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1. 发明授权

US4525468A Olefin polymerization catalyst 失效
标题翻译：烯烃聚合催化剂
公开(公告)号：US4525468A
公开(公告)日：1985-06-25
申请号：US489687
申请日：1983-04-28
申请人： Mark P. Mack , Mark L. Shannon
发明人： Mark P. Mack , Mark L. Shannon
IPC分类号： C08F4/64 , C08F10/00
CPC分类号： C08F10/00
摘要： High activity catalysts for the polymerization of ethylene and other .alpha.-olefins are made by contacting a soluble magnesium compound of the general formula Mg(OSiR.sup.1 R.sup.2 R.sup.3).sub.2, wherein each of R.sup.1, R.sup.2, and R.sup.3 is, independently, alkyl, alkoxy or aryl with a metal alkoxide, or a mixture of a titanium tetraalkoxide with an alkoxide of another transition metal, in a saturated aliphatic hydrocarbon solution, followed by chlorination and precipitation by a suitable chlorinating agent. These catalysts show high activity for the polymerization of ethylene, especially under slurry polymerization conditions.
摘要翻译：通过使通式Mg（OSiR1R2R3）2的可溶性镁化合物与其中R1，R2和R3各自独立地为烷基，烷氧基或芳基与通式Mg（OSiR 2 R 3）2的可溶性镁化合物接触而制备用于乙烯和其它α-烯烃聚合的高活性催化剂，金属醇盐或四烷氧基钛与另一过渡金属的醇盐的混合物，在饱和脂族烃溶液中，然后氯化并通过合适的氯化剂沉淀。这些催化剂对于乙烯的聚合显示出高的活性，特别是在淤浆聚合条件下。

2. 发明授权

US4440869A Olefin polymerization catalyst 失效
标题翻译：烯烃聚合催化剂
公开(公告)号：US4440869A
公开(公告)日：1984-04-03
申请号：US429632
申请日：1982-09-30
申请人： Mark L. Shannon , Mark P. Mack
发明人： Mark L. Shannon , Mark P. Mack
IPC分类号： C08F4/62 , C08F10/00 , C08F4/64 , C08F4/68
CPC分类号： C08F10/00
摘要： High activity catalysts for the polymerization of ethylene and other .alpha.-olefins are made by contacting a soluble magnesium compound of the general formula Mg(OSiR.sub.3).sub.2, wherein each R is, independently, alkyl, alkoxy or aryl, with a titanium tetralkoxide (titanate) in a saturated aliphatic hydrocarbon solution, followed by chlorination and precipitation by a suitable chlorinating agent. These catalysts show high activity for the polymerization of ethylene under slurry polymerization conditions.
摘要翻译：通过使通式Mg（OSiR 3）2的可溶性镁化合物，其中每个R独立地是烷基，烷氧基或芳基与四氢化钛（钛酸盐）接触来制备用于乙烯和其它α-烯烃聚合的高活性催化剂）饱和脂肪族烃溶液中，然后通过合适的氯化剂进行氯化和沉淀。这些催化剂在淤浆聚合条件下对乙烯的聚合显示出高活性。

3. 发明授权

US4529778A Preparation of modified aromatic moiety-containing polymers 失效
标题翻译：改性芳族部分聚合物的制备
公开(公告)号：US4529778A
公开(公告)日：1985-07-16
申请号：US534855
申请日：1983-09-22
申请人： Mark L. Shannon
发明人： Mark L. Shannon
IPC分类号： C08G81/02 , C08F8/00
CPC分类号： C08G81/024 , C08G81/021
摘要： A process for preparing aromatic-moiety-containing polymers having modified physical properties is disclosed. Briefly, the process comprises reacting in the presence of a Friedel-Crafts catalyst: (a) a suitable aromatic-moiety containing polymer resin and (b) a homopolymer of .omega.-halo-.alpha.-olefins, or co- or terpolymer of .omega.-halo-.alpha.-olefins with other .alpha.-olefins and/or ethylene.
摘要翻译：公开了一种制备具有改性物理性质的含芳香族部分的聚合物的方法。简言之，该方法包括在Friedel-Crafts催化剂存在下反应：（a）合适的含芳香部分的聚合物树脂和（b）ω-卤代-α-烯烃的均聚物，或ω- 卤代-α-烯烃与其它α-烯烃和/或乙烯。

4. 发明授权

US4424308A Preparation of modified aromatic-moiety-containing polymers 失效
标题翻译：含改性芳香族部分的聚合物的制备
公开(公告)号：US4424308A
公开(公告)日：1984-01-03
申请号：US329790
申请日：1981-12-11
申请人： Mark L. Shannon
发明人： Mark L. Shannon
IPC分类号： C08G81/02 , C08F8/00
CPC分类号： C08G81/024 , C08G81/021
摘要： A process for preparing aromatic-moiety-containing polymers having modified physical properties is disclosed. Briefly, the process comprises reacting in the presence of a Friedel-Crafts catalyst: (a) a suitable aromatic-moiety containing polymer resin and (b) a homopolymer of .omega.-halo-.alpha.-olefins, or co- or terpolymer of .omega.-halo-.alpha.-olefins with other .alpha.-olefins and/or ethylene.
摘要翻译：公开了一种制备具有改性物理性质的含芳香族部分的聚合物的方法。简言之，该方法包括在Friedel-Crafts催化剂存在下反应：（a）合适的含芳香部分的聚合物树脂和（b）ω-卤代-α-烯烃的均聚物，或ω- 卤代-α-烯烃与其它α-烯烃和/或乙烯。

5. 发明授权

US4835321A Alkoxylaton process using calcium based catalysts 失效
标题翻译：使用钙基催化剂的烷氧基化方法
公开(公告)号：US4835321A
公开(公告)日：1989-05-30
申请号：US181197
申请日：1988-04-13
申请人： Bruce E. Leach , Mark L. Shannon , Donald L. Wharry
发明人： Bruce E. Leach , Mark L. Shannon , Donald L. Wharry
IPC分类号： B01J31/02 , B01J31/14 , C07C41/03 , C08G65/10 , C08G65/26
CPC分类号： C08G65/269 , B01J31/0212 , C07C41/03 , C08G65/10 , B01J2231/48
摘要： A process for preparing an alkoxylation catalyst in which the catalyst pre-mix is formed by admixing an alkoxylated alcohol with a calcium containing compound which is dispersible in the alkoxylated alcohol, an inorganic acid and an aluminum trialkoxide, the pre-mix being heated to a temperature and for a time sufficient to effect at least partial exchange reaction betweeen the alkoxide groups of the aluminum alkoxide and the hydroxyl groups of the alkoxylated alcohol. There is also disclosed and claimed an alkoxylation process utilizing the catalysts formed as described above.
摘要翻译：制备烷氧基化催化剂的方法，其中通过将烷氧基化醇与可分散在烷氧基化醇中的含钙化合物，无机酸和三烷氧基铝混合而形成催化剂预混物，将预混合物加热至温度和足以实现烷氧基铝的醇盐基团与烷氧基化醇的羟基之间的至少部分交换反应的时间。还公开并要求使用如上所述形成的催化剂的烷氧基化方法。

6. 发明授权

US4775653A Alkoxylation process using calcium based catalysts 失效
标题翻译：使用基于钙的催化剂的烷氧基化方法
公开(公告)号：US4775653A
公开(公告)日：1988-10-04
申请号：US43660
申请日：1987-04-28
申请人： Bruce E. Leach , Mark L. Shannon , Donald L. Wharry
发明人： Bruce E. Leach , Mark L. Shannon , Donald L. Wharry
IPC分类号： B01J31/26 , B01J31/02 , B01J31/14 , C07B61/00 , C07C41/00 , C07C41/03 , C07C43/11 , C07C67/00 , C08G65/10 , C08G65/26 , B01J31/04
CPC分类号： C08G65/269 , B01J31/0212 , C07C41/03 , C07C41/42 , C08G65/10
摘要： A process for preparing an alkoxylation catalyst in which the catalyst pre-mix is formed by admixing an alkoxylated alcohol with a calcium containing compound which is dispersible in the alkoxylated alcohol, an inorganic acid and an aluminum trialkoxide, the pre-mix being heated to a temperature and for a time sufficient to effect at least partial exchange reaction between the alkoxide groups of the aluminum alkoxide and the hydroxyl groups of the alkoxylated alcohol. There is also disclosed and claimed an alkoxylation process utilizing the catalysts formed as described above.

7. 发明授权

US4397764A Polymer-supported ethylene polymerization catalyst 失效
标题翻译：聚合物负载的乙烯聚合催化剂
公开(公告)号：US4397764A
公开(公告)日：1983-08-09
申请号：US362182
申请日：1982-03-26
申请人： Mark L. Shannon
发明人： Mark L. Shannon
IPC分类号： C08F4/64 , C08F10/02
CPC分类号： C08F10/02
摘要： A polymer-supported ethylene polymerization catalyst prepared by a method comprising (a) a polymer supported titanium-based catalyst consisting of(1) a polymer resin containing an amino borane reducing agent;(2) a titanium tetrahalide;(3) and a suitable organometallic and/or organic metallic co-catalyst.The polymers produced are resins of high density and melting point.
摘要翻译：一种聚合物负载的乙烯聚合催化剂，其通过包括（a）由（1）含有氨基硼烷还原剂的聚合物树脂组成的聚合物负载的钛基催化剂的方法制备; （2）四卤化钛; （3）和合适的有机金属和/或有机金属助催化剂。所生产的聚合物是高密度和熔点的树脂。

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