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1. 发明授权

US06213540B1 Energy absorbing articles of extruded thermoplastic foams 失效
标题翻译：挤压热塑性泡沫的能量吸收制品
公开(公告)号：US06213540B1
公开(公告)日：2001-04-10
申请号：US09105619
申请日：1998-06-26
申请人： Martin H. Tusim , Martin C. Cornell , Kyung W. Suh , Christopher P. Christenson , Chung P. Park
发明人： Martin H. Tusim , Martin C. Cornell , Kyung W. Suh , Christopher P. Christenson , Chung P. Park
IPC分类号： B60K3700
CPC分类号： B32B5/18 , B29C43/00 , B29C43/02 , B29C43/18 , B29C44/22 , B29C44/352 , B29C44/468 , B29C47/0019 , B29C47/0021 , B29C47/0028 , B29C47/003 , B29C47/004 , B29C47/0042 , B29C47/0054 , B29C47/06 , B29C47/067 , B29K2105/04 , B29L2031/3041 , B29L2031/3044 , B32B3/12 , B32B5/32 , B32B27/065 , B32B2266/025 , B32B2305/024 , B32B2307/56 , B32B2307/718 , B32B2605/08 , B60R19/22 , B60R21/04 , B60R21/0428 , F16F7/00 , Y10S428/91 , Y10T428/2495 , Y10T428/24992 , Y10T428/249986 , Y10T428/249989
摘要： An energy absorbing article having a direction in which impact resistance is desired is formed of extruded thermoplastic foam exhibit anisotropic compressive strength. The extrusion direction of the thermoplastic foam is aligned substantially parallel with the direction in which impact resistance is desired to provide an energy absorbing article exhibiting a high ratio of compressive strength to weight.
摘要翻译：具有期望抗冲击性的方向的能量吸收制品由挤出的热塑性泡沫形成，具有各向异性的抗压强度。热塑性泡沫的挤出方向基本上平行于需要耐冲击性的方向，以提供表现出高比例的抗压强度与重量的能量吸收制品。

2. 发明授权

US06251319B1 Method of forming a thermoformable polypropylene foam sheet 失效
标题翻译：形成可热成形的聚丙烯泡沫板的方法
公开(公告)号：US06251319B1
公开(公告)日：2001-06-26
申请号：US09302306
申请日：1999-04-30
申请人： Martin H. Tusim , Martin C. Cornell , Kyung W. Suh , Christopher P. Christenson , Chung P. Park
发明人： Martin H. Tusim , Martin C. Cornell , Kyung W. Suh , Christopher P. Christenson , Chung P. Park
IPC分类号： B29C4420
CPC分类号： B32B5/18 , B29C43/00 , B29C44/22 , B29C44/5654 , B29C47/0014 , B29C47/0016 , B29C47/0021 , B29C47/0023 , B29C47/0038 , B29C47/004 , B29C47/0042 , B29C47/0054 , B29C47/0066 , B29C47/02 , B29K2105/04 , B29K2105/0854 , B32B5/245 , B32B5/32 , B32B27/065 , B32B27/32 , B32B2266/0257 , B32B2266/0264 , B32B2305/30 , B32B2323/10 , B32B2605/00 , B60R13/02 , B60R13/0225 , B60R13/0815 , C08J9/127 , C08J9/141 , C08J9/142 , C08J2201/03 , C08J2323/12 , Y10S264/05
摘要： A process for making a polymer foam sheet, which comprises (i) extruding through an annular extrusion die a foamable composition comprising at least one polypropylene polymer and at least one blowing agent, at a pressure, temperature, and extrusion rate sufficient to prevent foaming of the composition prior to exiting the die, under conditions sufficient to form a foam tube having a density of at least 16 kg/m3 and no greater than 200 kg/m3, an open cell content of less than 70 percent, a circumference of at least 1 meter, and a foam thickness of at least 2 mm and no greater than 25 mm, wherein the blowing agent is used in an amount of from 0.2 to 4.5 moles per kg of polymer, (ii) allowing the foam to cool to a temperature below the melt temperature of the polypropylene, and (iii) cutting the tube of foam along its radius to form a foam sheet, wherein at least 70 percent by weight of the polymer in such sheet is a polypropylene having a melt strength in the range of from 25 to 60 cN when measured at 190° C.
摘要翻译：一种制备聚合物泡沫片的方法，其包括（i）通过环形挤出模挤出包含至少一种聚丙烯聚合物和至少一种发泡剂的可发泡组合物，其压力，温度和挤出速率足以防止发泡在足以形成具有至少16kg / m 3且不大于200kg / m 3的密度的泡沫管的条件下离开模具之前的组合物，开孔的含量小于70％，至少为周长 1米，泡沫厚度为至少2mm且不大于25毫米，其中发泡剂的用量为每公斤聚合物0.2至4.5摩尔，（ii）使泡沫体冷却至温度低于聚丙烯的熔融温度，和（iii）沿着其半径切割泡沫管，以形成泡沫片，其中该片材中至少70重量％的聚合物是熔体强度范围为从25到60 cN en在190℃测量

3. 发明授权

US06417242B1 Propylene polymer foams 失效
标题翻译：丙烯聚合物泡沫
公开(公告)号：US06417242B1
公开(公告)日：2002-07-09
申请号：US09970282
申请日：2001-10-02
申请人： Kevin R. Hughes , Robert L. Sammler , Kyung W. Suh , Jin Zhao , Johan A. Thoen , Martin H. Tusim
发明人： Kevin R. Hughes , Robert L. Sammler , Kyung W. Suh , Jin Zhao , Johan A. Thoen , Martin H. Tusim
IPC分类号： C08J900
CPC分类号： C08J9/141 , C08J9/106 , C08J9/14 , C08J2205/052 , C08J2323/12 , C08L23/10 , C08L2203/14
摘要： The present invention relates to a foam, a process for preparing the foam and an article containing the foam. The foam contains a coupled propylene polymer and has a density in of from 9.6 to 801 kg/m3 and has either a foamability factor of more than 1.8 to less than 2.8 and an open cell content less than 20 percent, or a foamability factor of at least 2.8 and less than 15 and an open cell content of less than 50 percent. The process includes heating a coupled propylene polymer having a melt flow rate from 0.2 to 20 g/10 min and a melt strength of at least 39 cN to a molten state to produce a molten polymer material and mixing said molten polymer material with a blowing agent under conditions to produce a foamed material having a density in the range of from 9.6 to 801 kg/m3.
摘要翻译：本发明涉及泡沫，制备泡沫的方法和含有泡沫的物品。该泡沫体含有一种偶联的丙烯聚合物，其密度为9.6至801kg / m 3，并且具有大于1.8至小于2.8的发泡性因子，开孔率低于20％，或至少2.8和小于15，开孔含量小于50％。该方法包括加热熔融流动速率为0.2-20g / 10min，熔体强度至少为39cN的熔融态丙烯聚合物，生成熔融聚合物材料，并将所述熔融聚合物材料与发泡剂在生产密度在9.6至801kg / m 3范围内的发泡材料的条件下。

4. 发明授权

US5411684A Process for making large cross-section olefinic polymer foam structure blown with 1, 1-difluoroethane 失效
标题翻译：用1,1-二氟乙烷吹制大截面烯烃聚合物泡沫结构的方法
公开(公告)号：US5411684A
公开(公告)日：1995-05-02
申请号：US56231
申请日：1993-04-30
申请人： Martin H. Tusim , Chung P. Park
发明人： Martin H. Tusim , Chung P. Park
IPC分类号： C08J9/14 , B29C44/00
CPC分类号： C08J9/149 , C08J2323/02
摘要： Disclosed is an extruded, unitary, closed-cell olefin polymer foam structure in plank form. The foam structure has a cross-section of 2 or more inches in one dimension and 18 or more inches in the other dimension. The olefin polymer material has a melt index of about 3.5 grams/10 minutes or less. The foam structure contains a blowing agent of about 75 mole percent or more 1,1-difluoroethane based upon the total moles of blowing agent. Further disclosed is a process for making the foam structure at a shear rate of about 400/second or more. It was found surprising that 1,1-difluoroethane which has relatively low solubility in olefin polymers, could be used to make olefin polymer foam structures of large cross-section.
摘要翻译：公开了一种板状的挤出的，单一的闭孔烯烃聚合物泡沫结构。泡沫结构在一个尺寸上具有2英寸或更多英寸的横截面，在另一个尺寸上具有18英寸或更多英寸的横截面。烯烃聚合物材料的熔体指数为约3.5克/ 10分钟或更短。泡沫结构含有基于发泡剂总摩尔数的约75摩尔％或更多的1,1-二氟乙烷的发泡剂。进一步公开的是使泡沫结构的剪切速率为约400 /秒以上的方法。发现在烯烃聚合物中具有较低溶解度的1,1-二氟乙烷可用于制备具有大横截面的烯烃聚合物泡沫结构。

5. 发明授权

US4912140A Expandable and expanded alkenyl aromatic polymer particles 失效
标题翻译：可扩展和扩展的链烯基芳族聚合物颗粒
公开(公告)号：US4912140A
公开(公告)日：1990-03-27
申请号：US247195
申请日：1988-09-21
申请人： Martin H. Tusim
发明人： Martin H. Tusim
IPC分类号： C08J9/18 , C08J9/14
CPC分类号： C08J9/149 , C08J2325/02 , Y10S264/05 , Y10S521/91
摘要： Expandable and expanded particles are prepared from an alkenyl aromatic polymer and a volatile fluid blowing agent mixture of a first blowing agent of 1,1-difluoro-1-chloroethane; and a second blowing agent selected from normal pentane, isopentane, neopentane or mixtures of the various pentanes.

6. 发明授权

US5071606A Plasticizers for expandable styrene-acrylonitrile resin 失效
标题翻译：可膨胀苯乙烯 - 丙烯腈树脂增塑剂
公开(公告)号：US5071606A
公开(公告)日：1991-12-10
申请号：US582043
申请日：1990-09-13
申请人： Martin H. Tusim , Timothy W. Rhoads
发明人： Martin H. Tusim , Timothy W. Rhoads
IPC分类号： C08J9/00
CPC分类号： C08J9/0023 , C08J2325/12
摘要： Novel, expandable polymeric blends comprising at least one vinylaromatic monomer-acylonitrile resinous material, an effective amount of at least one blowing agent, and from about 0.2 to about 1.0 percent by weight, based on the weight of resinous material, of an expansion aid consisting essentially of triethylene glycol. The triethylene glycol expansion aid unexpectedly reduces the amount of expansion agent required to expand the composition, particularly to low density products, without adversely affecting the final properties of the foamed product.
摘要翻译：包含至少一种乙烯基芳族单体 - 酰基腈树脂材料，有效量的至少一种发泡剂和基于树脂材料重量的约0.2至约1.0重量％的膨胀助剂的新型可发泡聚合物共混物包含基本上是三甘醇。三乙二醇膨胀助剂意外地减少了扩展组合物所需的膨胀剂的量，特别是低密度产品，而不会不利地影响发泡产品的最终性能。

7. 发明授权

US07687002B2 Substantially proportional drawing die for polymer compositions 有权
标题翻译：用于聚合物组合物的基本成比例的拉伸模头
公开(公告)号：US07687002B2
公开(公告)日：2010-03-30
申请号：US11974619
申请日：2007-10-15
申请人： Kevin L. Nichols , Brett M. Birchmeier , Martin H. Tusim , Ian M. Ward , Philip D. Coates , Phil Caton-Rose , Glen P. Thompson
发明人： Kevin L. Nichols , Brett M. Birchmeier , Martin H. Tusim , Ian M. Ward , Philip D. Coates , Phil Caton-Rose , Glen P. Thompson
IPC分类号： B29C47/00
CPC分类号： B29C55/30
摘要： An inventive solid state drawing die has shaping walls that define a shaping channel and that, in the course of solid state drawing, direct polymer composition along a drawing path. Each cross section of the drawing path (and, hence, polymer composition in the drawing path) is non-circular, substantially proportional to one another, contains a centroid that lies on a substantially straight line parallel to the drawing direction and all cross sectional dimensions are 1.5 millimeters or more.
摘要翻译：本发明的固态拉伸模头具有限定成形通道的成形壁，并且在固态拉伸过程中，沿着牵引路径的直接聚合物组合物。拉伸路径的每个横截面（以及因此在拉伸路径中的聚合物组成）是非圆形的，基本上彼此成比例，包含位于平行于拉伸方向的基本直线上的质心，并且所有横截面尺寸是1.5毫米以上。

8. 发明授权

US07300612B2 Hollow strandfoam and preparation thereof 失效
公开(公告)号：US07300612B2
公开(公告)日：2007-11-27
申请号：US10863917
申请日：2004-06-09
申请人： Vyacheslav D. Grinshpun , Michael E. Schaller , Martin H. Tusim , Andrew R. Brush , Jonathan D. Park
发明人： Vyacheslav D. Grinshpun , Michael E. Schaller , Martin H. Tusim , Andrew R. Brush , Jonathan D. Park
IPC分类号： B29C44/20 , B29C44/24
CPC分类号： B29C47/30 , B29C44/04 , B29C44/468 , B29C47/0014 , B29C47/0023 , B29K2025/06 , B29K2101/12 , Y10T428/24066 , Y10T428/24091 , Y10T428/249953 , Y10T428/249971 , Y10T428/249972 , Y10T428/249976 , Y10T428/249977 , Y10T428/249987 , Y10T428/31507 , Y10T428/31551 , Y10T428/31591 , Y10T428/31721 , Y10T428/31725 , Y10T428/31779 , Y10T428/31786 , Y10T428/3179 , Y10T428/31855 , Y10T428/31971
摘要： Prepare a foam structure that includes hollow coalesced foam strands and, optionally, solid coalesced foam strands using an extrusion die block equipped with apertures that promote forming the hollow strands and, optionally, the solid foam strands.

9. 发明授权

US4839396A Expandable and expanded alkenyl aromatic polymer particles and methods of making the same 失效
公开(公告)号：US4839396A
公开(公告)日：1989-06-13
申请号：US234986
申请日：1988-08-22
申请人： Martin H. Tusim
发明人： Martin H. Tusim
IPC分类号： C08J9/00 , C08J9/16 , C08K5/134
CPC分类号： C08J9/16 , C08J9/0023 , C08K5/1345 , C08J2325/00
摘要： The present invention relates to expandable and expanded alkenyl aromatic polymer particles having the ability to use a decreased amount of blowing agent to produce an expanded alkenyl aromatic polymer particle of an equivalent bulk density or the same amount of blowing agent to produce an expanded alkenyl aromatic polymer particle having a decreased bulk density by including a density modifier in the expandable alkenyl aromatic polymer particle in an amount of about 0.005 to 0.5 weight percent by weight of the total mixture. Also included as part of the invention are methods of making the expandable and expanded alkenyl aromatic polymer particles wherein the expandable and expanded alkenyl aromatic polymer particles have a density modifier included in an amount of about 0.005 percent to about 0.5 weight percent by weight of the total mixture.

10. 发明授权

US4376799A Quiet film and container 失效
标题翻译：安静的电影和容器
公开(公告)号：US4376799A
公开(公告)日：1983-03-15
申请号：US187660
申请日：1980-09-16
申请人： Martin H. Tusim
发明人： Martin H. Tusim
IPC分类号： C08L23/00 , A61F5/44 , A61L28/00 , B29C47/04 , B32B7/02 , B32B27/08 , B32B27/32 , C08J5/12 , C08K5/04 , C08K5/09 , C08L23/04 , C08L23/26 , C08L23/28
CPC分类号： C08J5/128 , A61F5/44 , A61L28/008 , B32B27/08 , B32B27/322 , C08L23/28 , Y10T428/2495 , Y10T428/24967 , Y10T428/24975 , Y10T428/31909 , Y10T428/3192
摘要： A substantially rustle-free thermoplastic film and container made therefrom. The film may be a multilayer structure, a skin of which is formed of a chlorinated polyethylene resin blend. The composition of said structure is such that quietness is imparted without detracting from the extrudability and other physical characteristics necessary for practical applications. A vapor barrier may be included as a core layer. A particular application for the present invention is an ostomy bag.
摘要翻译：由其制成的基本上无沙拉的热塑性薄膜和容器。膜可以是多层结构，其皮肤由氯化聚乙烯树脂混合物形成。所述结构的组成是赋予静音，而不会降低实际应用所需的挤出性和其它物理特性。可以包括蒸气阻挡层作为核心层。本发明的具体应用是造口袋。

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