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1. 发明授权

US4748207A Polypropylene sheet 失效
标题翻译：聚丙烯片
公开(公告)号：US4748207A
公开(公告)日：1988-05-31
申请号：US753082
申请日：1985-07-09
申请人： Masahiro Kakugo , Yoshiharu Fukui , Kizuku Wakatsuki , Hideaki Nishio
发明人： Masahiro Kakugo , Yoshiharu Fukui , Kizuku Wakatsuki , Hideaki Nishio
IPC分类号： C08L23/00 , C08F210/06 , C08L7/00 , C08L21/00 , C08L23/12 , C08L23/14 , C08L23/18 , C08L23/20 , C08L77/00 , C08L101/00 , C08J5/18 , C08L53/00
CPC分类号： C08L23/12 , C08L23/142 , C08F210/06 , C08L23/20 , C08L2314/02
摘要： A crystalline polypropylene sheet is described, characterized by containing a polymer of a vinylcycloalkane having at least 6 carbon atoms in an amount of 0.05 wt ppm to 1 wt % (calculated as a vinylcycloalkane unit). This sheet is excellent in stiffness and transparency and is suitable for use in the production of various articles such as containers and trays.
摘要翻译：描述了结晶聚丙烯片材，其特征在于含有0.05重量％至1重量％（以乙烯基环烷烃单元计算）的具有至少6个碳原子的乙烯基环烷烃的聚合物。该片材的刚度和透明度优异，适用于各种制品如容器和托盘的生产。

2. 发明授权

US4603174A Stretched polypropylene film 失效
标题翻译：拉伸聚丙烯薄膜
公开(公告)号：US4603174A
公开(公告)日：1986-07-29
申请号：US686865
申请日：1984-12-27
申请人： Tadayuki Okada , Masahiro Kakugo , Yoshiharu Fukui , Kizuku Wakatsuki , Seiichiro Ima , Junichi Kimura
发明人： Tadayuki Okada , Masahiro Kakugo , Yoshiharu Fukui , Kizuku Wakatsuki , Seiichiro Ima , Junichi Kimura
IPC分类号： B29C55/00 , B29C55/02 , B29K23/00 , B29L7/00 , C08J5/18 , C08L23/12 , C08L23/14 , C08L23/20 , C08L23/04
CPC分类号： C08J5/18 , C08L23/12 , C08L23/142 , C08J2323/10 , C08L23/20 , C08L2314/02 , Y10S428/91 , Y10T428/31913
摘要： A stretched polypropylene film having excellent see-through characteristics, which is prepared by stretching in at least one direction a polypropylene resin sheet containing 0.05 ppm to 10,000 ppm by weight of a 3-position branched .alpha.-olefin unit and/or a vinyl cycloalkane unit, each having at least 6 carbon atoms.
摘要翻译：一种拉伸聚丙烯薄膜，具有优异的透视特性，其通过至少一个方向拉伸含有0.05ppm至10,000ppm重量的3-位支链α-烯烃单元和/或乙烯基环烷烃单元的聚丙烯树脂板各自具有至少6个碳原子。

3. 发明授权

US4584239A Stretched multilayer polypropylene film 失效
标题翻译：拉伸多层聚丙烯薄膜
公开(公告)号：US4584239A
公开(公告)日：1986-04-22
申请号：US753846
申请日：1985-07-11
申请人： Masahiro Kakugo , Yoshiharu Fukui , Kizuku Wakatsuki , Seiichiro Ima , Junichi Kimura
发明人： Masahiro Kakugo , Yoshiharu Fukui , Kizuku Wakatsuki , Seiichiro Ima , Junichi Kimura
IPC分类号： B32B27/00 , B32B27/32 , C09J7/02 , C09J123/08 , C09J123/14
CPC分类号： C09J7/0242 , B32B27/32 , C09J123/0815 , C09J123/142 , Y10S428/91 , Y10T428/2826
摘要： A stretched multilayer polypropylene film is described, comprising a stretched crystalline polypropylene layer and a layer of a composition (Composition B) laminated on at least one side of said polypropylene layer, wherein the composition B comprises a homo- or copolymer composed mainly of ethylene, propylene or butene-1 and having a melting point of 150.degree. C. or less, and a vinylcycloalkane polymer in an amount of 0.05 wt ppm to 10 wt % calculated as a vinylcycloalkane unit. This multilayer film is greatly improved in optical properties such as excellent see-through properties without deteriorating its good heat sealability. Thus it is very useful for wrapping.
摘要翻译：描述了拉伸的多层聚丙烯薄膜，其包含拉伸的结晶聚丙烯层和层压在所述聚丙烯层的至少一侧上的组合物层（组合物B），其中组合物B包含主要由乙烯组成的均聚物或共聚物，丙烯或丁烯-1，熔点为150℃以下，乙烯基环烷烃聚合物的量为0.05重量％〜10重量％，以乙烯基环烷烃单元计算。这种多层膜在透光性方面优异的光学特性大大提高，而不会使其良好的热封性劣化。因此，它是非常有用的包装。

4. 发明授权

US4696979A Process for producing propylene copolymer 失效
标题翻译：制备丙烯共聚物的方法
公开(公告)号：US4696979A
公开(公告)日：1987-09-29
申请号：US686864
申请日：1984-12-27
申请人： Akinobu Shiga , Masahiro Kakugo , Junpei Kozima , Kizuku Wakatsuki
发明人： Akinobu Shiga , Masahiro Kakugo , Junpei Kozima , Kizuku Wakatsuki
IPC分类号： C08L23/10 , C08L23/20 , C08L53/00 , C08L23/14
CPC分类号： C08L23/10 , C08L53/00 , C08L23/20
摘要： A process for producing a propylene copolymer having improved transparency and rigidity, which comprises carrying out (A) the polymerization of a vinyl cycloalkane having at least 6 carbon atoms and (B) the polymerization of propylene either alone or with ethylene in a multiplicity of steps in the presence of a catalyst system composed of a titanium compound and an organoaluminum compound. The content of the vinyl cycloalkane unit in the resulting copolymer is 0.05 to 10,000 weight ppm.
摘要翻译：一种制备具有改善的透明度和刚性的丙烯共聚物的方法，其包括进行（A）聚合具有至少6个碳原子的乙烯基环烷烃和（B）单独或与乙烯在多个步骤中聚合丙烯在由钛化合物和有机铝化合物组成的催化剂体系的存在下。所得共聚物中乙烯基环烷烃单元的含量为0.05至10,000重量ppm。

5. 发明授权

US4551501A Crystalline propylene polymer composition 失效
标题翻译：结晶丙烯聚合物组合物
公开(公告)号：US4551501A
公开(公告)日：1985-11-05
申请号：US686866
申请日：1984-12-27
申请人： Akinobu Shiga , Masahiro Kakugo , Junpei Kojima , Kizuku Wakatsuki
发明人： Akinobu Shiga , Masahiro Kakugo , Junpei Kojima , Kizuku Wakatsuki
IPC分类号： C08L23/12 , C08F297/08 , C08L7/00 , C08L21/00 , C08L23/00 , C08L23/10 , C08L23/18 , C08L23/20 , C08L23/24 , C08L53/00 , C08L101/00 , C08L23/14
CPC分类号： C08L53/00 , C08F297/08 , C08F297/083 , C08L23/10 , C08L23/20
摘要： A crystalline propylene polymer composition having excellent transparency and rigidity comprising a blend of a crystalline polypropylene with a polymer of a vinyl cycloalkane having at least 6 carbon atoms. The composition contains 0.05 weight ppm to 10,000 weight ppm of the vinyl cycloalkane unit.
摘要翻译：一种结晶丙烯聚合物组合物，其具有优异的透明度和刚度，包括结晶聚丙烯与具有至少6个碳原子的乙烯基环烷烃聚合物的共混物。该组合物含有0.05重量ppm至10,000重量ppm的乙烯基环烷烃单元。

6. 发明授权

US5039748A High-strength polypropylene fiber 失效
标题翻译：高强度聚丙烯纤维
公开(公告)号：US5039748A
公开(公告)日：1991-08-13
申请号：US524526
申请日：1990-05-17
申请人： Kizuku Wakatsuki , Noboru Yamaguchi , Kazuki Wakamatsu , Masahiro Kakugo , Tadayuki Ohmae
发明人： Kizuku Wakatsuki , Noboru Yamaguchi , Kazuki Wakamatsu , Masahiro Kakugo , Tadayuki Ohmae
IPC分类号： C08L23/10 , C08L23/12 , C08L23/14 , C08L23/20 , D01F6/06
CPC分类号： C08L23/10 , C08L23/12 , D01F6/06 , C08L2203/12 , C08L23/20 , C08L2314/02
摘要： High-Strength polypropylene fiber is obtained from polypropylene having incorporated therein from 0.05 to 10,000 ppm by weight of a vinylcycloalkane polymer. The disclosed fiber polypropylene has an intrinsic viscosity of from 0.5 to 2.5 dl/g as measured in a tetralin solution at 135.degree. C. and a ratio of weight average molecular weight to number average molecular weight of not more than 3.5/1.

7. 发明授权

US4663394A Crystalline polybutene-1 compositions 失效
标题翻译：结晶聚丁烯-1组合物
公开(公告)号：US4663394A
公开(公告)日：1987-05-05
申请号：US746690
申请日：1985-06-20
申请人： Masahiro Kakugo , Kizuku Wakatsuki
发明人： Masahiro Kakugo , Kizuku Wakatsuki
IPC分类号： C08F10/08 , C08F210/00 , C08F210/08 , C08L23/18 , C08L23/20 , C08F297/08
CPC分类号： C08L23/20
摘要： A crystalline polybutene-1 composition containing from 1.times.10.sup.-6 to 10% byweight of a vinylcycloalkane unit having a melting point of 180.degree. C. or higher in terms of its homopolymer, is disclosed. The composition has a markedly improved rate of crystal conversion of polybutene-1.
摘要翻译：公开了一种结晶聚丁烯-1组合物，其含有1×10 -6至10重量％的其均聚物的熔点为180℃或更高的乙烯基环烷烃单元。该组合物的聚丁烯-1的晶体转化率显着提高。

8. 发明授权

US4259461A Process for producing propylene-ethylene block copolymers 失效
标题翻译：制备丙烯 - 乙烯嵌段共聚物的方法
公开(公告)号：US4259461A
公开(公告)日：1981-03-31
申请号：US041462
申请日：1979-05-22
申请人： Akinobu Shiga , Masahiro Kakugo , Yoshiharu Fukui , Koji Yamada , Hajime Sadatoshi , Kazuki Wakamatsu , Hiroshi Yoshioka
发明人： Akinobu Shiga , Masahiro Kakugo , Yoshiharu Fukui , Koji Yamada , Hajime Sadatoshi , Kazuki Wakamatsu , Hiroshi Yoshioka
IPC分类号： C08F297/08
CPC分类号： C08F297/083
摘要： An improved process for producing propylene-ethylene block copolymer is disclosed utilizing a catalyst system comprising (A) a titanium trichloride solid catalyst obtained by reducing titanium tetrachloride with an organoaluminum compound and activating, (B) an organoaluminum compound, and optionally, (C) an electron donor.
摘要翻译：公开了一种用于生产丙烯 - 乙烯嵌段共聚物的改进方法，该催化剂体系包含（A）通过用有机铝化合物还原四氯化钛并活化（B）有机铝化合物和任选的（C）电子供体。

9. 发明授权

US5147942A Thermoplastic resin composition 失效
公开(公告)号：US5147942A
公开(公告)日：1992-09-15
申请号：US476687
申请日：1990-02-08
申请人： Hiroomi Abe , Taichi Nishio , Yasurou Suzuki , Takeshi Sanada , Masahiro Kakugo
发明人： Hiroomi Abe , Taichi Nishio , Yasurou Suzuki , Takeshi Sanada , Masahiro Kakugo
IPC分类号： C08L51/00 , C08G65/48 , C08L51/06 , C08L53/00 , C08L67/00 , C08L71/00 , C08L71/12 , C08L75/00 , C08L77/00 , C08L81/00 , C08L101/00
CPC分类号： C08L71/12 , C08G65/485 , C08L77/00 , C08L67/00 , C08L71/00 , C08L75/00 , C08L81/00 , Y10S525/905
摘要： Disclosed is a thermoplastic resin composition improved in low-temperature impact resistance and processability which comprises:(A) 5-95% by weight of a polyamide resin which has a relative viscosity of 3.1-4.5 and has a ratio .alpha. of terminal amino group to terminal carboxyl group of 0

10. 发明授权

US4414373A Propylene-ethylene copolymer having improved stretchability 失效
标题翻译：具有改善的拉伸性的丙烯 - 乙烯共聚物
公开(公告)号：US4414373A
公开(公告)日：1983-11-08
申请号：US399146
申请日：1982-07-16
申请人： Akinobu Shiga , Kiyoshi Matsuyama , Masahiro Kakugo , Yukio Naito , Seiichiro Ima , Katsuyoshi Yamashita
发明人： Akinobu Shiga , Kiyoshi Matsuyama , Masahiro Kakugo , Yukio Naito , Seiichiro Ima , Katsuyoshi Yamashita
IPC分类号： C08F4/00 , C08F2/00 , C08F4/60 , C08F4/64 , C08F10/00 , C08F10/06 , C08F210/00 , C08F210/06 , C08F210/16
CPC分类号： C08F210/06
摘要： In a process for producing polypropylene comprising polymerizing propylene in the presence of hydrogen and a catalyst system comprising (A) titanium trichloride obtained by reducing titanium tetrachloride with an organoaluminum compound and reacting the reduced solid with an ether represented by the formula:R.sup.1 --O--R.sup.2wherein R.sup.1 and R.sup.2 are defined hereinbefore, and a halogen compound selected from the group consisting of (i) halogen or interhalogen compounds of the formula, X.sup.1 X.sup.2.sub.a (wherein X.sup.1, X.sup.2 and a are defined hereinbefore), (ii) titanium halides, and (iii) organic halogen compounds, simultaneously or successively and (B) an organoaluminum compound, the improvement which comprises supplying ethylene together with propylene to the polymerization system such that the ethylene concentration in the vapor phase of the system based on the total amount of propylene, ethylene and hydrogen in the vapor phase of the system is 0.15 to 1.5 mol % to obtain a propylene-ethylene copolymer having an ethylene content of from 0.1 to 1.0 wt % is disclosed. The propylene-ethylene copolymer is improved in stretchability.
摘要翻译：在制备聚丙烯的方法中，包括在氢气存在下聚合丙烯和催化剂体系，所述催化剂体系包含（A）通过用有机铝化合物还原四氯化钛获得的三氯化钛，并将还原的固体与由下式表示的醚反应：R1-O- 其中R 1和R 2如上定义，卤素化合物选自（ⅰ）卤素或下式的卤代化合物：X1X2a（其中X1，X2和a定义如前），（ⅱ）卤化钛和（iii）有机卤素化合物，同时或相继和（B）有机铝化合物，其改进包括将乙烯与丙烯一起供应到聚合体系中，使得基于丙烯总量的体系的气相中的乙烯浓度，系统的气相中的乙烯和氢为0.15〜1.5摩尔％，得到丙烯 - 乙烯共聚物公开了乙烯含量为0.1〜1.0重量％。丙烯 - 乙烯共聚物的拉伸性提高。

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