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1. 发明申请

US20080300349A1 Flame-Retardant Polyester and Process for Producing the Same 审中-公开
标题翻译：阻燃聚酯及其制备方法
公开(公告)号：US20080300349A1
公开(公告)日：2008-12-04
申请号：US11720157
申请日：2005-11-22
申请人： Masaki Fuchikami , Shoji Koketsu , Tetsumori Atsuchi , Maki Sato
发明人： Masaki Fuchikami , Shoji Koketsu , Tetsumori Atsuchi , Maki Sato
IPC分类号： C08K5/5313
CPC分类号： C08G63/863 , C08G63/6926 , C08K5/5313 , C08L67/02
摘要： To easily obtain a polyester having excellent mechanical properties, a satisfactory hue, and a high degree of flame retardancy. [MEANS FOR SOLVING PROBLEMS] The flame-retardant polyester is a polyester comprising ethylene terephthalate units as the main structural units and a phosphorus compound copolymerized or incorporated therein or is a resin composition comprising polyesters including that polyester. The flame-retardant polyester is characterized in that a polycarboxylic acid and/or polyol having three or more functional groups capable of forming an ester bond is contained in the polyester in a total amount of 0.05-2.00 mol (per 200 mol of the sum of the dicarboxylic acid ingredient and the diol ingredient), that a specific phosphorus compound having a functional group capable of forming an ester bond is contained in the polyester in an amount of 5,000-50,000 ppm of the polyester in terms of phosphorus amount, and that the polyester pellet obtained has a b value of −5 to 20, an L value of 35 or larger, and a melt viscosity at 280° C. of 1,000-20,000 dPa·s.
摘要翻译：为了容易地获得具有优异的机械性能，令人满意的色调和高阻燃性的聚酯。作为解决问题的手段阻燃性聚酯是以对苯二甲酸乙二醇酯单元作为主要结构单元的聚酯和共聚或并入其中的磷化合物，或包含该聚酯的聚酯的树脂组合物。阻燃聚酯的特征在于，聚酯中含有三个或更多个能形成酯键的官能团的多元羧酸和/或多元醇，其总量为0.05-2.00mol（相对于二羧酸成分和二醇成分），聚酯中含有能够形成酯键的官能团的特定磷化合物以磷量计为5,000〜5000ppm的聚酯，获得的聚酯粒料的ab值为-5〜20，L值为35以上，280℃下的熔融粘度为1000〜20,000dPa.s。

2. 发明申请

US20070106055A1 Polyester polymerization catalyst, polyester produced therewith and process for producing the polyester 审中-公开
标题翻译：聚酯聚合催化剂，由其制造的聚酯和聚酯的制造方法
公开(公告)号：US20070106055A1
公开(公告)日：2007-05-10
申请号：US10588652
申请日：2005-02-08
申请人： Katsuhiko Kageyama , Kenichi Funaki , Masaki Fuchikami , Satoru Nakagawa , Kazuo Katayose , Takahiro Nakajima , Naoki Watanabe , Fumikazu Yoshida , Tetsumori Atsuchi , Shoichi Gyobu , Haruo Matsumoto , Ryuichi Murashige , Gaku Maruyama , Yoshiko Akitomo , Hideki Shimizu
发明人： Katsuhiko Kageyama , Kenichi Funaki , Masaki Fuchikami , Satoru Nakagawa , Kazuo Katayose , Takahiro Nakajima , Naoki Watanabe , Fumikazu Yoshida , Tetsumori Atsuchi , Shoichi Gyobu , Haruo Matsumoto , Ryuichi Murashige , Gaku Maruyama , Yoshiko Akitomo , Hideki Shimizu
IPC分类号： C08G63/00
CPC分类号： C08G63/84 , C08G63/87
摘要： The invention provides a polyester produced in the presence of a polycondensation catalyst comprising at least one compound selected from a group consisting of aluminum compounds and at least one compound selected from a group consisting of phosphorus compounds and being excellent in color tone, thermal stability, and transparency and improved in terms of insoluble particles. Particularly, the invention provides a polyester in which the content of an aluminum containing insoluble particles in the polyester is 3500 ppm or lower and a polyester which has a haze value of 2% or lower when being formed into a monoaxially oriented film. The aluminum catalyst for attaining these characteristics and properties may be polyester polymerization catalyst obtained by mixing an aluminum compound and a phosphorus compound in a solvent and has specified spectral characteristics in the side measurement of 31P-NMR spectrum and 27Al-NMR spectrum.
摘要翻译：本发明提供一种在缩聚催化剂存在下制备的聚酯，其包含至少一种选自铝化合物和至少一种选自磷化合物的化合物并且色调优异，热稳定性和透明度和不溶性颗粒方面的改进。特别地，本发明提供一种聚酯，其中在形成单轴取向膜时，聚酯中含有不溶性的铝的含量为3500ppm以下，聚酯的雾度值为2％以下。用于获得这些特性和性质的铝催化剂可以是通过在溶剂中混合铝化合物和磷化合物而获得的聚酯聚合催化剂，并且在侧谱测定中具有特定的光谱特性， Al-NMR光谱。

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