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    • 1. 发明授权
    • Electrophotographic toner and production process thereof
    • 电子照相调色剂及其制备方法
    • US5370958A
    • 1994-12-06
    • US10871
    • 1993-01-29
    • Masaaki ShinKenji UchiyamaYasuo Okada
    • Masaaki ShinKenji UchiyamaYasuo Okada
    • G03G9/087
    • G03G9/08791G03G9/08793G03G9/08795
    • An object of the present invention is to provide an electrophotographic toner for high-speed copying machines having a high hot-roll speed and capable of fixing a toner at lower temperatures. The toner according to the present invention comprises a vinyl resin which has a wide molecular-weight distribution (Mn:1,000-20,000, Mw: 50,000-2,000,000), a glass transition temperature (Tg) of 40.degree.-75.degree. C. and a low acid value (AV:1-10); and a glycidyl compound in an amount sufficient to provide 0.05-1.0 equivalent of glycidyl groups per equivalent of COOH groups in the vinyl resin. It assures well-balanced fixing property, offset resistance and blocking resistance. In particular, it exhibits a remarkable effect in improving offset resistance and also in grindability during the production of the toner.
    • 本发明的目的是提供一种具有高热轧速度并且能够在较低温度下固定调色剂的高速复印机的电子照相调色剂。 根据本发明的调色剂包括具有宽分子量分布(Mn:1,000-20,000,Mw:50,000-2,000,000),玻璃化转变温度(Tg)为40-75℃的乙烯基树脂和 低酸值(AV:1-10); 和足以在乙烯基树脂中每当量COOH基团提供0.05-1.0当量缩水甘油基的量的缩水甘油基化合物。 它确保平衡的定影性能,抗偏移性和抗粘连性。 特别是,在调色剂生产过程中,其抗粘着性以及可磨性的改善表现出显着的效果。
    • 5. 发明授权
    • Toner composition for electrophotography
    • 电子照相用调色剂组合物
    • US5427883A
    • 1995-06-27
    • US343995
    • 1994-11-18
    • Akira MisawaKazuo HisamatsuKeiichi IshikawaKazuo HagiwaraMasaaki Shin
    • Akira MisawaKazuo HisamatsuKeiichi IshikawaKazuo HagiwaraMasaaki Shin
    • C08G18/42G03G9/087
    • C08G18/4255G03G9/08764Y10S430/105
    • The present invention provides a toner composition mainly comprising a binder resin (D) which contains at least 20% by weight of an urethane-modified polyester resin (C) obtained by reacting a polyester resin (A) with an isocyanate compound (B) and whose gel fraction ranges from 2 to 75% by weight. The toner composition exhibits good melting properties upon heating suitable for fast reproduction such as a low lower limit of the fixing temperature and a wide range for permitted fixing temperature and is further excellent in resistance to blocking, resistance to carrier contamination and image-forming properties. The binder resin as the main component of the toner composition can be prepared according to a method comprising the step of continuously adding an isocyanate compound (B) to a polyester resin (A) in an equivalent ratio, NCO/OH, of the amount of the NCO groups of the isocyanate compound (B) to that of OH groups of the polyester resin (A) ranging from 0.3 to 1.00 with kneading to react them, in a kneading means having a built-in screw.
    • 本发明提供一种主要包含粘合剂树脂(D)的调色剂组合物,其含有至少20重量%的通过使聚酯树脂(A)与异氰酸酯化合物(B)反应得到的氨基甲酸酯改性聚酯树脂(C)和 其凝胶分数为2至75重量%。 调色剂组合物在适合快速再生的加热时显示出良好的熔融性能,例如定影温度的低下限和允许定影温度的宽范围,并且具有更好的耐粘连性,耐载体污染和成像性能。 作为调色剂组合物的主要成分的粘合剂树脂可以根据以下方法制备:将异氰酸酯化合物(B)以等于NCO / OH的比例连续加入到聚酯树脂(A)中的方法, 异氰酸酯化合物(B)的NCO基与聚酯树脂(A)的OH基的NCO基团在0.3〜1.00的范围内混炼,在具有内置螺杆的捏合装置中进行反应。
    • 6. 发明授权
    • Resins for toner of electrophotography and method for manufacturing the
same
    • 电子照相用调色剂用树脂及其制造方法
    • US5037715A
    • 1991-08-06
    • US535490
    • 1990-06-11
    • Kazuo HagiwaraAkira MisawaKazuo HisamatsuMasaaki Shin
    • Kazuo HagiwaraAkira MisawaKazuo HisamatsuMasaaki Shin
    • C08G18/42G03G9/087
    • C08G18/4202G03G9/08764
    • A resin for toner of electrophotography comprises a urethane-modified polyester resin (D) having a glass transition temperature ranging from 40.degree. to 75.degree. C., which is obtained by reacting a resin mixture composed of a polyester resin (A) having a number-averaging molecular weight of 1,000 to 15,000 and a hydroxyl value of 10 to 100 and a polyester resin (B) having a number-average molecular weight ranging from 1,000 to 5,000 and a sum of acid value and hydroxyl value of less than 10, in a weight ratio of (A)/(B) ranging from 20:80 to 60:40, with 0.3 to 0.99 molar equivalent of an isocyanate compound (C) per one molar equivalent of hydroxyl group of the polyester resin (A).The resin for toner is excellent in grindability and storage stability and it provides toners for electrophotography having good anti-blocking properties and good fixing properties whereby good images free of fogging can be obtained.
    • 用于电子照相调色剂的树脂包括玻璃化转变温度为40-75℃的聚氨酯改性聚酯树脂(D),其通过使具有数量的聚酯树脂(A)组成的树脂混合物 分子量为1000〜15000,羟基值为10〜100,数均分子量为1,000〜5000,酸值与羟值的和小于10的聚酯树脂(B)在 (A)/(B)的重量比为20:80至60:40,每摩尔当量的聚酯树脂(A)的羟基为0.3至0.99摩尔当量的异氰酸酯化合物(C)。 用于调色剂的树脂具有优异的可研磨性和储存稳定性,并且提供了具有良好的防粘连性和良好的定影性的电子照相用调色剂,从而可以获得没有起雾的良好图像。