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1. 发明申请

US20120231334A1 POSITIVE ELECTRODE ACTIVE MATERIAL PARTICLES FOR LITHIUM ION SECONDARY BATTERIES, POSITIVE ELECTRODE USING THE SAME, AND LITHIUM ION SECONDARY BATTERY 有权
标题翻译：用于锂离子二次电池的正极电极活性材料颗粒，使用其的正极和锂离子二次电池
公开(公告)号：US20120231334A1
公开(公告)日：2012-09-13
申请号：US13510876
申请日：2011-08-10
申请人： Masahiro Kinoshita , Kensuke Nakura
发明人： Masahiro Kinoshita , Kensuke Nakura
IPC分类号： H01M10/052 , B05D5/12 , H01M4/64 , H01M4/485 , H01M10/054 , H01M4/131
CPC分类号： H01M4/5825 , B82Y30/00 , C01P2002/72 , C01P2002/88 , C01P2004/62 , C01P2004/64 , C01P2004/84 , C01P2006/40 , H01M4/366
摘要： Positive electrode active material particles for lithium ion secondary batteries include: a core particle including a first olivine-structured, lithium-containing phosphate compound which includes Fe and/or Mn and Li; and a shell layer attached to the surface of the core particle. The shell layer includes a second olivine-structured, lithium-containing phosphate compound which includes Fe and/or Mn and Li. At least the core particle includes a phosphorous compound represented by the formula (1): MemPnOp, where Me is Fe and/or Mn, 0
摘要翻译：用于锂离子二次电池的正极活性物质颗粒包括：包含第一橄榄石结构的含锂磷酸盐化合物的核心颗粒，其包含Fe和/或Mn和Li; 以及附着在芯粒子表面的壳层。壳层包括包含Fe和/或Mn和Li的第二橄榄石结构的含锂磷酸盐化合物。至少核心颗粒包括由式（1）表示的磷化合物：MemPnOp，其中Me是Fe和/或Mn，0

2. 发明授权

US09040199B2 Positive electrode active material particles for lithium ion secondary batteries, positive electrode using the same, and lithium ion secondary battery 有权
标题翻译：锂离子二次电池用正极活性物质粒子，使用其的正极和锂离子二次电池
公开(公告)号：US09040199B2
公开(公告)日：2015-05-26
申请号：US13510876
申请日：2011-08-10
申请人： Masahiro Kinoshita , Kensuke Nakura
发明人： Masahiro Kinoshita , Kensuke Nakura
IPC分类号： H01M4/58 , B82Y30/00 , H01M4/36
CPC分类号： H01M4/5825 , B82Y30/00 , C01P2002/72 , C01P2002/88 , C01P2004/62 , C01P2004/64 , C01P2004/84 , C01P2006/40 , H01M4/366
摘要： Positive electrode active material particles for lithium ion secondary batteries include: a core particle including a first olivine-structured, lithium-containing phosphate compound which includes Fe and/or Mn and Li; and a shell layer attached to the surface of the core particle. The shell layer includes a second olivine-structured, lithium-containing phosphate compound which includes Fe and/or Mn and Li. At least the core particle includes a phosphorous compound represented by the formula (1): MemPnOp, where Me is Fe and/or Mn, 0
摘要翻译：用于锂离子二次电池的正极活性物质颗粒包括：包含第一橄榄石结构的含锂磷酸盐化合物的核心颗粒，其包含Fe和/或Mn和Li; 以及附着在芯粒子表面的壳层。壳层包括包含Fe和/或Mn和Li的第二橄榄石结构的含锂磷酸盐化合物。至少核心颗粒包括由式（1）表示的磷化合物：MemPnOp，其中Me是Fe和/或Mn，0

3. 发明申请

US20120319659A1 SYSTEM AND METHOD FOR CONTROLLING CHARGE/DISCHARGE OF NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY, AND BATTERY PACK 审中-公开
标题翻译：用于控制非水电解质二次电池充电/放电的系统和方法和电池组
公开(公告)号：US20120319659A1
公开(公告)日：2012-12-20
申请号：US13575782
申请日：2011-08-25
申请人： Masahiro Kinoshita , Kensuke Nakura , Takashi Hosokawa
发明人： Masahiro Kinoshita , Kensuke Nakura , Takashi Hosokawa
IPC分类号： H02J7/00
CPC分类号： H01M4/525 , H01M4/485 , H01M4/505 , H01M10/425 , H01M10/44
摘要： A charge/discharge control system for controlling charge/discharge of a non-aqueous electrolyte secondary battery having a positive electrode including a composite oxide containing lithium and nickel. This system includes a charge/discharge circuit for discharging the secondary battery and charging the secondary battery with power from an external power source; and a control unit for controlling the charge/discharge circuit such that the voltage of the secondary battery is within a voltage range having a predetermined end-of-discharge voltage as a lower limit value and a predetermined end-of-charge voltage as an upper limit value. The control unit is configured to change at least the end-of-discharge voltage according to a variable related to deterioration of the secondary battery.
摘要翻译：一种充电/放电控制系统，用于控制具有正极的非水电解质二次电池的充电/放电，所述正极包括含有锂和镍的复合氧化物。该系统包括用于对二次电池放电并从外部电源供电的二次电池充电的放电电路; 以及控制单元，用于控制充电/放电电路，使得二次电池的电压处于具有预定放电后电压作为下限值的电压范围内，并将预定充电电压作为上限极限值。控制单元被配置为根据与二次电池的劣化相关的变量来至少改变放电终止电压。

4. 发明授权

US08399113B2 Nonaqueous electrolyte secondary battery 有权
标题翻译：非水电解质二次电池
公开(公告)号：US08399113B2
公开(公告)日：2013-03-19
申请号：US12596579
申请日：2008-04-10
申请人： Kensuke Nakura , Hajime Nishino , Miyuki Nakai , Mikinari Shimada
发明人： Kensuke Nakura , Hajime Nishino , Miyuki Nakai , Mikinari Shimada
IPC分类号： H01M10/50 , H01M2/00
CPC分类号： H01M10/0525 , H01M2/1673 , H01M2/348 , H01M4/131 , H01M4/485 , H01M4/525 , H01M4/62 , H01M4/66 , H01M4/667 , H01M10/4235 , H01M2004/021 , Y02T10/7011
摘要： An object of the present invention is to provide a high-energy density nonaqueous electrolyte secondary battery that controls the rise in temperature during short circuiting.Used is a nonaqueous electrolyte secondary battery 1, including a battery case 2, and a positive electrode plate 5 having a positive electrode current collector and a positive electrode mixture layer containing a cathode material capable of absorbing and desorbing lithium, a negative electrode plate 6 having a negative electrode current collector and a negative electrode mixture layer containing an anode material capable of absorbing and desorbing lithium, a separator 7 held between the positive and negative electrode plates, and a nonaqueous electrolyte that are enclosed in the battery case, wherein at least one of the positive electrode plate 5 and the negative electrode plate 6 has an electrode plate resistance, as determined in the charged state in the thickness direction when pressurized at 50 kg/cm2, of 0.4 Ω·cm2 or more.
摘要翻译：本发明的目的是提供一种控制短路时的温度上升的高能密度非水电解质二次电池。使用的是具有电池壳体2的非水电解质二次电池1和具有正极集电体的正极板5和含有能够吸收和解吸锂的正极材料的正极合剂层，负极板6具有含有能够吸收和解吸锂的负极材料的负极集电体和负极混合物层，保持在正极板和负极板之间的隔板7和封入电池壳体中的非水电解质，其中至少一个正极板5和负极板6的电极板电阻在50kg / cm 2的加压下，在厚度方向的充电状态下测定为0.4Ω·cm 2·cm 2以上。

5. 发明授权

US08187749B2 Positive electrode for lithium ion secondary battery and lithium ion secondary battery using the same 有权
标题翻译：锂离子二次电池用正极和使用其的锂离子二次电池
公开(公告)号：US08187749B2
公开(公告)日：2012-05-29
申请号：US12052094
申请日：2008-03-20
申请人： Keiichi Takahashi , Kozo Watanabe , Kensuke Nakura
发明人： Keiichi Takahashi , Kozo Watanabe , Kensuke Nakura
IPC分类号： H01M4/58
CPC分类号： H01M4/131 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/621 , H01M10/052 , H01M2004/021 , H01M2004/028
摘要： According to a positive electrode for a lithium ion secondary battery comprising a current collector and a mixture layer containing a transition metal-containing complex oxide as a positive electrode active material formed on the current collector, wherein the mixture layer has surface roughness of 0.1 μm or more and 0.5 μm or less in terms of a Ra value and the mixture layer has a surface treated layer treated with a coupling agent on the surface, it is possible to obtain a positive electrode which is excellent in suppression of moisture absorption. By using the positive electrode, it is possible to obtain a lithium ion secondary battery which is excellent in storage characteristics and causes less battery swelling since the amount of a gas generated upon charging and discharging decreases.
摘要翻译：根据由集电体构成的锂离子二次电池用正极和含有过渡金属的复合氧化物作为集电体上形成的正极活性物质的混合层，其中，所述混合层的表面粗糙度为0.1μm， Ra值为0.5μm以下，混合层在表面具有用偶联剂处理的表面处理层，可以得到抑制吸湿性的正极。通过使用正极，可以获得由于充放电时产生的气体量减少而导致储存特性优异且电池膨胀小的锂离子二次电池。

6. 发明申请

US20090081547A1 LITHIUM ION SECONDARY BATTERY 有权
标题翻译：锂离子二次电池
公开(公告)号：US20090081547A1
公开(公告)日：2009-03-26
申请号：US11915781
申请日：2006-06-26
申请人： Kensuke Nakura
发明人： Kensuke Nakura
IPC分类号： H01M4/54 , H01M4/50 , H01M4/52 , H01M4/48
CPC分类号： H01M10/0525 , H01M4/131 , H01M4/366 , H01M4/485 , H01M4/525 , H01M10/4235 , Y02T10/7011
摘要： The present invention aims to achieve both safety upon shorting by a nail penetration and safety upon overcharging.In a lithium ion secondary battery including a positive electrode, a negative electrode, and a non-aqueous electrolyte, the positive electrode includes active material particles, the active material particles include secondary particles of the lithium composite oxide, and some of the secondary particles have a crack. At least a surface layer portion of the active material particles includes element Me of at least one selected from the group consisting of Mn, Al, Mg, Ca, Zr, B, W, Nb, Ta, In, Mo, and Sn. Element Me is distributed more in the surface layer portion compared with the inner portion of the active material particles.
摘要翻译：本发明的目的在于通过钉子穿透来实现短路的安全性和在过充电时的安全性。在包括正极，负极和非水电解质的锂离子二次电池中，正极包括活性物质粒子，活性物质粒子包括锂复合氧化物的二次粒子，一些二次粒子具有一个裂缝至少活性物质粒子的表层部分包含选自Mn，Al，Mg，Ca，Zr，B，W，Nb，Ta，In，Mo和Sn中的至少一种的元素Me。与活性物质颗粒的内部相比，元素Me更多地分布在表层部分中。

7. 发明申请

US20090035659A1 Non-Aqueous Electrolyte Secondary Battery 有权
标题翻译：非水电解液二次电池
公开(公告)号：US20090035659A1
公开(公告)日：2009-02-05
申请号：US11794579
申请日：2006-04-17
申请人： Takashi Takeuchi , Akihiro Taniguchi , Shuji Tsutsumi , Kensuke Nakura , Hiroshi Matsuno , Hideo Sasaoka , Satoshi Matsumoto
发明人： Takashi Takeuchi , Akihiro Taniguchi , Shuji Tsutsumi , Kensuke Nakura , Hiroshi Matsuno , Hideo Sasaoka , Satoshi Matsumoto
IPC分类号： H01M4/48 , H01M4/02 , H01M10/00 , H01B1/02 , C01G53/00 , H01M4/04
CPC分类号： H01M4/525 , C01G53/42 , C01P2002/52 , C01P2004/51 , C01P2004/61 , C01P2004/62 , C01P2006/11 , C01P2006/12 , C01P2006/40 , H01B1/122 , H01M4/131 , H01M4/485 , H01M4/505 , H01M10/052 , H01M2004/021
摘要： A lithium-containing composite oxide represented by the formula 1: LixNi1-y-z-v-wCoyAlzM1vM2wO2 is used as a positive electrode active material for a non-aqueous electrolyte secondary battery. The element M1 is at least one selected from the group consisting of Mn, Ti, Y, Nb, Mo, and W. The element M2 includes at least two selected from the group consisting of Mg, Ca, Sr, and Ba, and the element M2 includes at least Mg and Ca. The formula 1 satisfies 0.97≦x≦1.1, 0.05≦y≦0.35, 0.005≦z≦0.1, 0.0001≦v≦0.05, and 0.0001≦w≦0.05. The primary particles have a mean particle size of 0.1 μm or more and 3 μm or less, and the secondary particles have a mean particle size of 8 μm or more and 20 μm or less.
摘要翻译：作为非水电解质二次电池用正极活性物质，使用由式1表示的含锂复合氧化物：LixNi1-y-z-v-wCoyAlzM1vM2wO2。元素M1是选自Mn，Ti，Y，Nb，Mo和W中的至少一种元素。元素M2包括选自Mg，Ca，Sr和Ba中的至少两种元素，并且元素M2至少包括Mg和Ca。式1满足0.97 <= x <= 1.1,0.05 <= y <=0.35,0.005≤z≤0.1,0.0001≤v≤0.05,0.0001≤w≤0.05。初级粒子的平均粒径为0.1μm以上3μm以下，二次粒子的平均粒径为8μm以上且20μm以下。

8. 发明申请

US20070166624A1 Non-aqueous electrolyte secondary battery 有权
标题翻译：非水电解质二次电池
公开(公告)号：US20070166624A1
公开(公告)日：2007-07-19
申请号：US11595897
申请日：2006-11-13
申请人： Akihiro Taniguchi , Kensuke Nakura , Takashi Takeuchi
发明人： Akihiro Taniguchi , Kensuke Nakura , Takashi Takeuchi
IPC分类号： H01M10/40 , H01M4/52
CPC分类号： H01M10/0587 , H01M4/131 , H01M4/485 , H01M4/505 , H01M4/525 , H01M10/0569 , H01M2010/4292 , H01M2300/0037
摘要： A non-aqueous electrolyte secondary battery including: an electrode group in which a positive electrode and a negative electrode are spirally wound with a separator interposed therebetween; and a non-aqueous electrolyte including a non-aqueous solvent and a lithium salt dissolved in the non-aqueous solvent, the positive electrode including a positive electrode material mixture layer containing a nickel-containing lithium composite metal oxide, wherein a product of A and B equals 150 to 350, A equals 15 to 20%, and B equals 8 to 25%, where A (%) represents a porosity of the positive electrode material mixture layer, and B (%) represents a volume percentage of ethylene carbonate in the non-aqueous solvent.
摘要翻译： 1.一种非水电解质二次电池，其特征在于，具有：正极和负极间隔开间隔地螺旋状卷绕的电极组，以及包含溶解在非水溶剂中的非水溶剂和锂盐的非水电解质，所述正极包括含有镍的锂复合金属氧化物的正极合剂层，其中A和 B等于150至350，A等于15至20％，B等于8至25％，其中A（％）表示正极合剂层的孔隙率，B（％）表示碳酸亚乙酯的体积百分比非水溶剂。

9. 发明申请

US20120088137A1 NONAQUEOUS ELECTROLYTE SECONDARY BATTERY 审中-公开
标题翻译：非电解电解质二次电池
公开(公告)号：US20120088137A1
公开(公告)日：2012-04-12
申请号：US13378210
申请日：2010-06-24
申请人： Kensuke Nakura
发明人： Kensuke Nakura
IPC分类号： H01M10/0525 , H01M10/05 , H01M10/02 , H01M4/13
CPC分类号： H01M10/052 , H01M2/26 , H01M4/661 , H01M10/0585 , H01M10/0587 , Y02T10/7011
摘要： A battery case houses an electrode group formed by winding a positive electrode plate where a positive electrode active material layer is provided on a positive electrode current collector and a negative electrode plate where a negative electrode active material layer is provided on a negative electrode current collector with a porous insulating layer interposed therebetween. The current collectors are made of metal foil of an identical material. An end of the positive electrode current collector has a first exposed portion provided with no positive electrode active material layer. An end of the negative electrode current collector has a second exposed portion provided with no negative electrode active material layer. The exposed portions and project from the porous insulating layer in opposite directions. The first and second exposed portions and are connected to positive and negative electrode current collector plates, respectively.
摘要翻译：电池壳体容纳通过在正极集电体上设置正极活性物质层的正极板和在负极集电体上设置负极活性物质层的负极板卷绕正极板而形成的电极组，插入其间的多孔绝缘层。集电器由相同材料的金属箔制成。正极集电体的端部具有不具有正极活性物质层的第一露出部。负极集电体的端部具有不具有负极活性物质层的第二露出部。暴露部分并从相反方向从多孔绝缘层突出。第一和第二暴露部分分别连接到正极和负极集电板。

10. 发明申请

US20120009475A1 ELECTRODE FOR NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY AND NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY INCLUDING THE SAME 审中-公开
标题翻译：非水电解二次电池电极和非水电解质二次电池，包括它们
公开(公告)号：US20120009475A1
公开(公告)日：2012-01-12
申请号：US13257549
申请日：2011-03-03
申请人： Kensuke Nakura
发明人： Kensuke Nakura
IPC分类号： H01M4/131
CPC分类号： H01M10/0587 , H01M4/131 , H01M4/133 , H01M4/136 , H01M4/485 , H01M4/5825 , H01M10/0525 , H01M2004/021 , Y02T10/7011
摘要： An electrode for a non-aqueous electrolyte secondary battery includes a sheet-like current collector and an active material layer including a first layer and a second layer which are adhering to a surface of the current collector in this order. The first layer includes a carbon material that absorbs or releases lithium ions reversibly at a first potential, while the second layer includes a transition metal oxide that absorbs or releases lithium ions reversibly at a second potential higher than the first potential. The difference between the first potential and the second potential is 0.1 V or more, and the ratio of the thickness T1 of the first layer to the thickness T2 of the second layer, i.e., the ratio T1/T2, is from 0.33 to 75.
摘要翻译：非水电解质二次电池用电极包括依次附着在集电体的表面上的片状集电体和含有第一层和第二层的活性物质层。第一层包括在第一电势下可逆地吸收或释放锂离子的碳材料，而第二层包括在高于第一电位的第二电位下可逆地吸收或释放锂离子的过渡金属氧化物。第一电位和第二电位之间的差为0.1V以上，第一层的厚度T1与第二层的厚度T2之比即T1 / T2为0.33〜75。

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