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1. 发明授权

US06180175B2 Coating composition 失效
标题翻译：涂料组成
公开(公告)号：US06180175B2
公开(公告)日：2001-01-30
申请号：US09177082
申请日：1998-10-23
申请人： Masaaki Saika , Yoshiyuki Yukawa , Motoshi Yabuta , Seiji Wada , Kohsuke Noura , Yasumasa Okumura
发明人： Masaaki Saika , Yoshiyuki Yukawa , Motoshi Yabuta , Seiji Wada , Kohsuke Noura , Yasumasa Okumura
IPC分类号： B05D302
CPC分类号： B05D7/532 , C08G18/4063 , C08G18/6295 , C08G18/73 , C08G18/771 , C09D175/04
摘要： There is disclosed a novel organic solvent type coating composition capable of making the solid content concentration at the time of coating to higher than 70% by weight, without lowering the properties, which urethane type coating materials have, such as acid resistance, scratch resistance, finishing appearance etc. The composition comprises (A) a vinyl type polymer having both hydroxyl groups and alkoxysilyl groups in the molecule and having a number-average molecular weight in a range of 2,000 to 10,000; (B) a polyol compound having a number-average molecular weight of less than 1,000 and having a hydroxyl value in a range of 120 to 1,000 mgKOH/g; (C) a polyisocyanate compound having a number-average molecular weight of less than 2,000; and (D) a silanol group forming catalyst.
摘要翻译：公开了一种新型的有机溶剂型涂料组合物，其能够使涂布时的固体成分浓度高于70重量％，而不降低聚氨酯类涂料具有的耐酸性，耐刮擦性，整理外观等。该组合物包含（A）分子中具有羟基和烷氧基甲硅烷基的乙烯基类聚合物，数均分子量在2,000〜10,000的范围内; （B）数均分子量小于1000且羟基值在120〜1000mgKOH / g范围内的多元醇化合物; （C）数均分子量小于2,000的多异氰酸酯化合物; 和（D）形成硅烷醇基团的催化剂。

2. 发明授权

US6045870A High solid coating composition and method for forming topcoat using same 失效
标题翻译：高固体涂料组合物和使用其形成面漆的方法
公开(公告)号：US6045870A
公开(公告)日：2000-04-04
申请号：US145427
申请日：1998-09-01
申请人： Kohsuke Noura , Yoshiyuki Yukawa , Masaaki Saika , Motoshi Yabuta , Yasumasa Okumura
发明人： Kohsuke Noura , Yoshiyuki Yukawa , Masaaki Saika , Motoshi Yabuta , Yasumasa Okumura
IPC分类号： C09D143/04 , C09D201/08 , B05D3/02
CPC分类号： C09D201/08 , C09D143/04 , C08L2205/18
摘要： An organic solvent-based heat-curable high solid coating composition comprising:(A) a carboxyl-containing compound having an acid value of 50 to 500 mg KOH/g wherein 20 mol % or more of the carboxyl groups are silylated carboxyl groups,(B) at least one epoxide selected from (B-1) an epoxy-, hydroxyl- and hydrolyzable alkoxysilyl-containing vinyl polymer, (B-2) the vinyl polymer (B-1) wherein 20 mol % or more of the hydroxyl groups are silylated hydroxyl groups, and (B-3) an epoxy compound having a number average molecular weight less than 1,000, and(C) a crosslinked particulate polymer,the composition having a solid content of 65 wt. % or more; and a method for forming a topcoat using the composition. The composition of the invention has a sufficiently high solid content, is capable of forming a coating film with high resistance to acids and the like, and is excellent in low-temperature curability, storage stability and recoat adhesion.
摘要翻译：一种有机溶剂型可热固化高固体涂料组合物，其包含：（A）酸值为50〜500mgKOH / g的含羧基化合物，其中20摩尔％以上的羧基为甲硅烷基化羧基（ B）至少一种选自（B-1）环氧基，羟基和可水解的含烷氧基甲硅烷基的乙烯基聚合物的环氧化物，（B-2）乙烯基聚合物（B-1），其中20mol％或更多的羟基是（甲基）丙烯酸羟基，和（B-3）数均分子量小于1000的环氧化合物，和（C）交联的颗粒聚合物，该组合物的固含量为65重量％％或者更多; 以及使用该组合物形成面漆的方法。本发明的组合物具有足够高的固体含量，能够形成具有高耐酸性等的涂膜，并且具有优异的低温固化性，储存稳定性和重涂性。

3. 发明授权

US5719234A High solid coating composition and method for forming topcoat using same 失效
标题翻译：高固体涂料组合物和使用其形成面漆的方法
公开(公告)号：US5719234A
公开(公告)日：1998-02-17
申请号：US747341
申请日：1996-11-12
申请人： Motoshi Yabuta , Masaaki Saika , Satoru Ito , Hiroyuki Okada , Yasumasa Okumura , Hiroshi Igarashi , Satoshi Ikushima
发明人： Motoshi Yabuta , Masaaki Saika , Satoru Ito , Hiroyuki Okada , Yasumasa Okumura , Hiroshi Igarashi , Satoshi Ikushima
IPC分类号： B05D1/36 , B05D7/00 , C08L43/04 , C08L83/04 , C09D133/06 , C09D137/00 , C09D143/04 , C09D163/00 , C09D183/04 , C09D201/08
CPC分类号： B05D7/532 , C09D133/064 , C09D143/04 , C09D201/08 , C08L2205/18 , C08L43/04 , C08L83/04 , Y10T428/2949 , Y10T428/2958 , Y10T428/31663
摘要： An object of the present invention is to provide a heat-curable high solid coating composition capable of forming a coating film which is excellent in both acid resistance and scratch resistance, and a method for forming a topcoat using said composition. The present invention provides a heat-curable high solid coating composition comprising: (A) a carboxyl-containing compound, (B) a vinyl polymer having an epoxy group, a hydroxyl group and a hydrolyzable alkoxysilyl group in one molecule, (C) a reactive organopolysiloxane, and (D) a crosslinked particulate polymer. The present invention also provides a method for forming a topcoat using said composition.
摘要翻译：本发明的目的是提供一种能够形成耐酸性和耐划伤性优异的涂膜的热固性高固体涂料组合物，以及使用该组合物形成面漆的方法。本发明提供一种热固性高固体涂料组合物，其包含：（A）含羧基化合物，（B）一分子中具有环氧基，羟基和可水解烷氧基甲硅烷基的乙烯基聚合物，（C）反应性有机聚硅氧烷，（D）交联的颗粒聚合物。本发明还提供了使用所述组合物形成面漆的方法。

4. 发明授权

US06261642B1 High-solids coating composition and method for forming topcoat using the same 失效
标题翻译：高固含量涂料组合物和使用其形成面漆的方法
公开(公告)号：US06261642B1
公开(公告)日：2001-07-17
申请号：US09462383
申请日：2000-01-07
申请人： Kenichi Nagai , Masaaki Saika , Haruhiko Aida , Motoshi Yabuta , Hiroshi Igarashi , Yasumasa Okumura
发明人： Kenichi Nagai , Masaaki Saika , Haruhiko Aida , Motoshi Yabuta , Hiroshi Igarashi , Yasumasa Okumura
IPC分类号： B05D136
CPC分类号： C09D151/003 , C08F265/04 , C08F283/12 , C08L33/066 , C09D143/04 , C09D167/00 , Y10T428/31663 , Y10T428/31678 , C08L2666/04 , C08L2666/28 , C08L2666/02 , C08L2666/10
摘要： This invention provides a thermosetting high solids coating composition comprising: (A) a copolymer prepared by polymerizing monomer components comprising (a) 30 to 50 wt. % of vinyltrimethoxysilane and/or vinyltriethoxysilane, (b) 5 to 15 wt. % of N-methylol(meth)acrylamide alkyl ether and (c) 35 to 65 wt. % of another polymerizable unsaturated monomer, (B) a hydroxyl-containing resin having a hydroxyl value of 10 to 200 mg KOH/g, and (C) a curing catalyst. This invention further provides a method for forming a topcoat using said composition. The composition of the invention achieves the following remarkable effects: it forms a coating film excellent in acid resistance and scratch resistance, and it is superior in storage stability and recoat adhesion.
摘要翻译：本发明提供了一种热固性高固体涂料组合物，其包含：（A）通过聚合单体组分制备的共聚物，所述单体组分包含（a）30至50重量％％的乙烯基三甲氧基硅烷和/或乙烯基三乙氧基硅烷，（b）5〜15wt。％的N-羟甲基（甲基）丙烯酰胺烷基醚和（c）35-65重量％％的另一种可聚合不饱和单体，（B）羟基值为10-200mg KOH / g的羟基树脂，（C）固化催化剂。本发明还提供了一种使用所述组合物形成面漆的方法。本发明的组合物具有以下显着效果：形成耐酸性和耐刮擦性优异的涂膜，其保存稳定性和再涂覆性优异。

5. 发明授权

US06214418B1 Thermosetting, high-solids coating composition and method of forming topcoat by using the same 失效
标题翻译：热固性，高固含量涂料组合物及使用其形成面漆的方法
公开(公告)号：US06214418B1
公开(公告)日：2001-04-10
申请号：US09462839
申请日：2000-01-14
申请人： Hiroshi Igarashi , Hiroshi Kitagawa , Yasumasa Okumura , Masaaki Saika , Kenichi Nagai , Motoshi Yabuta
发明人： Hiroshi Igarashi , Hiroshi Kitagawa , Yasumasa Okumura , Masaaki Saika , Kenichi Nagai , Motoshi Yabuta
IPC分类号： B05D136
CPC分类号： C09D143/04 , C08G59/42 , C08G59/4261 , C08L33/068 , C08L63/00 , C09D163/00 , Y10T428/31663 , Y10T428/31678 , C08L2666/04 , C08L2666/28 , C08L2666/14
摘要： The present invention provides a thermosetting high solids coating composition comprising (A) a carboxyl-containing compound, (B) a polyepoxide, and (C) a copolymer prepared by polymerizing monomer components comprising (a) 30 to 50% by weight of vinyltrimethoxysilane and/or vinyltriethoxysilane, (b) 5 to 15% by weight of N-methylol(meth)acrylamide alkyl ether, and (c) 35 to 65% by weight of another polymerizable unsaturated monomer, and a method for forming a topcoat using said composition. The composition of the present invention is highly effective in forming a coating film excellent in resistance to both acids and scratch, and is superior in storage stability and recoat adhesion.
摘要翻译：本发明提供一种热固性高固体涂料组合物，其包含（A）含羧基化合物，（B）聚环氧化物，和（C）通过聚合单体组分制备的共聚物，所述共聚物包含（a）30至50重量％的乙烯基三甲氧基硅烷和 /或乙烯基三乙氧基硅烷，（b）5〜15重量％的N-羟甲基（甲基）丙烯酰胺烷基醚，和（c）35〜65重量％的其他可聚不饱和单体，以及使用所述组合物形成面漆的方法。本发明的组合物在形成耐酸性和耐刮擦性优异的涂膜方面非常有效，并且具有优异的储存稳定性和重涂性。

6. 发明授权

US5889115A Curable coating composition and method of forming a top coat 失效
标题翻译：可固化涂料组合物和形成顶涂层的方法
公开(公告)号：US5889115A
公开(公告)日：1999-03-30
申请号：US595397
申请日：1996-02-01
申请人： Motoshi Yabuta , Masaaki Saika , Yasushi Nakao , Hiroshi Igarashi , Satoshi Ikushima
发明人： Motoshi Yabuta , Masaaki Saika , Yasushi Nakao , Hiroshi Igarashi , Satoshi Ikushima
IPC分类号： B05D1/36 , B05D7/00 , C08G59/20 , C08G59/32 , C08L33/06 , C08L43/04 , C08L63/00 , C09D133/04 , C09D133/06 , C09D133/14 , C09D137/00 , C09D143/04 , C09D163/00 , C08L37/00
CPC分类号： B05D7/532 , C09D133/068 , C09D143/04 , C08L33/064 , C08L33/068 , C08L43/04
摘要： The invention provides a curable coating composition comprising:(a) a vinyl polymer having, in one molecule, (i) a group formed by half esterification of an acid anhydride group and (ii) a primary hydroxyl group,(b) a vinyl polymer having an epoxy group and a primary hydroxyl group in one molecule, and(c) a vinyl polymer having an ethoxysilyl group and a secondary hydroxyl group in one molecule, and a method of forming a top coat using said composition.
摘要翻译：本发明提供一种可固化涂料组合物，其包含：（a）乙烯基聚合物，其在一个分子中具有（i）通过酸酐基团半酯化和（ii）伯羟基形成的基团，（b）乙烯基聚合物在一个分子中具有环氧基和伯羟基，和（c）在一个分子中具有乙氧基甲硅烷基和次羟基的乙烯基聚合物，以及使用所述组合物形成面漆的方法。

7. 发明申请

US20120238667A1 CHIPPING-RESISTANT COATING COMPOSITION 审中-公开
标题翻译：耐旋涂涂料组合物
公开(公告)号：US20120238667A1
公开(公告)日：2012-09-20
申请号：US13512390
申请日：2010-12-01
申请人： Kouta Gotou , Masaaki Saika , Hironori Tonomura
发明人： Kouta Gotou , Masaaki Saika , Hironori Tonomura
IPC分类号： C09D175/12 , C09D163/00
CPC分类号： C08G18/4854 , C08G18/0823 , C08G18/3853 , C08G18/42 , C08G18/44 , C08G18/4833 , C08G18/6692 , C08G18/73 , C08G18/755 , C08G18/758 , C08G18/7621 , C08G18/792 , C08G18/8077 , C08G18/8093 , C08L61/28 , C09D175/04 , C08L2666/16
摘要： The present invention provides a chipping-resistant coating composition including a hydroxyl group-containing urethane resin (A) obtained by reacting a polyol component (a) composed of a cyclic polyol compound (a1) having a nurate structure and another polyol compound (a2) with a polyisocyanate compound (b), and a curing agent (B). This chipping-resistant coating composition is capable of forming a coated film excellent in chipping resistance and water resistance. Furthermore, the present invention also provides an article coated with the chipping-resistant coating composition.
摘要翻译：本发明提供一种耐崩裂性涂料组合物，其包含通过使由具有培养结构的环状多元醇化合物（a1）构成的多元醇成分（a）和多元醇化合物（a2）反应得到的含羟基的聚氨酯树脂（A）与多异氰酸酯化合物（b）和固化剂（B）。这种耐崩裂涂料组合物能够形成耐崩裂性和耐水性优异的涂膜。此外，本发明还提供了涂有耐崩裂涂料组合物的制品。

8. 发明申请

US20070283852A1 Coating composition for cans 失效
标题翻译：罐头涂料组合物
公开(公告)号：US20070283852A1
公开(公告)日：2007-12-13
申请号：US11727176
申请日：2007-03-23
申请人： Masaaki Saika , Hideki Matsuda , Yuuichi Inada , Naoki Horike , Sumio Noda , Hideki Masuda , Keiichi Shimizu , Hiromi Harakawa
发明人： Masaaki Saika , Hideki Matsuda , Yuuichi Inada , Naoki Horike , Sumio Noda , Hideki Masuda , Keiichi Shimizu , Hiromi Harakawa
IPC分类号： C08F20/32
CPC分类号： C08G59/1461 , C08K3/30 , C08L33/064 , C08L63/00 , C09D5/024 , C09D7/43 , C09D7/65 , C09D7/67 , C09D7/68 , C09D151/08 , C09D163/00 , C08L2666/02 , C08L2666/04
摘要： The present invention provides a coating composition for cans comprising 100 parts by mass of a neutralized acrylic resin-modified epoxy resin (A), and from 1 to 50 parts by mass of anionic polymer crosslinked fine particles (B), (A) and (B) being dispersed in an aqueous medium, wherein the anionic polymer fine particles (B) are polymer fine particles comprising a polymer having an acid value of from 10 to 120 mg KOH/g and being produced by polymerizing radically polymerizable unsaturated monomers comprising from 2 to 30% by mass of a carboxyl group-containing radically polymerizable unsaturated monomer (b1), from 2 to 30% by mass of a polyvinyl compound (b2) and from 40 to 96% by mass of other radically polymerizable unsaturated monomer (b3) in the presence of water.
摘要翻译：本发明提供一种罐装用涂料组合物，其包含100质量份中和的丙烯酸树脂改性环氧树脂（A）和1至50质量份阴离子聚合物交联的细颗粒（B），（A）和（ B）分散在水性介质中，其中阴离子聚合物细颗粒（B）是包含酸值为10至120mg KOH / g的聚合物的聚合物细颗粒，并且通过聚合自由基聚合的不饱和单体制备，包含2 〜30质量％的含羧基的自由基聚合性不饱和单体（b1），2-30质量％的聚乙烯基化合物（b2）和40〜96质量％的其他自由基聚合性不饱和单体（b3）在水的存在下。

9. 发明申请

US20070155917A1 Curable resin composition 失效
标题翻译：可固化树脂组合物
公开(公告)号：US20070155917A1
公开(公告)日：2007-07-05
申请号：US11607003
申请日：2006-12-01
申请人： Hideyuki Yamada , Masaaki Saika , Hideo Sugai
发明人： Hideyuki Yamada , Masaaki Saika , Hideo Sugai
IPC分类号： C08L63/00 , B32B27/38
CPC分类号： C08G59/4261 , C08F8/12 , C08F2800/20 , C08G59/3209 , C08L33/02 , C08L33/062 , C08L33/068 , C08L33/14 , C08L63/00 , C09D163/00 , C08L2666/04 , C08L33/00 , C08F2220/1825
摘要： The present invention provides a curable resin composition comprising: (A) an acryl resin having (a) a carboxyl group originating in a carboxyl group-containing polymerizable unsaturated monomer selected from acrylic acid, methacrylic acid, maleic acid and itaconic acid and (b) a carboxyl group originating in a carboxyl group-containing polymerizable unsaturated monomer having a polymerizable carbon-carbon double bond and a carboxyl group separated from the double bond by at least 6 carbon atoms, (B) an epoxy group-containing acryl resin and (C) a curing catalyst.
摘要翻译：本发明提供一种固化性树脂组合物，其含有：（A）丙烯酸树脂，其具有（a）来源于选自丙烯酸，甲基丙烯酸，马来酸和衣康酸的含羧基的聚合性不饱和单体的羧基，（b）来源于具有可聚合碳 - 碳双键的羧基基团和从双键至少分离6个碳原子的羧基的羧基，（B）含环氧基的丙烯酸树脂和（C ）固化催化剂。

10. 发明授权

US07935764B2 Composition of carboxyl acryl resin and epoxy acryl resin 失效
标题翻译：羧基丙烯酸树脂和环氧丙烯酸树脂的组成
公开(公告)号：US07935764B2
公开(公告)日：2011-05-03
申请号：US11607003
申请日：2006-12-01
申请人： Hideyuki Yamada , Masaaki Saika , Hideo Sugai
发明人： Hideyuki Yamada , Masaaki Saika , Hideo Sugai
IPC分类号： C08L33/02 , C08L33/14
CPC分类号： C08G59/4261 , C08F8/12 , C08F2800/20 , C08G59/3209 , C08L33/02 , C08L33/062 , C08L33/068 , C08L33/14 , C08L63/00 , C09D163/00 , C08L2666/04 , C08L33/00 , C08F2220/1825
摘要： The present invention provides a curable resin composition comprising: (A) an acryl resin having (a) a carboxyl group originating in a carboxyl group-containing polymerizable unsaturated monomer selected from acrylic acid, methacrylic acid, maleic acid and itaconic acid and (b) a carboxyl group originating in a carboxyl group-containing polymerizable unsaturated monomer having a polymerizable carbon-carbon double bond and a carboxyl group separated from the double bond by at least 6 carbon atoms, (B) an epoxy group-containing acryl resin and (C) a curing catalyst.
摘要翻译：本发明提供一种固化性树脂组合物，其含有：（A）丙烯酸树脂，其具有（a）来源于选自丙烯酸，甲基丙烯酸，马来酸和衣康酸的含羧基的聚合性不饱和单体的羧基，（b）来源于具有可聚合碳 - 碳双键的羧基基团和从双键至少分离6个碳原子的羧基的羧基，（B）含环氧基的丙烯酸树脂和（C ）固化催化剂。

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