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1. 发明授权

US06767447B2 Electrolytic cell for hydrogen peroxide production and process for producing hydrogen peroxide 有权
标题翻译：用于过氧化氢生产的电解槽和生产过氧化氢的方法
公开(公告)号：US06767447B2
公开(公告)日：2004-07-27
申请号：US10123114
申请日：2002-04-17
申请人： Masaharu Uno , Shuhei Wakita , Masao Sekimoto , Tsuneto Furuta , Yoshinori Nishiki
发明人： Masaharu Uno , Shuhei Wakita , Masao Sekimoto , Tsuneto Furuta , Yoshinori Nishiki
IPC分类号： C25B130
CPC分类号： C25B1/30
摘要： An electrolytic cell and method of electrolysis for producing hydrogen peroxide at a moderate current density while preventing metal deposition on the cathode surface. A feed water from which multivalent metal ions have been removed and in which a salt of a univalent metal, e.g., sodium sulfate, has been dissolved in a given concentration is prepared with an apparatus for removing multivalent metal ions and dissolving a salt in low concentration. The feed water is supplied to an electrolytic cell. Even when electrolysis is continued, almost no deposition of a hydroxide or carbonate occurs on the cathode because multivalent metal ions are not present in the electrolytic solution. Due to the dissolved salt, a sufficient current density is secured to prevent an excessive load from being imposed on the electrodes, etc. Thus, stable production of hydrogen peroxide is possible over a long period of time.
摘要翻译：一种电解槽和电解方法，用于在中等电流密度下生产过氧化氢，同时防止阴极表面上的金属沉积。用一种除去多价金属离子并溶解盐浓度低的装置制备已经除去多价金属离子并且其中以一定浓度的硫酸钠等单价盐溶解的给水的给水。给水供给电解池。即使继续进行电解，因为在电解液中不存在多价金属离子，所以在阴极上几乎不发生氢氧化物或碳酸盐的沉积。由于溶解的盐，确保足够的电流密度以防止对电极等施加过大的负荷。因此，可以长期稳定地生产过氧化氢。

2. 发明授权

US07468121B2 Conductive diamond electrode and process for producing the same 有权
标题翻译：导电金刚石电极及其制造方法
公开(公告)号：US07468121B2
公开(公告)日：2008-12-23
申请号：US11496394
申请日：2006-08-01
申请人： Masashi Hosonuma , Masaharu Uno , Tomoyasu Shibata , Yoshinori Nishiki , Tsuneto Furuta
发明人： Masashi Hosonuma , Masaharu Uno , Tomoyasu Shibata , Yoshinori Nishiki , Tsuneto Furuta
IPC分类号： C25B11/12
CPC分类号： C25B11/0442 , C02F1/46109 , C02F2001/46138 , C23C16/0281 , C23C16/271 , C23C16/278 , Y10T428/12535 , Y10T428/12625
摘要： The present invention provides a conductive diamond electrode having: a conductive substrate; a coating layer formed on a surface of the conductive substrate, the coating layer containing one of a metal and an alloy each including at least one of niobium and tantalum; and a conductive diamond layer formed on a surface of the coating layer, and a process for producing the conductive diamond electrode.
摘要翻译：本发明提供一种导电金刚石电极，其具有导电性基板; 形成在所述导电性基材的表面上的被覆层，所述被覆层含有金属和合金中的至少一种，包含铌和钽中的至少一种; 以及形成在所述涂层的表面上的导电金刚石层，以及所述导电金刚石电极的制造方法。

3. 发明申请

US20070170070A1 Electrolysis cell for synthesizing perchloric acid compound and method for electrolytically synthesizing perchloric acid compound 审中-公开
标题翻译：用于合成高氯酸化合物的电解槽和电解合成高氯酸化合物的方法
公开(公告)号：US20070170070A1
公开(公告)日：2007-07-26
申请号：US11657071
申请日：2007-01-24
申请人： Masaharu Uno , Miwako Nara , Yoshinori Nishiki , Tsuneto Furuta
发明人： Masaharu Uno , Miwako Nara , Yoshinori Nishiki , Tsuneto Furuta
IPC分类号： C25B11/12 , C25B1/28
CPC分类号： C25B1/28
摘要： The present invention provides an electrolysis cell for synthesizing a perchloric acid compound, the electrolysis cell having: a feedstock solution containing a chloride or a chloric acid compound; a cathode; and an anode having an electroconductive diamond as an anode substance, the anode electrolytically oxidizing the chloride or the chloric acid compound to synthesize the perchloric acid compound, and a method for electrolytically synthesizing a perchloric acid compound.
摘要翻译：本发明提供了一种用于合成高氯酸化合物的电解槽，所述电解槽具有：含有氯化物或氯酸化合物的原料溶液; 阴极和具有导电金刚石作为阳极物质的阳极，阳极电解氧化氯化物或氯酸化合物以合成高氯酸化合物，以及电解合成高氯酸化合物的方法。

4. 发明授权

US07857953B2 Oxygen-reducing gas diffusion cathode and method of sodium chloride electrolysis 失效
标题翻译：减氧气体扩散阴极和氯化钠电解方法
公开(公告)号：US07857953B2
公开(公告)日：2010-12-28
申请号：US11585979
申请日：2006-10-25
申请人： Yuji Yamada , Yuki Izawa , Masaharu Uno , Yoshinori Nishiki , Tsuneto Furuta
发明人： Yuji Yamada , Yuki Izawa , Masaharu Uno , Yoshinori Nishiki , Tsuneto Furuta
IPC分类号： C25B11/06 , C25B11/12
CPC分类号： C25B1/46 , C25B1/16 , C25B11/035 , H01M4/8605 , H01M4/8663 , H01M4/8807 , H01M4/8821 , H01M4/92 , H01M4/926
摘要： The present invention provides an oxygen-reduction gas diffusion cathode having: a porous conductive substrate; diamond particle having a hydrophobic surface; and catalyst particle, the diamond particle and the catalyst particle being disposed on the porous conductive substrate, and a method of sodium chloride electrolysis using the cathode.
摘要翻译：本发明提供一种氧还原气体扩散阴极，具有：多孔导电性基板; 具有疏水性表面的金刚石颗粒; 和催化剂颗粒，金刚石颗粒和催化剂颗粒设置在多孔导电性基材上，以及使用阴极进行氯化钠电解的方法。

5. 发明授权

US07217347B2 Diamond electrode for electrolysis 有权
标题翻译：用于电解的金刚石电极
公开(公告)号：US07217347B2
公开(公告)日：2007-05-15
申请号：US10823752
申请日：2004-04-14
申请人： Masashi Hosonuma , Miwako Nara , Masaharu Uno , Yoshinori Nishiki , Tsuneto Furuta , Tateki Kurosu , Osamu Fukunaga , Tetsuro Tojo
发明人： Masashi Hosonuma , Miwako Nara , Masaharu Uno , Yoshinori Nishiki , Tsuneto Furuta , Tateki Kurosu , Osamu Fukunaga , Tetsuro Tojo
IPC分类号： C25B11/12
CPC分类号： C25B11/0478 , C02F1/46114 , C02F1/4672 , C02F2001/46142 , Y10T428/30
摘要： A diamond electrode having a prolonged life by combining a conventional diamond electrode having a relatively short life with other components is provided. A diamond electrode for electrolysis includes an electrode substrate, at least the surface of which comprises Magneli phase titanium oxide, and conductive diamond supported as an electrode catalyst on a surface of the electrode. The electrode catalyst may contain a titanium oxide powder. Magneli phase titanium oxide improves conductivity without forming a stable oxide layer on the substrate surface.
摘要翻译：提供了通过将具有相对短寿命的常规金刚石电极与其它组分组合而具有延长使用寿命的金刚石电极。用于电解的金刚石电极包括至少其表面包含Magneli相氧化钛的电极基底和在电极表面上作为电极催化剂负载的导电金刚石。电极催化剂可以含有氧化钛粉末。 Magneli相二氧化钛改善导电性，而在基材表面上形成稳定的氧化物层。

6. 发明申请

US20070095676A1 Oxygen-reducing gas diffusion cathode and method of sodium chloride electrolysis 失效
标题翻译：减氧气体扩散阴极和氯化钠电解方法
公开(公告)号：US20070095676A1
公开(公告)日：2007-05-03
申请号：US11585979
申请日：2006-10-25
申请人： Yuji Yamada , Yuki Izawa , Masaharu Uno , Yoshinori Nishiki , Tsuneto Furuta
发明人： Yuji Yamada , Yuki Izawa , Masaharu Uno , Yoshinori Nishiki , Tsuneto Furuta
IPC分类号： C25B1/16
CPC分类号： C25B1/46 , C25B1/16 , C25B11/035 , H01M4/8605 , H01M4/8663 , H01M4/8807 , H01M4/8821 , H01M4/92 , H01M4/926
摘要： The present invention provides an oxygen-reduction gas diffusion cathode having: a porous conductive substrate; diamond particle having a hydrophobic surface; and catalyst particle, the diamond particle and the catalyst particle being disposed on the porous conductive substrate, and a method of sodium chloride electrolysis using the cathode.
摘要翻译：本发明提供一种氧还原气体扩散阴极，具有：多孔导电性基板; 具有疏水性表面的金刚石颗粒; 和催化剂颗粒，金刚石颗粒和催化剂颗粒设置在多孔导电性基材上，以及使用阴极进行氯化钠电解的方法。

7. 发明申请

US20070031694A1 Conductive diamond electrode and process for producing the same 有权
标题翻译：导电金刚石电极及其制造方法
公开(公告)号：US20070031694A1
公开(公告)日：2007-02-08
申请号：US11496394
申请日：2006-08-01
申请人： Masashi Hosonuma , Masaharu Uno , Tomoyasu Shibata , Yoshinori Nishiki , Tsuneto Furuta
发明人： Masashi Hosonuma , Masaharu Uno , Tomoyasu Shibata , Yoshinori Nishiki , Tsuneto Furuta
IPC分类号： C25B11/12 , C23C16/00 , B21D39/00 , C03C27/00
CPC分类号： C25B11/0442 , C02F1/46109 , C02F2001/46138 , C23C16/0281 , C23C16/271 , C23C16/278 , Y10T428/12535 , Y10T428/12625
摘要： The present invention provides a conductive diamond electrode having: a conductive substrate; a coating layer formed on a surface of the conductive substrate, the coating layer containing one of a metal and an alloy each including at least one of niobium and tantalum; and a conductive diamond layer formed on a surface of the coating layer, and a process for producing the conductive diamond electrode.
摘要翻译：本发明提供一种导电金刚石电极，其具有导电性基板; 形成在所述导电性基材的表面上的被覆层，所述被覆层含有金属和合金中的至少一种，包含铌和钽中的至少一种; 以及形成在所述涂层的表面上的导电金刚石层，以及所述导电金刚石电极的制造方法。

8. 发明申请

US20070023273A1 Method of sterilization and electrolytic water ejecting apparatus 有权
标题翻译：灭菌方法和电解水喷射装置
公开(公告)号：US20070023273A1
公开(公告)日：2007-02-01
申请号：US11452937
申请日：2006-06-15
申请人： Noriyuki Kitaori , Masaharu Uno , Yoshinori Nishiki , Tsuneto Furuta
发明人： Noriyuki Kitaori , Masaharu Uno , Yoshinori Nishiki , Tsuneto Furuta
IPC分类号： H05F3/00 , B01J19/08
CPC分类号： A61L2/183 , A61L2/186 , A61L2/202 , A61L2/22 , A61L2202/11 , C02F1/46114 , C02F1/4672 , C02F1/66 , C02F2001/46138 , C02F2001/46152 , C02F2201/003 , C02F2201/46115 , C02F2201/46125 , C02F2209/23 , C02F2303/04 , C02F2305/04 , C02F2307/02
摘要： The present invention provides a method of sterilization with an electrolytic water, including: electrolyzing a raw water with an electrolytic unit including: a cathode; and an anode at least having a part containing a conductive diamond to prepare an electrolytic water; and ejecting the electrolytic water to a substance to be sterilized, and an electrolytic water ejecting apparatus.
摘要翻译：本发明提供一种用电解水灭菌的方法，包括：用电解单元电解原水，包括：阴极; 和至少具有包含导电金刚石的部分以制备电解水的阳极; 并将电解水排出到待灭菌物质，以及电解水喷射装置。

9. 发明申请

US20060066203A1 Conductive diamond electrode and process for producing the same 有权
标题翻译：导电金刚石电极及其制造方法
公开(公告)号：US20060066203A1
公开(公告)日：2006-03-30
申请号：US11220685
申请日：2005-09-08
申请人： Masaharu Uno , Yoshinori Nishiki , Tsuneto Furuta , Miho Ohashi , Tetsuro Tojo , Hitoshi Takebayashi , Tateki Kurosu
发明人： Masaharu Uno , Yoshinori Nishiki , Tsuneto Furuta , Miho Ohashi , Tetsuro Tojo , Hitoshi Takebayashi , Tateki Kurosu
IPC分类号： H01J1/05
CPC分类号： H01M4/58 , C02F1/46109 , C02F2001/46142 , C23C8/02 , C23C28/04 , C25B1/245 , C25B11/0442
摘要： A conductive diamond electrode including a conductive substrate comprising a carbonaceous material, a conductive diamond catalyst layer formed on a surface of the conductive substrate, and a carbon fluoride formed on an exposed portion present on the surface of the conductive substrate. The formed carbon fluoride prevents the conductive substrate from contacting with an electrolytic solution, thereby suppressing corrosion of the substrate. A long life of the electrode can be attained.
摘要翻译：导电金刚石电极，其包括含有碳质材料的导电性基材，形成在导电性基材的表面上的导电性金刚石催化剂层，以及形成在导电性基材的表面上的露出部分上形成的氟化碳。形成的碳氟化物防止导电性基材与电解液接触，从而抑制基板的腐蚀。可以实现电极的寿命长。

10. 发明授权

US07858551B2 Electrode catalyst for electrochemical reaction, process for producing the electrode catalyst and electrode for electrochemical reaction having the electrode catalyst 有权
标题翻译：用于电化学反应的电极催化剂，用于生产电极催化剂的方法和具有电极催化剂的电化学反应用电极
公开(公告)号：US07858551B2
公开(公告)日：2010-12-28
申请号：US11715868
申请日：2007-03-09
申请人： Yoshio Takasu , Yasushi Murakami , Wataru Sugimoto , Yuji Yamada , Masaharu Uno , Yoshinori Nishiki , Tsuneto Furuta
发明人： Yoshio Takasu , Yasushi Murakami , Wataru Sugimoto , Yuji Yamada , Masaharu Uno , Yoshinori Nishiki , Tsuneto Furuta
IPC分类号： H01M4/88 , B01J23/40 , B01J23/42 , B01J23/48
CPC分类号： H01M4/90 , C25B1/34 , C25B11/0478 , H01M4/8605 , H01M4/9083 , H01M4/92 , H01M4/926 , H01M2008/1095
摘要： The present invention provides an electrode catalyst for electrochemical reaction, the electrode catalyst having: a conductive diamond particle having fine pores on a surface thereof; and a carbon-reactive catalyst metal in the fine pores, a process for producing the electrode catalyst, and an electrode.
摘要翻译：本发明提供一种用于电化学反应的电极催化剂，所述电极催化剂具有：在其表面上具有细孔的导电金刚石颗粒; 和细孔中的碳反应性催化剂金属，电极催化剂的制造方法和电极。

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