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1. 发明授权

US07098263B2 Thermoplastic resin composition, molded article, and process for producing the same 失效
标题翻译：热塑性树脂组合物，成型体及其制造方法
公开(公告)号：US07098263B2
公开(公告)日：2006-08-29
申请号：US10381103
申请日：2002-07-19
申请人： Masaki Mitsunaga , Katsuhiko Hironaka , Masami Okamoto
发明人： Masaki Mitsunaga , Katsuhiko Hironaka , Masami Okamoto
IPC分类号： C08K3/34
CPC分类号： C08L69/00 , C08K3/34 , C08K5/19 , C08K5/50 , C08K5/541 , C08K9/04 , C08K9/06 , C08L25/08 , C08L67/025 , C08L101/08 , C08L2666/18 , C08L2666/06 , C08L2666/02
摘要： A thermoplastic resin composition comprising: (A) 100 parts by weight of a noncrystalline thermoplastic resin component (component A); (B) 0.1 to 50 parts by weight of a layered silicate (component B) which satisfies the following (i) to (iii): (i) it has a cation exchange capacity of 50 to 200 milliequivalents/100 g, and at least 40% of the cation exchange capacity being exchanged with an organic onium ion, (ii) 60% or more of the layered silicate particles have a thickness of 100 nm or less in the resin composition, and (iii) the interlayer spacing of the layered silicate (component B) in the resin composition is smaller than the interlayer spacing of the layered silicate alone by 0.5 nm or more; and (C) 0 to 50 parts by weight of a compound (component C) having affinity for the noncrystalline thermoplastic resin component as the component A and a hydrophilic component; and molded articles thereof. According to the present invention, a noncrystalline thermoplastic resin composition having excellent stiffness, surface appearance and heat stability, especially a polycarbonate resin composition and molded articles thereof are obtained.
摘要翻译：一种热塑性树脂组合物，其包含：（A）100重量份的非结晶性热塑性树脂组分（组分A）; （B）0.1〜50重量份满足以下（i）〜（iii）的层状硅酸盐（B成分）：（i）阳离子交换容量为50〜200毫当量/ 100g，至少阳离子交换容量的40％与有机鎓离子交换，（ii）60％以上的层状硅酸盐颗粒在树脂组合物中的厚度为100nm以下，（iii）层状间隔树脂组合物中的硅酸盐（组分B）小于层状硅酸盐的层间距离为0.5nm以上; 和（C）0〜50重量份对作为组分A的非结晶性热塑性树脂组分具有亲和性的化合物（组分C）和亲水性组分; 及其成型品。根据本发明，获得具有优异的刚度，表面外观和热稳定性的非结晶性热塑性树脂组合物，特别是聚碳酸酯树脂组合物及其模塑制品。

2. 发明授权

US07189796B2 Aromatic polycarbonate resin composition 失效
标题翻译：芳香族聚碳酸酯树脂组合物
公开(公告)号：US07189796B2
公开(公告)日：2007-03-13
申请号：US10531914
申请日：2003-10-29
申请人： Masaki Mitsunaga , Katsuhiko Hironaka
发明人： Masaki Mitsunaga , Katsuhiko Hironaka
IPC分类号： C08G64/00
CPC分类号： C08K5/521 , C08K9/04 , C08L69/00
摘要： An object of the present invention is to provide an aromatic polycarbonate resin composition having good rigidity and good hydrolysis resistance.The present invention is an aromatic polycarbonate resin composition comprising: (A) 100 parts by weight of aromatic polycarbonate (component A) (B) 0.1 to 20 parts by weight of layer silicate (component B) having 50 to 200 milliequivalents/100 g of cation exchange capacity and ion-exchanged by an organic onium ion represented by the following general formula (I): (wherein M represents a nitrogen atom or a phosphorus atom, R1 and R2 represent an alkyl group having 6 to 16 carbon atoms and may be the same as or different from each other, and R3 and R4 represent an alkyl group having 1 to 4 carbon atoms and may be the same as or different from each other), (C) 0.1 to 50 parts by weight of compound (component C) having an affinity for the component A and having a hydrophilic component, and (D) 0.005 to 1 part by weight of ester (component D) of a higher fatty acid and a polyhydric alcohol.
摘要翻译：本发明的目的是提供一种刚性好，耐水解性好的芳香族聚碳酸酯树脂组合物。本发明是一种芳族聚碳酸酯树脂组合物，其包含：（A）100重量份芳族聚碳酸酯（组分A）（B）0.1至20重量份具有50至200毫当量的层状硅酸盐（组分B）/ 100g 阳离子交换容量，并由以下通式（I）表示的有机鎓离子离子交换：（其中M表示氮原子或磷原子，R 1和R 2，表示具有6〜16个碳原子的烷基，可以相同或不同，R 3和R 4表示具有 1〜4个碳原子，可以相同或不同），（C）0.1〜50重量份对组分A具有亲和性且具有亲水性成分的化合物（C成分），（D） 0.005〜1重量份的高级脂肪酸和多元醇的酯（组分D）。

3. 发明申请

US20070155888A1 Aromatic polycarbonate resin composition and process for the production thereof 审中-公开
标题翻译：芳香族聚碳酸酯树脂组合物及其制造方法
公开(公告)号：US20070155888A1
公开(公告)日：2007-07-05
申请号：US10590722
申请日：2005-02-23
申请人： Koichi Imamura , Masaki Mitsunaga , Kunio Hatanaka , Katsuhiko Hironaka
发明人： Koichi Imamura , Masaki Mitsunaga , Kunio Hatanaka , Katsuhiko Hironaka
IPC分类号： C08K3/34
CPC分类号： C08K3/34 , C08G64/20 , C08K9/04 , C08L69/00
摘要： This invention aims at providing an aromatic polycarbonate resin composition having high elasticity with a small content of an inorganic filler and a process for the production thereof, and provides a process for the production of a resin composition comprising 100 parts by weight of an aromatic polycarbonate (Component A) and 0.01 to 50 parts by weight of a silicate filler (Component B), (I) Component B being a silicate filler prepared by introducing at least one compound (Component B-1) selected from (i) an organosilicon compound (Component B-1-i) containing a hydrolyzable group and/or a hydroxyl group bonded to a silicon atom and (ii) an organic titanate compound (Component B-1-ii) into a lamellar silicate (Component B-2) having an cation exchange capacity of 50 to 200 milliequivalents/100 g, (II) the process comprising causing a polymer precursor of Component A to undergo interfacial polycondensation reaction in the presence of Component B and in the substantial absence of a polymerization catalyst, and the resin composition.
摘要翻译：本发明的目的在于提供一种具有高弹性且无机填料含量少的芳香族聚碳酸酯树脂组合物及其制备方法，提供一种制备包含100重量份芳族聚碳酸酯（组分A）和0.01至50重量份硅酸盐填料（组分B），（I）组分B是硅酸盐填料，其通过引入至少一种选自（i）有机硅化合物（I）的化合物（组分B-1）成分B-1-i）和（ⅱ）有机钛酸酯化合物（B-1-ⅱ）成分为具有硅原子的层状硅酸酯（B-2）阳离子交换容量为50至200毫当量/ 100g，（II）该方法包括使组分A的聚合物前体在组分B存在下进行界面缩聚反应，并且基本上不存在聚合物硫化催化剂和树脂组合物。

4. 发明申请

US20050272903A1 Aromatic polycarbonate resin composition 失效
标题翻译：芳香族聚碳酸酯树脂组合物
公开(公告)号：US20050272903A1
公开(公告)日：2005-12-08
申请号：US10531914
申请日：2003-10-29
申请人： Masaki Mitsunaga , Katsuhiko Hironaka
发明人： Masaki Mitsunaga , Katsuhiko Hironaka
IPC分类号： C08K5/521 , C08K9/04 , C08G64/00
CPC分类号： C08K5/521 , C08K9/04 , C08L69/00
摘要： An object of the present invention is to provide an aromatic polycarbonate resin composition having good rigidity and good hydrolysis resistance. The present invention is an aromatic polycarbonate resin composition comprising: (A) 100 parts by weight of aromatic polycarbonate (component A) (B) 0.1 to 20 parts by weight of layer silicate (component B) having 50 to 200 milliequivalents/100 g of cation exchange capacity and ion-exchanged by an organic onium ion represented by the following general formula (I): (wherein M represents a nitrogen atom or a phosphorus atom, R1 and R2 represent an alkyl group having 6 to 16 carbon atoms and may be the same as or different from each other, and R3 and R4 represent an alkyl group having 1 to 4 carbon atoms and may be the same as or different from each other), (C) 0.1 to 50 parts by weight of compound (component C) having an affinity for the component A and having a hydrophilic component, and (D) 0.005 to 1 part by weight of ester (component D) of a higher fatty acid and a polyhydric alcohol.
摘要翻译：本发明的目的是提供一种刚性好，耐水解性好的芳香族聚碳酸酯树脂组合物。本发明是一种芳族聚碳酸酯树脂组合物，其包含：（A）100重量份芳族聚碳酸酯（组分A）（B）0.1至20重量份具有50至200毫当量的层状硅酸盐（组分B）/ 100g 阳离子交换容量，并由以下通式（I）表示的有机鎓离子离子交换：（其中M表示氮原子或磷原子，R 1和R 2，表示具有6〜16个碳原子的烷基，可以相同或不同，R 3和R 4表示具有 1〜4个碳原子，可以相同或不同），（C）0.1〜50重量份对组分A具有亲和性且具有亲水性成分的化合物（C成分），（D） 0.005〜1重量份的高级脂肪酸和多元醇的酯（组分D）。

5. 发明申请

US20100184884A1 FLAME-RETARDANT POLYCARBONATE RESIN COMPOSITION 有权
标题翻译：阻燃聚碳酸酯树脂组合物
公开(公告)号：US20100184884A1
公开(公告)日：2010-07-22
申请号：US12602571
申请日：2008-05-28
申请人： Toshiyuki Miyake , Masami Kinoshita , Mizuho Saito , Katsuhiko Hironaka
发明人： Toshiyuki Miyake , Masami Kinoshita , Mizuho Saito , Katsuhiko Hironaka
IPC分类号： C08K3/32 , C08K5/51 , C08K5/49
CPC分类号： C08K5/5313 , C08G64/0208 , C08G64/0216 , C08G64/186 , C08L69/00 , C08L2666/04
摘要： There is provided a resin composition that comprises a polycarbonate resin derived from an ether diol such as isosorbide and that is excellent in flame retardancy, heat resistance, thermal stability, rigidity, transparency and moldability.The resin composition is a flame-retardant resin composition comprising 1 to 60 parts by weight of phosphorus compound (component B) having a thermal decomposition temperature of not higher than 340° C. based on 100 parts by weight of polycarbonate resin (component A) that mainly comprises a recurring unit represented by the following formula (1).
摘要翻译：提供一种树脂组合物，其包含衍生自醚二醇的聚碳酸酯树脂，例如异山梨醇，并且其阻燃性，耐热性，热稳定性，刚性，透明性和成型性优异。该树脂组合物是含有1〜60重量份的基于100重量份聚碳酸酯树脂（A成分）的热分解温度不高于340℃的磷化合物（B成分）的阻燃性树脂组合物，其主要包括由下式（1）表示的重复单元。

6. 发明授权

US06248814B1 Resin composition 失效
标题翻译：树脂组成
公开(公告)号：US06248814B1
公开(公告)日：2001-06-19
申请号：US09424678
申请日：1999-11-24
申请人： Katsuhiko Hironaka , Mioko Suzuki
发明人： Katsuhiko Hironaka , Mioko Suzuki
IPC分类号： C08K322
CPC分类号： C08K3/38 , C08K3/01 , C08K3/02 , C08K3/22 , C08K3/24 , C08K3/32 , C08K5/49 , C08K2003/026 , C08K2003/2296 , C08K2003/387 , C08L67/02
摘要： An aromatic polyester resin composition excellent in heat resistance, mechanical characteristics, flame retardant property and electric insulation property, and mainly used in electric/electronic uses is obtained by a resin composition comprising (A) an aromatic polyester of 100 parts weight, (B) red phosphorus and/or organic phosphorus compound of 1 to 20 parts weight based on phosphorus atom content and (C) at least one kind selected from a group consisting of zinc borate, zinc stannate and zinc oxide of 2 to 50 parts weight.
摘要翻译：主要用于电气/电子用途的耐热性，机械特性，阻燃性和电绝缘性优异的芳族聚酯树脂组合物通过包含（A）100重量份的芳族聚酯，（B）红磷和/或有机磷化合物，以磷原子计含量为1〜20重量份，（C）选自硼酸锌，锡酸锌和氧化锌中的至少一种为2〜50重量份。

7. 发明授权

US08034894B2 Terminal modified polycarbonate and manufacturing process thereof 有权
标题翻译：端改性聚碳酸酯及其制造方法
公开(公告)号：US08034894B2
公开(公告)日：2011-10-11
申请号：US12530437
申请日：2008-03-05
申请人： Toshiyuki Miyake , Masami Kinoshita , Mizuho Saito , Katsuhiko Hironaka
发明人： Toshiyuki Miyake , Masami Kinoshita , Mizuho Saito , Katsuhiko Hironaka
IPC分类号： C08G64/02
CPC分类号： C08G64/0216
摘要： A terminal modified polycarbonate having a high content of biogenic matter, excellent heat resistance, heat stability, moldability and moist absorption resistance and high surface energy and a manufacturing process thereof are provided. The terminal modified polycarbonate has a main chain essentially composed of a recurring unit represented by the following formula (1): has a specific viscosity at 20° C. of a solution obtained by dissolving 0.7 g of the polycarbonate in 100 ml of methylene chloride of 0.2 to 0.5, and contains a terminal group represented by the following formula (2) or (3) in an amount of 0.3 to 9 wt % based on the main chain:
摘要翻译：提供具有高生物量含量，优异的耐热性，热稳定性，成型性和耐潮湿吸收性以及高表面能的末端改性聚碳酸酯及其制造方法。末端改性聚碳酸酯具有基本上由下述式（1）表示的重复单元构成的主链：在20℃下具有通过将0.7g聚碳酸酯溶解在100ml二氯甲烷中得到的溶液的比粘度 0.2〜0.5，并且含有由下式（2）或（3）表示的末端基团：相对于主链为0.3〜9重量％

8. 发明申请

US20100160563A1 POLYCARBONATE RESIN COMPOSITION 有权
标题翻译：聚碳酸酯树脂组合物
公开(公告)号：US20100160563A1
公开(公告)日：2010-06-24
申请号：US12600909
申请日：2008-05-16
申请人： Toshiyuki Miyake , Masami Kinoshita , Mizuho Saito , Katsuhiko Hironaka
发明人： Toshiyuki Miyake , Masami Kinoshita , Mizuho Saito , Katsuhiko Hironaka
IPC分类号： C08L69/00 , C08L9/06 , C08L9/02
CPC分类号： C08L69/00 , C08G64/0208 , C08L21/00 , C08L25/10 , C08L51/04 , C08L55/02 , C08L2666/08 , C08L2666/04 , C08L2666/24
摘要： A resin composition comprising a polycarbonate resin derived from an ether diol residue such as isosorbide and has excellent impact resistance, heat resistance, heat stability and moldability.The resin composition comprises a rubber polymer (component B) in an amount of 1 to 30 parts by weight based on 100 parts by weight of a polycarbonate resin (component A) which contains a recurring unit represented by the following formula (1) as the main constituent and has a glass transition temperature (Tg) of 145 to 165° C. and a 5% weight loss temperature (Td) of 320 to 400° C.
摘要翻译：一种树脂组合物，其含有衍生自醚二醇残基如异山梨醇的聚碳酸酯树脂，并且具有优异的耐冲击性，耐热性，热稳定性和成型性。树脂组合物包含相对于100重量份的含有下述式（1）表示的重复单元的聚碳酸酯树脂（A成分）为1〜30重量份的橡胶聚合物（B成分），作为主要成分，玻璃化转变温度（Tg）为145〜165℃，5％重量损失温度（Td）为320〜400℃。

9. 发明授权

US5104943A Resin composition 失效
公开(公告)号：US5104943A
公开(公告)日：1992-04-14
申请号：US359472
申请日：1989-05-23
申请人： Katsuhiko Hironaka , Hiroo Inata , Shunichi Matsumura
发明人： Katsuhiko Hironaka , Hiroo Inata , Shunichi Matsumura
IPC分类号： C08L77/00 , C08L77/06 , C08L79/08
CPC分类号： C08L77/00 , C08L79/08
摘要： The invention relates to a resin composition comprising 100 parts by weight polyamide 4.6 resin and 2 to 200 parts by weight of a polyamide amide resin.The composition has improved HDT in wet state and improved impact resistance in dry state.

10. 发明授权

US4908407A Resin compositions 失效
标题翻译：树脂组合物
公开(公告)号：US4908407A
公开(公告)日：1990-03-13
申请号：US311371
申请日：1989-02-14
申请人： Yoshinari Ogawa , Seiichi Yamashiro , Katsuhiko Hironaka
发明人： Yoshinari Ogawa , Seiichi Yamashiro , Katsuhiko Hironaka
IPC分类号： C08K5/14 , C08L77/00
CPC分类号： C08K5/14 , C08L77/00
摘要： A resin composition comprising a nylon-4,6 resin, an epoxy compound having two epoxy groups and at least one polymer selected from halogenated polystyrenes and halogenated poly-alpha-methylstyrenes, represented by the following general formula (I) ##STR1## (wherein R is a hydrogen atom or a methyl group; X is a bromine or chlorine atom; p is an integer of 1 to 5; and n is an integer of 2 or more).

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