takano , Mitsuhisa Tamura , Kiyoshi Ikimi
发明人： Gohu Suzukamo , Tetsuo Takano , Mitsuhisa Tamura , Kiyoshi Ikimi
IPC分类号： C07C29/00 , C07C43/178 , C07D309/04 , C25B3/02
CPC分类号： C25B3/02 , C07C29/00 , C07C43/178 , C07D309/04
摘要： Rose oxide, which is an important olfactive compound valuable in the art of perfumery, is advantageously produced from citronellol through a novel synthetic route comprising(1) anodic alkoxylation of citronellol using as a supporting electrolyte an alkali metal aromatic sulfonate,(2) dealkoxylation of the resulting 2,6-dimethyl-3-alkoxyoct-1-en-8-ol in the presence of a palladium or nickel complex, and then(3) cyclization of the resulting dehydrocitronellol in the presence of an acid.
摘要翻译：玫瑰氧化物是香料技术中有价值的重要的嗅觉化合物，有利地由香茅醇通过新的合成路线制备，其包括（1）使用碱金属芳族磺酸盐作为支持电解质的香茅醇的阳极烷氧基化，（2）所得的2,6-二甲基-3-烷氧基辛-1-烯-8-醇在钯或镍络合物的存在下，然后（3）在酸的存在下环化所得的脱氢天ron醇。

7. 发明授权

US5600026A Process for production of cresols 失效
标题翻译：甲酚生产工艺
公开(公告)号：US5600026A
公开(公告)日：1997-02-04
申请号：US393031
申请日：1995-02-23
申请人： Kiyoshi Ikimi , Yoichi Ikeda , Akira Murakami , Kazushige Okamoto , Tooru Tokumaru , Motoo Hazama
发明人： Kiyoshi Ikimi , Yoichi Ikeda , Akira Murakami , Kazushige Okamoto , Tooru Tokumaru , Motoo Hazama
IPC分类号： C07C39/07 , C07C409/08 , C07C37/08 , C07C37/06 , C07C37/68
CPC分类号： C07C39/07 , C07C407/00 , C07C409/08
摘要： There is disclosed a process for the production of cresols, including the steps of: (a) conducting oxygenation of cymene with oxygen gas or an oxygen-containing gas, thereby obtaining a solution of oxygenation products containing tertiary and primary hydroperoxides of cymene; (b) reacting the solution of oxygenation products obtained in the step (a) with an organic quaternary ammonium salt and an alkali, or with an organic quaternary ammonium hydroxide, thereby decreasing the content of primary hydroperoxide; (c) subjecting the reaction mixture in the step (b) to decomposition in the presence of a catalyst; and (d) subjecting the decomposition mixture in the step (c) to hydrogenation, thereby obtaining the desired cresols.
摘要翻译：公开了一种生产甲酚的方法，包括以下步骤：（a）用氧气或含氧气体进行甲基异丙基苯的氧化反应，从而得到含有甲基异丙苯的叔级和过氧化氢过氧化氢的氧化产物溶液; （b）使步骤（a）中得到的氧合产物的溶液与有机季铵盐和碱或与有机季铵氢氧化物反应，从而降低初级氢过氧化物的含量; （c）使步骤（b）中的反应混合物在催化剂存在下分解; 和（d）使步骤（c）中的分解混合物进行氢化，从而得到所需的甲酚。

8. 发明授权

US4709112A Process for dimerizing lower .alpha.-olefins 失效
标题翻译：二聚低级α-烯烃的方法
公开(公告)号：US4709112A
公开(公告)日：1987-11-24
申请号：US947873
申请日：1986-12-30
申请人： Hiroshi Sato , Kiyoshi Ikimi , Hideto Tojima , Mikoto Takahashi
发明人： Hiroshi Sato , Kiyoshi Ikimi , Hideto Tojima , Mikoto Takahashi
IPC分类号： B01J31/02 , B01J31/04 , B01J31/14 , B01J31/18 , B01J31/24 , C07C2/30 , C07C2/32 , C07C2/36 , C07C2/24
CPC分类号： C07C2/36 , B01J31/0211 , B01J31/0231 , B01J31/0264 , B01J31/04 , B01J31/143 , B01J31/24 , B01J31/2404 , C07C2/30 , C07C2/32 , B01J2231/20 , B01J2531/847 , B01J2540/22 , B01J31/1845 , C07C2531/02 , C07C2531/04 , C07C2531/14 , C07C2531/22 , C07C2531/24
摘要： An improved process for dimerizing lower .alpha.-olefins using a novel nickel-containing Ziegler catalyst system including(A) an organic acid salt or complex of nickel,(B) a trialkylaluminum,(C) a trivalent phosphorus compound of the formula:PR.sup.1 R.sup.2 R.sup.3 (I)P(NR.sup.1.sub.2).sub.3 (II)P(OR.sup.1).sub.3 (III) wherein R.sup.1, R.sup.2, R.sup.3 are alkyl, cycloalkyl, aryl or aralkyl,(D) a fluorinated isopropanol of the formula: ##STR1## wherein m and n are in 4.ltoreq.m+n.ltoreq.6, and optionally (E) a catalyst co-activator: halogenated compounds of the formulae: ##STR2## wherein X is halogen, R.sup.4, R.sup.5, R.sup.6 are alkyl, and n is 1 to 3, and further optionally,(F) a compound selected from aliphatic alcohol and aliphatic carboxylic acid or ester thereof,which yields the dimers with high selectivity of isomers and uniformity of the catalyst without corrosion of the apparatus.
摘要翻译：一种使用新型含镍齐格勒催化剂体系二聚化低级α-烯烃的改进方法，包括（A）有机酸盐或镍络合物，（B）三烷基铝，（C）下式的三价磷化合物：PR1R2R3（ I）P（NR 12）3（II）P（OR 1）3（III）其中R 1，R 2，R 3是烷基，环烷基，芳基或芳烷基，（D）下式的氟化异丙醇：其中 m和n分别为4≤m+n≤6，和任选地（E）催化剂助活化剂：下式的卤化化合物：其中X是卤素，（V）和R4R5R6CX（VI） R4，R5，R6是烷基，n是1至3，进一步任选地，（F）选自脂族醇和脂肪族羧酸或其酯的化合物，其以异构体的高选择性和催化剂的均匀性产生二聚体没有设备的腐蚀。

9. 发明授权

US6120653A Separation and purification method of t-butyl-methylphenol isomer 失效
标题翻译：叔丁基甲基苯酚异构体的分离纯化方法
公开(公告)号：US6120653A
公开(公告)日：2000-09-19
申请号：US76806
申请日：1998-05-13
申请人： Kiyoshi Ikimi , Susumu Tsukada , Masaaki Toma
发明人： Kiyoshi Ikimi , Susumu Tsukada , Masaaki Toma
IPC分类号： C07C37/74 , C07C39/06 , B01D3/00 , C07C27/28
CPC分类号： C07C37/74 , C07C37/685
摘要： A method is provided for industrially advantageously and effectively separating 4M2B and 3M6B from a t-butylcresol mixture containing 2-t-butyl-4-methylphenol (4M2B), 2-tbutyl-5-methylphenol (3M6B), compounds having a lower boiling point than that of 4M2B and compounds having a higher boiling point than that of 3M6B derived from a m,p-cresol mixture.
摘要翻译：提供了一种工业上有利和有效地从含有2-叔丁基-4-甲基苯酚（4M2B），2-叔丁基-5-甲基苯酚（3M6B），具有较低沸点的化合物的叔丁基甲酚混合物中分离4M2B和3M6B的方法比具有比来自对甲酚混合物的3M6B沸点高的沸点的4M2B和化合物。

10. 发明授权

US5399791A Process for production of cresols 失效
标题翻译：甲酚生产工艺
公开(公告)号：US5399791A
公开(公告)日：1995-03-21
申请号：US202160
申请日：1994-02-25
申请人： Kiyoshi Ikimi , Yoichi Ikeda , Akira Murakami , Kazushige Okamoto , Tooru Tokumaru , Motoo Hazama
发明人： Kiyoshi Ikimi , Yoichi Ikeda , Akira Murakami , Kazushige Okamoto , Tooru Tokumaru , Motoo Hazama
IPC分类号： C07C39/07 , C07C37/08 , C07C37/06
CPC分类号： C07C39/07
摘要： There is disclosed a process for the production of cresols, including the steps of: (a) conducting oxygenation of cymene with oxygen gas or an oxygen-containing gas without any addition of an alkali, thereby obtaining a solution of oxygenation products containing tertiary and primary hydroperoxides of cymene; (b) washing the solution of oxygenation products obtained in step (a) with an aqueous alkali solution at a temperature in the range of from 10.degree. to 95.degree. C.; (c) subjecting the solution of oxygenation products obtained in step (b) to hydrogenation at a temperature in the range of from 60.degree. to 100.degree. C. to decrease the content of primary hydroperoxide in such a manner that the weight ratio of primary hydroperoxide to tertiary hydroperoxide is not greater than 1/25 (w/w); (d) subjecting the solution treated in step (c) to decomposition in the presence of a catalyst; and (e) subjecting the solution treated in step (d) to hydrogenation to obtain cresols.
摘要翻译：公开了一种生产甲酚的方法，包括以下步骤：（a）在不加碱的条件下，用氧气或含氧气体进行甲基异丙基苯的氧化反应，从而得到含有叔，伞形氢过氧化物; （b）在10℃至95℃的温度范围内用碱水溶液洗涤步骤（a）中获得的氧合产物的溶液; （c）将步骤（b）中获得的氧合产物溶液在60℃至100℃的温度范围内进行氢化，以降低初级氢过氧化物的含量，使得初级氢过氧化物的重量比叔氢过氧化物不大于1/25（w / w）; （d）使在步骤（c）中处理的溶液在催化剂存在下进行分解; 和（e）使步骤（d）中处理的溶液进行氢化以获得甲酚。

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