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    • 3. 发明授权
    • Methods and materials for selective boron adsorption from aqueous solution
    • 从水溶液中选择性硼吸附的方法和材料
    • US08357300B2
    • 2013-01-22
    • US12856755
    • 2010-08-16
    • Il Juhn RohMark WilfCraig R. Bartels
    • Il Juhn RohMark WilfCraig R. Bartels
    • B01D61/00B01D11/00C02F1/26B01D63/00
    • C02F1/444C02F1/288C02F1/442C02F1/58C02F1/683C02F2101/108C02F2103/08C02F2209/06
    • A method for reducing a boron concentration in a boron-containing aqueous liquid involves administering micelle(s) for selective boron adsorption to the boron-containing aqueous liquid to produce boron-bonded micelle(s), wherein the micelle(s) comprise a reaction product of an N-substituted-glucamine and a glycidyl ether; passing the micelle-containing aqueous liquid through a membrane to separate the boron-bonded micelle(s) from the aqueous liquid; and recovering a permeate having a reduced boron concentration from the membrane. A material capable of selectively adsorbing boron from a boron-containing aqueous liquid contains at least one micelle having a hydrophobic tail and a head comprising a hydrophilic functional group having formula (I): R1—O-A  (I) R1 represents a hydrocarbon group selected from the group consisting of substituted and unsubstituted aromatic, linear aliphatic, and branched aliphatic hydrocarbon groups and mixtures thereof, and A contains hydroxyl and amine groups.
    • 一种用于降低含硼水溶液中的硼浓度的方法包括给含硼水性液体施加用于选择性硼吸附的胶束以产生硼键合的胶束,其中所述胶束包含反应 N-取代葡糖胺和缩水甘油醚的产物; 使含胶束的含水液体通过膜以将硼键合的胶束与水性液体分离; 并从膜中回收具有降低的硼浓度的渗透物。 能够从含硼水溶液中选择性吸附硼的材料含有至少一个具有疏水性尾巴的胶束和包含具有式(I)的亲水性官能团的头:R1-OA(Ⅰ)R1表示选自 由取代和未取代的芳族,直链脂族和支链脂族烃基及其混合物组成的组,A包含羟基和胺基团。