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    • 1. 发明申请
    • Cyclic compounds and the use thereof as light absorbers, light emitters, or complex ligands
    • 环化合物及其作为光吸收剂,光发射体或复合配体的用途
    • US20050167637A1
    • 2005-08-04
    • US10509944
    • 2003-04-04
    • Martin KonemannThomas GessnerRudiger SensChristian LennartzGunther Seybold
    • Martin KonemannThomas GessnerRudiger SensChristian LennartzGunther Seybold
    • A61K8/00A61K8/49A61Q17/04B01J31/02B01J31/18B01J31/22C07B61/00C07D487/22C07D498/22C07D513/22C08K5/3417C09B57/00C09B67/46C09D7/12C09D201/00C09K11/06C09K15/16
    • C09B67/0085A61K8/19A61K8/49A61K8/4946A61K2800/58A61Q17/04B01J31/0235B01J31/183B01J2231/70B01J2531/62B01J2531/821B01J2531/842B01J2531/845B01J2531/98C07D487/22C07D498/22C07D513/22
    • The use of cyclic compounds of the formula (I) where n is a number in the range from 1 to 7, X-Y-Z, in each case independently of one another, is O—C═N, N═C—O, NR5—C═N, N═C—NR5, N+R52—C═N, N═C—N+R52, O—C═N+R5, N+R5═C—O, S—C═N+R5, N+R5═C—S, S—C═N, N═C—S, R1, R2 and R3 each independently are, for example, H or a substituent or corresponding heterocyclic compounds in which at least one group —CR1═, —CR2═, CR3═ is replaced by —N, R5 in each case independently are, for example, H or a substituent R7, in each case independently of one another, are H, C1-12-alkyl or C6-12-aryl, or metal complexes of the cyclic compounds or complexes of the cyclic compounds with mineral acids, chloride, sulfate, bisulfate, phosphate, hydrogen phosphate, nitrate, BF4− or methanesulfonate being present as opposite ions X− in the case of cationic cyclic structures, as light absorbers, materials for hole injection layers in OLEDs, light-emitting compounds in OLED, phase-transfer catalysts or synergistic agents for the dispersing of pigments or for optical data storage, is described.
    • 使用式(I)的环状化合物,其中n为1至7的数,XYZ在每种情况下彼此独立地为OCN,NCO,NR 5 -CN ,NC-NR 5,N + 5,...,5,...,...,N N + > 5 5 2,...,... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... > 5-CO,SCN +,...,5,...,...,...,... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ,NCS,R 1,R 2和R 3各自独立地为例如H或取代基或相应的杂环化合物,其中在 至少一个基团-CR 1, - CR 2 - , - CR 3 - 被-N,R 5, 在每种情况下,各自独立地是H或取代基R 7,在每种情况下彼此独立地为H,C 1-12 - 烷基或 C 6-12芳基或环状化合物的金属络合物或环状化合物与无机酸,氯化物,硫酸盐,硫酸氢盐,磷酸盐的络合物 在阳离子环状结构的情况下,作为阳离子环状结构存在,作为相反离子存在的磷酸根,硝酸根,BF 4 - 或 - 甲磺酸盐作为光 吸收剂,OLED中的空穴注入层的材料,OLED中的发光化合物,相转移催化剂或用于颜料分散或光学数据存储的协同剂。
    • 3. 发明申请
    • Compounds Comprising 2,6-Naphthyl Groups
    • US20080221289A1
    • 2008-09-11
    • US11914365
    • 2006-05-10
    • Olivier EngerRudiger SensChristian LennartzRobert Parker
    • Olivier EngerRudiger SensChristian LennartzRobert Parker
    • C08F28/02C07C69/76C08F122/10
    • C09K19/322
    • The present invention relates to compounds of the general formula I in which the variables are each defined as follows: Z1, Z2 are each independently hydrogen, optionally substituted C1-C20-alkyl in which the carbon chain may be interrupted by oxygen atoms in ether function, sulfur atoms in thioether function or by nonadjacent imino or C1-C4-alkylimino groups, or reactive radicals by means of which polymerization can be brought about, A1, A2 are each independently spacers having from 1 to 30 carbon atoms, in which the carbon chain may be interrupted by oxygen atoms in ether function, sulfur atoms in thioether function or by nonadjacent imino or C1-C4-alkylimino groups, Y1, Y2 are each independently a chemical single bond, oxygen, sulfur, —CO—, —O—CO—, —CO—O—, —S—CO—, —CO—S—, —NR—CO— or —CO—NR—, Y3, Y4 are each independently a chemical single bond, oxygen, sulfur, —CR═CR—, —C≡C—, —CR═CR—CO—O—, —O—CO—CR═CR—, —C≡C—O—, —O—C≡C—, —CH2—CH2—, —CH2—O—, —O—CH2—, —CH2—S—, —S—CH2—, —CO—, —O—CO—, —CO—O—, —S—CO—, —CO—S—, —NR—CO—, —CO—NR—, —O—CO—O—, —O—CO—NR— or —NR—CO—O—, R is hydrogen or C1-C4-alkyl, Y5 independently of Y1 and Y2, is as defined therefor above or is —O—COO—, T1, T2 are divalent saturated or unsaturated, optionally substituted iso- or heterocyclic radicals, r, t are each independently 0 or 1  and s is 0, 1, 2 or 3, where the particular variables T2 and Y3, in the case that s>1, may be the same as one another or different from one another and both the hydrogen atoms in the 2,6-naphthyl radical and the hydrogen atoms bonded to carbon atoms in the variables Z1, Z2, A1, A2, Y3, Y4, R, T1 and T2 may be substituted partly or fully by halogen atoms. The invention further relates to a polymerizable or nonpolymerizable liquid-crystalline composition comprising one or more of the inventive compounds, to an oligomer or polymer obtainable by oligomerization or polymerization of a polymerizable inventive liquid-crystalline composition, to a process for printing or coating a substrate by applying a polymerizable inventive liquid-crystalline composition to the substrate and subsequent polymerization, to the use of the inventive liquid-crystalline composition or of the inventive oligomer or polymer for producing optical or electrooptical components, to a process for preparing selected inventive compounds, and to intermediates which are particularly suitable for preparing the selected inventive compounds.
    • 10. 发明授权
    • Naphtholactam dyes
    • 萘酚内酰胺染料
    • US5929245A
    • 1999-07-27
    • US776596
    • 1997-02-18
    • Clemens GrundErnst SchefczikGunther LammRoland MergerRudiger Sens
    • Clemens GrundErnst SchefczikGunther LammRoland MergerRudiger Sens
    • C07D401/04C07D495/04C07D495/06C09B57/00C09B57/06
    • C07D401/04C07D495/06C09B57/06
    • The invention concerns naphtholactam derivatives of formula (I), in which: R.sup.1 represents hydrogen, optionally substituted C.sub.1 -C.sub.6 alkyl C.sub.5 -C.sub.6 cycloalkcyl or substituted phenyl; R.sup.2 and R.sup.3 represent hydrogen, C.sub.1 -C.sub.8 alkanoyl, optionally substituted benzoyl, optionally substituted C.sub.2 -C.sub.4 alkyl, optionally substituted C.sub.2 -C.sub.4 alkenyl, optionally substituted C.sub.2 -C.sub.4 alkinyl, a halogen, nitro, sulphamoyl, optionally substituted hydroxy, optionally substituted mercapto, C.sub.1 -C.sub.6 alkysulphonyl or optionally substituted phenylsulphonyl; R.sup.4 represents hydrogen or, with R.sup.3, a group of formula (II); R.sup.5 represents hydrogen or C.sub.1 -C.sub.6 alkyl; R.sup.6 represents cyano, carbamoyl, C.sub.1 -C.sub.4 mono- or dialkylcarbamoyl carboxyl or C.sub.1 -C.sub.4 alkoxycarbonyl; and R.sup.7 represents substituted C.sub.1 -C.sub.4 alkyl, optionally substituted C.sub.5 -C.sub.13 alkyl or benzoyl. Also disclosed is the use of these derivatives for dyeing or printing textiles.
    • PCT No.PCT / EP95 / 03112 Sec。 371日期1997年2月18日 102(e)日期1997年2月18日PCT提交1995年8月4日PCT公布。 公开号WO96 / 06137 日期:1996年2月29日本发明涉及式(I)的萘内酰胺衍生物,其中:R 1表示氢,任选取代的C 1 -C 6烷基C 5 -C 6环烷基或取代的苯基; R 2和R 3表示氢,C 1 -C 8烷酰基,任选取代的苯甲酰基,任选取代的C 2 -C 4烷基,任选取代的C 2 -C 4烯基,任选取代的C 2 -C 4炔基,卤素,硝基,氨磺酰基,任选取代的羟基,任选取代的巯基 ,C 1 -C 6烷磺酰基或任选取代的苯基磺酰基; R4表示氢,或与R3表示式(Ⅱ)的基团。 R5表示氢或C1-C6烷基; R6表示氰基,氨基甲酰基,C1-C4单或二烷基氨基甲酰基羧基或C1-C4烷氧基羰基; 并且R 7表示取代的C 1 -C 4烷基,任选取代的C 5 -C 13烷基或苯甲酰基。 还公开了这些衍生物用于染色或印花纺织品的用途。