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    • 10. 发明授权
    • Electron beam curable polyurethane compositions
    • 电子束固化聚氨酯组合物
    • US4467078A
    • 1984-08-21
    • US548385
    • 1983-11-03
    • Edmond G. KolycheckLaura L. Tolle
    • Edmond G. KolycheckLaura L. Tolle
    • C08G18/67C08L75/14C08F283/06C08G65/32C08L75/04
    • C08G18/6795C08G18/672C08L75/14Y10S525/92
    • Improved electron beam curable compounds are prepared by mixing 100 weight parts of (1) polyurethanes prepared from polymeric polyols, organic diisocyanates and polyethers having terminal hydroxyl and unsaturated groups, or terminal hydroxyl and pendant unsaturated groups with (2) 1 to 25 weight parts of an acrylate or alkacrylate terminated polyurethanes prepared by reacting isocyanate terminated prepolymers of hydroxyl terminated polymers with hydroxyl-terminated acrylates or alkacrylates. Compositions of this blend may be crosslinked or cured in a few seconds by electron beam to provide an improved stable coating that can be cured to a variety of hardnesses. These polyurethanes combined with phenoxy resins also form particularly useful binder systems for magnetic tape.
    • 通过混合100重量份由聚合多元醇制备的(1)聚氨酯,有机二异氰酸酯和具有末端羟基和不饱和基团的聚醚,或末端羟基和侧基不饱和基团的(2)1至25重量份 通过使羟基封端的聚合物的异氰酸酯封端的预聚物与羟基封端的丙烯酸酯或烷基丙烯酸酯反应制备的丙烯酸酯或烷基丙烯酸酯封端的聚氨酯。 该混合物的组合物可以在几秒钟内通过电子束交联或固化,以提供可固化至各种硬度的改进的稳定涂层。 这些聚氨酯与苯氧基树脂组合也形成用于磁带的特别有用的粘合剂体系。