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    • 5. 发明授权
    • Method of forming thermoplastic foams using cell size enlarging agents
    • 使用细胞尺寸扩大剂形成热塑性泡沫的方法
    • US5489407A
    • 1996-02-06
    • US278283
    • 1994-07-21
    • Kyung W. SuhMasayuki WakabayashiChau V. VoAndrew N. Paquet
    • Kyung W. SuhMasayuki WakabayashiChau V. VoAndrew N. Paquet
    • C08J9/04C08J9/00B29C44/20
    • C08J9/0014Y10S264/13
    • A process for making a closed-cell, alkenyl aromatic polymer foam structure having enlarged cell size. An alkenyl aromatic polymer material is heated to form a melt polymer material. An amount of a non-waxy cell size enlarging agent is incorporated into the melt polymer material. The enlarging agent is present in an amount sufficient to enlarge the stabilized cell size of the formed foam structure by 20 percent or more over a corresponding foam structure made without the enlarging agent. Further, the enlarging agent is incorporated in a quantity such that the formed foam structure has physical properties substantially the same degree as the corresponding foam structure. A blowing agent is incorporated into the melt polymer material at an elevated pressure to form a foamable gel. The foamable gel is expanded in a zone of lower pressure to form the foam structure. Further, disclosed is a foam structure corresponding to the above.
    • 一种制备具有增大的孔尺寸的闭孔,链烯基芳族聚合物泡沫结构的方法。 将烯基芳族聚合物材料加热以形成熔融聚合物材料。 将一定量的非蜡状细胞尺寸扩大剂掺入熔融聚合物材料中。 增容剂的存在量足以使所形成的泡沫结构体的稳定的细胞尺寸在不含放大剂的相应的泡沫结构上扩大20%或更多。 此外,扩大剂的掺入量使得所形成的泡沫结构的物理性质与相应的泡沫结构基本相同。 将发泡剂在升高的压力下加入到熔融聚合物材料中以形成可发泡凝胶。 可发泡凝胶在较低压力的区域内膨胀以形成泡沫结构。 此外,公开了对应于上述的泡沫结构。
    • 6. 发明授权
    • Flexible bimodal foam structures
    • 柔性双峰泡沫结构
    • US5332761A
    • 1994-07-26
    • US161946
    • 1993-12-03
    • Andrew N. PaquetKyung W. Suh
    • Andrew N. PaquetKyung W. Suh
    • C08J9/12
    • C08J9/127C08J2203/12C08J2325/04
    • Disclosed is a flexibilized, insulative styrenic polymer foam structure comprising a foam of a polymeric composition of a styrenic polymer greater than 50 percent by weight styrenic monomeric units, the foam having relatively larger primary cells with an average cell size range of about 0.05 to about 1.2 millimeters and relatively smaller secondary cells ranging in cell size from about 5 percent to about 50 percent of the average cell size of the primary cells. The primary and secondary cells constitute at least about 90 percent of the total cell volume within the foam structure. Between 1 and 30 percent by number of the cells have microscopic "pinholes" between them. The presence of the pinholes enhances the flexure of the foam structure. Further disclosed is a method of insulating a surface comprising applying to the surface an insulating panel fashioned from the structure of claim 1.
    • 公开了一种柔性绝缘的苯乙烯聚合物泡沫结构,其包含苯乙烯聚合物的聚合物组合物的泡沫,苯乙烯聚合物的重量百分比大于50重量%苯乙烯单体单元,泡沫具有相对较大的原始细胞,平均泡孔尺寸范围为约0.05至约1.2 毫米,并且相对较小的二次电池的电池尺寸范围为原始电池的平均电池尺寸的约5%至约50%。 初级和次级细胞构成泡沫结构内总细胞体积的至少约90%。 1至30个数量的细胞在它们之间具有微观的“针孔”。 针孔的存在增强了泡沫结构的挠曲。 还公开了一种绝缘表面的方法,包括将由绝缘板构成的绝缘板施加在表面上。
    • 8. 发明授权
    • Carbon black-containing bimodal foam structures and process for making
    • 含黑炭的双峰泡沫结构及其制备方法
    • US5210105A
    • 1993-05-11
    • US947855
    • 1992-09-18
    • Andrew N. PaquetKyung W. Suh
    • Andrew N. PaquetKyung W. Suh
    • C08J9/00C08J9/12
    • C08J9/0066C08J9/12C08J2203/12C08J2325/06Y10S264/05Y10S264/13
    • Disclosed is a bimodal, insulative, styrenic polymer foam structure comprising a foam of a styrene polymer material of greater than 50 percent by weight of styrenic monomeric units, the foam having relatively larger primary cells with a cell size range of 0.05 to 1.2 millimeters and relatively smaller secondary cells ranging in cell size from about 5 percent to about 50 percent of the average cell size of the primary cells. The primary and secondary cells constitute at least about 90 percent of the total cell volume within the foam structure. The bimodal structure has an amount of carbon black sufficient to reduce the thermal conductivity of the structure below that of a corresponding bimodal structure without carbon black. Further disclosed is a process for making the foam structure.
    • 公开了一种双峰,绝缘,苯乙烯聚合物泡沫结构,其包含苯乙烯聚合物材料的泡沫,其大于50重量%的苯乙烯单体单元,泡沫具有相对较大的原电池,其电池尺寸范围为0.05至1.2毫米, 细胞尺寸小于原代细胞平均细胞大小的约5%至约50%的较小的二次细胞。 初级和次级细胞构成泡沫结构内总细胞体积的至少约90%。 双峰结构具有足以将结构的热导率降低到低于不具有炭黑的相应双峰结构的热导率的量的炭黑。 进一步公开的是制造泡沫结构的方法。
    • 10. 发明授权
    • Carbon black-containing bimodal foam structures and process for making
    • 含黑炭的双峰泡沫结构及其制备方法
    • US5240968A
    • 1993-08-31
    • US990228
    • 1992-12-14
    • Andrew N. PaquetKyung W. Suh
    • Andrew N. PaquetKyung W. Suh
    • C08J9/00C08J9/12
    • C08J9/0066C08J9/12C08J2203/12C08J2205/048C08J2325/06
    • Disclosed is a a bimodal, insulative, styrenic polymer foam structure comprising a foam of a styrene polymer material of greater than 50 percent by weight of styrenic monomeric units, the foam having relatively larger primary cells with a cell size range of 0.05 to 1.2 millimeters and relatively smaller secondary cells ranging in cell size from about 5 percent to about 50 percent of the average cell size of the primary cells. The primary and secondary cells constitute at least about 90 percent of the total cell volume within the foam structure. The bimodal structure has an amount of carbon black sufficient to reduce the thermal conductivity of the structure below that of a corresponding bimodal structure without carbon black. Further disclosed is a process for making the foam structure.
    • 公开了一种双峰,绝缘,苯乙烯聚合物泡沫结构,其包含苯乙烯聚合物材料的泡沫,其大于50重量%的苯乙烯单体单元,泡沫具有相对较大的原电池,其电池尺寸范围为0.05至1.2毫米, 细胞尺寸小于原代细胞平均细胞大小的约5%至约50%的较小的二次细胞。 初级和次级细胞构成泡沫结构内总细胞体积的至少约90%。 双峰结构具有足以将结构的热导率降低到低于不具有炭黑的相应双峰结构的热导率的量的炭黑。 进一步公开的是制造泡沫结构的方法。