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    • 3. 发明申请
    • Method For Producing Chlorine
    • 氯生产方法
    • US20080159948A1
    • 2008-07-03
    • US11816045
    • 2006-02-20
    • Martin SesingArmin DiefenbacherHartwig VossOlga SchubertLothar SeidemannMartin KarchesThomas GrasslerEckhard Stroefer
    • Martin SesingArmin DiefenbacherHartwig VossOlga SchubertLothar SeidemannMartin KarchesThomas GrasslerEckhard Stroefer
    • C01B7/04
    • C01B7/075C01B7/04C01B7/0743
    • Process for preparing chlorine from hydrogen chloride, which comprises the steps: a) feeding of a stream a1 comprising hydrogen chloride and of a stream a2 comprising oxygen into an oxidation zone and catalytic oxidation of hydrogen chloride to chlorine, giving a product gas stream a3 comprising chlorine, water, oxygen, carbon dioxide and inert gases; b) cooling of the product gas stream a3 and removal of water and hydrogen chloride as aqueous hydrochloric acid, leaving a gas stream b comprising chlorine, water, oxygen, carbon dioxide and inert gases; c) optional drying of the gas stream b) to leave a gas stream c which is substantially free of water and comprises chlorine, oxygen, carbon dioxide and inert gases; d) at least partial liquefaction of the gas stream c and of a chlorine-rich recycle stream f1 comprising chlorine, oxygen and carbon dioxide by compression and cooling, giving an at least partially liquefied stream d; e) gas/liquid separation of the stream d into a gas stream e1 comprising chlorine, oxygen, carbon dioxide and inert gases and into a liquid stream e2 comprising chlorine, oxygen and carbon dioxide; f) feeding of at least part of the gas stream e1 into a membrane separation unit and fractionation by membrane separation to give the chlorine-rich recycle stream f1 and a gas stream f2 which is low in chlorine and comprises chlorine, oxygen and carbon dioxide and recirculation of the chlorine-rich recycle stream f1 to step d); g) separation of the liquid stream e2 by distillation into a chlorine stream g1 and a stream g2 comprising essentially oxygen and carbon dioxide.
    • 从氯化氢制备氯的方法,其包括以下步骤:a)将包含氯化氢的物流1和包含氧的物流2加入氧化区并将氯化氢催化氧化成氯,得到产物气流 a 3,包括氯,水,氧,二氧化碳和惰性气体; b)冷却产物气流a 3,除去水和氯化氢作为盐酸水溶液,留下包含氯,水,氧气,二氧化碳和惰性气体的气流b; c)气流的任选干燥b)留下基本上不含水的气流c,包括氯,氧,二氧化碳和惰性气体; d)通过压缩和冷却至少部分液化气流c和包含氯,氧和二氧化碳的富含氯的循环流f 1,产生至少部分液化的流d; e)将气流d气体/液体分离成包含氯气,氧气,二氧化碳和惰性气体的气流e 1并进入包含氯​​气,氧气和二氧化碳的液体流e 2中; f)将至少部分气流e 1进料到膜分离单元中并通过膜分离进行分馏,得到富氯循环流f 1和氯含量低的气流f 2,包括氯,氧和 二氧化碳和富氯循环流f 1再循环到步骤d); g)通过蒸馏将液体流e 2分离成氯流g 1和基本上包含氧和二氧化碳的流g 2。
    • 10. 发明授权
    • Preparation of benzaldehyde dialkyl acetals
    • 制备苯甲醛二烷基缩醛
    • US5507922A
    • 1996-04-16
    • US289277
    • 1994-08-11
    • Dieter HermelingHeinz HannebaumHartwig VossAndreas Weiper-Idelmann
    • Dieter HermelingHeinz HannebaumHartwig VossAndreas Weiper-Idelmann
    • C07C41/50C07C43/307C25B3/02
    • C25B3/02
    • Benzaldehyde dialkyl acetals of the general formula I ##STR1## where R.sup.1 is C.sub.1 -C.sub.6 -alkyl, R.sup.2 is C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, halogen, cyano or carboxyalkyl where the alkyl group is of 1 to 6 carbon atoms, n is an integer of from 1 to 3 and the radicals R.sup.2 may be identical or different when n is >1, are prepared by electrochemical oxidation of a substituted toluene compound of the general formula II ##STR2## by a process in which a substituted toluene compound II is oxidized in the presence of an alkanol R.sup.1 --OH and of an auxiliary electrolyte in an electrolysis cell, the reaction solution thus obtained is let down outside the electrolysis cell to a pressure which is from 10 mbar to 10 bar lower than the pressure in the electrolysis cell andA) in the batchwise procedure, the gas released from the reaction solution on letting down the latter is separated off and the reaction solution is recycled at least once to the electrolysis cell, subjected to electrolysis, let down, separated from the released gas and then worked up to obtain the product, orB) in the continuous procedure, some of the reaction solution is worked up to obtain the product and the remaining part of the reaction solution is mixed with an amount of the originally used reaction solution which corresponds to the part removed and is recycled to the electrolysis cell, subjected to electrolysis and let down.
    • 其中R 1是C 1 -C 6烷基,R 2是C 1 -C 6烷基,C 1 -C 6烷氧基,卤素,氰基或羧基烷基的苯甲醛二烷基缩醛,其中烷基是1至6碳 原子,n为1〜3的整数,并且当n> 1时,基团R2可以相同或不同,是通过以下方法制备的,通过以下方法制备通式II II的取代的甲苯化合物:其中 取代的甲苯化合物II在电解槽中在烷醇R1-OH和辅助电解质的存在下被氧化,将由此获得的反应溶液在电解槽内排出至10mbar至10bar以下的压力 比电解池中的压力和A)在分批程序中,将从反应溶液中释放的气体释放出来,将反应溶液再循环至少一次至电解槽,进行电解,放电 与...分开 释放气体,然后处理以获得产物,或B)在连续步骤中,处理一些反应溶液以获得产物,并将剩余部分的反应溶液与一定量的最初使用的反应溶液 其对应于去除的部分并且被再循环到电解槽中,进行电解和放电。