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1. 发明申请

US20090069450A1 COMMERCIAL FISCHER-TROPSCH REACTOR 有权
标题翻译：商业FISCHER-TROPSCH反应堆
公开(公告)号：US20090069450A1
公开(公告)日：2009-03-12
申请号：US12206538
申请日：2008-09-08
申请人： Mark Ibsen , Sergio Mohedas , Frank Hogsett , Mark Bohn , Harold A. Wright
发明人： Mark Ibsen , Sergio Mohedas , Frank Hogsett , Mark Bohn , Harold A. Wright
IPC分类号： C07C1/04 , B01J19/00
CPC分类号： B03C1/02 , B01J8/005 , B01J8/007 , B01J8/22 , B01J8/228 , B01J35/0033 , B03C1/288 , B03C1/30 , B03C2201/18 , C10G2/33 , C10G2/332 , C10G2/342 , C10G45/00 , C10G45/58 , C10G47/00
摘要： A catalytic reaction system comprising: a catalytic reactor fluidly connected with at least two slurry loops, wherein the reactor comprises at least as many reactor product outlets and at least as many slurry return inlets as slurry loops; wherein each slurry loop comprises a separation system comprising a separation system inlet, a separation system product outlet, and a concentrated catalyst slurry outlet; a slurry offtake fluidly connecting the separation system inlet with one of the reactor product outlets; and a slurry return fluidly connecting the separation system outlet with one of the slurry return inlets. The system may comprise at least three slurry loops. The system may comprise at least four slurry loops. A method for converting synthesis gas into liquid hydrocarbons via the catalytic reaction system in also disclosed.
摘要翻译：一种催化反应系统，包括：与至少两个淤浆环流体连接的催化反应器，其中所述反应器至少包含反应器产物出口和至少与淤浆循环一样多的浆料返回入口; 其中每个浆料回路包括分离系统，其包括分离系统入口，分离系统产物出口和浓缩的催化剂浆料出口; 将分离系统入口与其中一个反应器产物出口流体连接的出料浆料; 以及将分离系统出口与其中一个浆料回流入口流体连接的浆料返回。该系统可以包括至少三个淤浆循环。该系统可以包括至少四个浆料循环。还公开了通过催化反应系统将合成气转化为液态烃的方法。

2. 发明授权

US09168501B2 Commercial Fischer-Tropsch reactor 有权
标题翻译：商业费 - 托反应堆
公开(公告)号：US09168501B2
公开(公告)日：2015-10-27
申请号：US12206538
申请日：2008-09-08
申请人： Mark Ibsen , Sergio Mohedas , Frank Hogsett , Mark Bohn , Harold A. Wright
发明人： Mark Ibsen , Sergio Mohedas , Frank Hogsett , Mark Bohn , Harold A. Wright
IPC分类号： B01J8/22 , C10G2/00 , B01J8/00 , B03C1/28 , B03C1/30
CPC分类号： B03C1/02 , B01J8/005 , B01J8/007 , B01J8/22 , B01J8/228 , B01J35/0033 , B03C1/288 , B03C1/30 , B03C2201/18 , C10G2/33 , C10G2/332 , C10G2/342 , C10G45/00 , C10G45/58 , C10G47/00
摘要： A catalytic reaction system comprising: a catalytic reactor fluidly connected with at least two slurry loops, wherein the reactor comprises at least as many reactor product outlets and at least as many slurry return inlets as slurry loops; wherein each slurry loop comprises a separation system comprising a separation system inlet, a separation system product outlet, and a concentrated catalyst slurry outlet; a slurry offtake fluidly connecting the separation system inlet with one of the reactor product outlets; and a slurry return fluidly connecting the separation system outlet with one of the slurry return inlets. The system may comprise at least three slurry loops. The system may comprise at least four slurry loops. A method for converting synthesis gas into liquid hydrocarbons via the catalytic reaction system in also disclosed.
摘要翻译：一种催化反应系统，包括：与至少两个淤浆环流体连接的催化反应器，其中所述反应器至少包含反应器产物出口和至少与淤浆循环一样多的浆料返回入口; 其中每个浆料回路包括分离系统，其包括分离系统入口，分离系统产物出口和浓缩的催化剂浆料出口; 将分离系统入口与其中一个反应器产物出口流体连接的出料浆料; 以及将分离系统出口与其中一个浆料回流入口流体连接的浆料返回。该系统可以包括至少三个淤浆循环。该系统可以包括至少四个浆料循环。还公开了通过催化反应系统将合成气转化为液态烃的方法。

3. 发明授权

US08530366B2 Protected fischer-tropsch catalyst and method of providing same to a fischer-tropsch process 有权
标题翻译：保护的费 - 托催化剂及其提供给费 - 托法的方法
公开(公告)号：US08530366B2
公开(公告)日：2013-09-10
申请号：US12984902
申请日：2011-01-05
申请人： Harold A. Wright , Belma Demirel , Sergio Mohedas , Bahman Rejai , Ray Huang , Deena Ferdous , Jesse W. Taylor , Dawid J. Duvenhage , Sara L. Rolfe
发明人： Harold A. Wright , Belma Demirel , Sergio Mohedas , Bahman Rejai , Ray Huang , Deena Ferdous , Jesse W. Taylor , Dawid J. Duvenhage , Sara L. Rolfe
IPC分类号： B01J20/34 , C07C27/00
CPC分类号： B01J8/006 , B01J8/18 , B01J8/1809 , B01J23/745 , B01J33/00 , B01J35/023 , B01J37/0045 , B01J37/18 , C10G2/32 , C10G2/33 , C10G2/332 , C10G2300/703
摘要： A method of preparing a spray dried catalyst by combining spray dried catalyst particles with wax so the spray dried catalyst particles are coated with wax, yielding wax coated catalyst particles, and shaping the wax coated catalyst to provide shaped wax coated catalyst. A method of activating Fischer-Tropsch catalyst particles containing oxides by contacting the catalyst particles with a reducing gas in an activation vessel to produce an activated catalyst, wherein contacting is performed in the absence of a liquid medium under activation conditions. A system for activating a Fischer-Tropsch catalyst containing an activation reactor configured to introduce an activation gas to a fixed or fluidized bed of the Fischer-Tropsch catalyst in the absence of a liquid medium and at least one separation device configured to separate a gas stream comprising entrained catalyst fines having an average particle size below a desired cutoff size from the activation reactor.
摘要翻译：通过将喷雾干燥的催化剂颗粒与蜡组合来制备喷雾干燥的催化剂的方法，使喷雾干燥的催化剂颗粒用蜡涂覆，产生蜡涂覆的催化剂颗粒，并使蜡涂覆的催化剂成形以提供成形的涂蜡催化剂。通过使催化剂颗粒与活化容器中的还原气体接触以产生活化的催化剂来活化含有氧化物的费 - 托催化剂颗粒的方法，其中在不存在液体介质的条件下进行接触。一种用于活化费 - 托催化剂的系统，其包含活化反应器，所述活化反应器配置成在没有液体介质的情况下将活化气体引入费 - 托催化剂的固定或流化床，以及至少一个分离装置，其被配置为分离气流包括夹带的催化剂细粒，其具有低于来自活化反应器的所需截留尺寸的平均粒度。

4. 发明申请

US20120022173A1 HYDROGEN AND CARBON UTILIZATION IN SYNTHETIC FUELS PRODUCTION PLANTS 有权
标题翻译：合成燃料生产厂的氢和碳利用
公开(公告)号：US20120022173A1
公开(公告)日：2012-01-26
申请号：US13248547
申请日：2011-09-29
申请人： Sergio Mohedas , Mark Ibsen
发明人： Sergio Mohedas , Mark Ibsen
IPC分类号： C07C27/00 , B01J19/00
CPC分类号： C10J3/00 , B01J37/16 , B01J37/18 , C01B3/34 , C01B3/56 , C01B2203/0405 , C01B2203/043 , C01B2203/046 , C01B2203/0485 , C01B2203/049 , C01B2203/062 , C10G2/332 , C10G45/60 , C10G47/02 , C10G49/02 , C10G2300/1011 , C10G2300/703 , C10J2300/0916 , C10J2300/093 , C10J2300/0943 , C10J2300/1618 , C10J2300/1659 , C10J2300/1823 , C10K3/00 , Y02P20/145 , Y02P20/52 , Y02P30/20
摘要： A system including at least one hydrogen extraction unit comprising an inlet for a synthesis feedgas from a synthesis feedgas line and adapted to remove at least one hydrogen-rich gas and at least one hydrogen-lean gas from the synthesis feedgas to yield a refined synthesis gas; and at least one hydrocarbon synthesis reactor, at least one dedicated activation reactor, or both, wherein the at least one hydrocarbon synthesis reactor is fluidly connected with the at least one hydrogen extraction unit and configured to provide liquid hydrocarbons and a first byproduct gas from a synthesis reactor feedstream comprising at least a portion of the refined synthesis gas; and wherein the at least one dedicated activation reactor is fluidly connected with the at least one hydrogen extraction unit, the at least one hydrocarbon synthesis reactor, or both, and configured for activation of hydrocarbon synthesis catalyst via an activation gas.
摘要翻译：一种包括至少一个氢气提取单元的系统，其包括用于从合成进料气管线合成进料气的入口，并适于从合成进料气中除去至少一种富氢气体和至少一种贫贫气体，以产生精制合成气 ; 和至少一个烃合成反应器，至少一个专用活化反应器或两者，其中所述至少一个烃合成反应器与所述至少一个氢提取单元流体连接并且构造成提供液体烃和来自第一副产物气体的第一副产物气体合成反应器进料流，其包含至少一部分精制合成气; 并且其中所述至少一个专用活化反应器与所述至少一个氢提取单元，所述至少一个烃合成反应器或两者流体连接，并且被配置为经由活化气体活化烃合成催化剂。

5. 发明授权

US08088187B2 Hydrogen and carbon utilization in synthetic fuels production plants 有权
标题翻译：合成燃料生产厂的氢和碳利用
公开(公告)号：US08088187B2
公开(公告)日：2012-01-03
申请号：US12207978
申请日：2008-09-10
申请人： Sergio Mohedas , Mark Ibsen
发明人： Sergio Mohedas , Mark Ibsen
IPC分类号： C01B3/36 , C01B6/24 , C01B3/02 , C10J3/46 , B01J7/00 , C07C27/00 , C07C27/06
CPC分类号： C10J3/00 , B01J37/16 , B01J37/18 , C01B3/34 , C01B3/56 , C01B2203/0405 , C01B2203/043 , C01B2203/046 , C01B2203/0485 , C01B2203/049 , C01B2203/062 , C10G2/332 , C10G45/60 , C10G47/02 , C10G49/02 , C10G2300/1011 , C10G2300/703 , C10J2300/0916 , C10J2300/093 , C10J2300/0943 , C10J2300/1618 , C10J2300/1659 , C10J2300/1823 , C10K3/00 , Y02P20/145 , Y02P20/52 , Y02P30/20
摘要： A method of utilizing hydrogen in synthesis gas production by forming synthesis gas from one or more carbonaceous materials, the synthesis gas comprising hydrogen and carbon monoxide; separating a hydrogen-rich product and a hydrogen-lean product from the synthesis gas to yield an adjusted synthesis gas product; and activating a hydrocarbon synthesis catalyst with at least a portion of the hydrogen-lean product. A system for carrying out the method is also provided, the system including at least one hydrogen extraction unit and an activation reactor operable to activate hydrocarbon synthesis catalyst, wherein the activation reactor comprises an inlet fluidly connected with the at least one hydrogen extraction unit whereby at least a portion of a hydrogen-lean gas stream, at least a portion of a hydrogen-rich gas stream, or at least a portion of both may be introduced into the activation reactor.
摘要翻译：一种通过从一种或多种含碳材料形成合成气而在合成气生产中利用氢的方法，所述合成气包含氢气和一氧化碳; 从合成气中分离富氢产物和贫氢产物以产生经调节的合成气产物; 以及用至少一部分所述富氢产物活化烃合成催化剂。还提供了一种用于实施该方法的系统，所述系统包括至少一个氢提取单元和可操作以活化烃合成催化剂的活化反应器，其中所述活化反应器包括与所述至少一个氢提取单元流体连接的入口，贫氢气流的至少一部分，富氢气流的至少一部分或两者的至少一部分可以被引入到活化反应器中。

6. 发明申请

US20100160156A1 CATALYST ACTIVATION IN FISCHER-TROPSCH PROCESSES 审中-公开
标题翻译： FISCHER-TROPSCH过程中的催化剂活化
公开(公告)号：US20100160156A1
公开(公告)日：2010-06-24
申请号：US12637686
申请日：2009-12-14
申请人： Mark Ibsen , Sergio Mohedas
发明人： Mark Ibsen , Sergio Mohedas
IPC分类号： B01J23/75 , B01J19/00 , B01J23/745 , B01J23/72 , B01J23/78 , B01J21/08
CPC分类号： B01J37/18 , B01J23/745 , B01J23/75 , B01J23/78 , B01J37/08 , B01J37/16 , C10G2/332 , C10G2300/703
摘要： A system for activating Fischer-Tropsch catalyst comprising a reactor having a reactor outlet for overhead gas and operable under suitable conditions whereby a catalyst in a volume of liquid carrier comprising Fischer-Tropsch diesel, hydrocracking recycle oil, or a combination thereof may be activated in the presence of an activation gas; a condenser comprising an inlet fluidly connected to the reactor outlet for overhead gas and comprising a condenser outlet for condensed liquids; and a separation unit comprising an inlet fluidly connected to the condenser outlet and a separator outlet for a stream comprising primarily Fischer-Tropsch diesel; and a recycle line fluidly connecting the separator outlet, a hydrocracking unit, or both to the reactor, whereby Fischer-Tropsch diesel recovered from the reactor overhead gas, hydrocracking recycle oil, or a combination thereof may serve as liquid carrier for catalyst in the reactor. A method for activating Fischer-Tropsch catalyst is also provided.
摘要翻译：用于活化费 - 托催化剂的系统，其包括具有用于塔顶气体的反应器出口的反应器并且在合适的条件下可操作的反应器，由此在一定体积的包含费 - 托柴油，加氢裂化循环油或其组合的液体载体中的催化剂可以在活化气体的存在; 冷凝器，包括流体连接到塔顶气体的反应器出口的入口，并且包括用于冷凝液体的冷凝器出口; 以及分离单元，其包括流体连接到冷凝器出口的入口和用于主要包含费 - 托柴油的物流的分离器出口; 以及将分离器出口，加氢裂化单元或二者流体连接到反应器的循环管线，其中从反应器塔顶气体回收的费 - 托柴油，加氢裂化循环油或其组合可用作反应器中的催化剂的液体载体。还提供了一种活化费 - 托催化剂的方法。

7. 发明申请

US20090064584A1 HYDROGEN AND CARBON UTILIZATION IN SYNTHETIC FUELS PRODUCTION PLANTS 有权
标题翻译：合成燃料生产厂的氢和碳利用
公开(公告)号：US20090064584A1
公开(公告)日：2009-03-12
申请号：US12207978
申请日：2008-09-10
申请人： Sergio Mohedas , Mark Ibsen
发明人： Sergio Mohedas , Mark Ibsen
IPC分类号： C10J1/20
CPC分类号： C10J3/00 , B01J37/16 , B01J37/18 , C01B3/34 , C01B3/56 , C01B2203/0405 , C01B2203/043 , C01B2203/046 , C01B2203/0485 , C01B2203/049 , C01B2203/062 , C10G2/332 , C10G45/60 , C10G47/02 , C10G49/02 , C10G2300/1011 , C10G2300/703 , C10J2300/0916 , C10J2300/093 , C10J2300/0943 , C10J2300/1618 , C10J2300/1659 , C10J2300/1823 , C10K3/00 , Y02P20/145 , Y02P20/52 , Y02P30/20
摘要： A method of utilizing hydrogen in synthesis gas production by forming synthesis gas from one or more carbonaceous materials, the synthesis gas comprising hydrogen and carbon monoxide; separating a hydrogen-rich product and a hydrogen-lean product from the synthesis gas to yield an adjusted synthesis gas product; and activating a hydrocarbon synthesis catalyst with at least a portion of the hydrogen-lean product. A system for carrying out the method is also provided, the system including at least one hydrogen extraction unit and an activation reactor operable to activate hydrocarbon synthesis catalyst, wherein the activation reactor comprises an inlet fluidly connected with the at least one hydrogen extraction unit whereby at least a portion of a hydrogen-lean gas stream, at least a portion of a hydrogen-rich gas stream, or at least a portion of both may be introduced into the activation reactor.
摘要翻译：一种通过从一种或多种含碳材料形成合成气而在合成气生产中利用氢的方法，所述合成气包含氢气和一氧化碳; 从合成气中分离富氢产物和贫氢产物以产生经调节的合成气产物; 以及用至少一部分所述富氢产物活化烃合成催化剂。还提供了一种用于实施该方法的系统，所述系统包括至少一个氢提取单元和可操作以活化烃合成催化剂的活化反应器，其中所述活化反应器包括与所述至少一个氢提取单元流体连接的入口，贫氢气流的至少一部分，富氢气流的至少一部分或两者的至少一部分可以被引入到活化反应器中。

8. 发明授权

US08778178B2 Integrated multi-step solid/liquid separation system for Fischer-Tropsch processes 有权
标题翻译：一种用于费 - 托工艺的多步固/液分离系统
公开(公告)号：US08778178B2
公开(公告)日：2014-07-15
申请号：US12577488
申请日：2009-10-12
申请人： Sergio Mohedas , Harold A. Wright
发明人： Sergio Mohedas , Harold A. Wright
IPC分类号： B03C1/32 , B01D17/028
CPC分类号： B03C1/02 , B01J8/228 , B03C1/032 , B03C1/286 , B03C1/30 , B03C2201/18 , B03C2201/20
摘要： A system for separating liquids from solids comprising an immobilization unit comprising an immobilization vessel containing a bed of magnetizable material and a magnet configured to produce a magnetic field within the immobilization vessel, wherein the immobilization vessel further comprises an immobilization vessel outlet and an immobilization vessel inlet for a fluid comprising liquid and metal-containing particles. A method for separating solid particles from liquid by introducing a fluid comprising liquid and a first concentration of solid particles into an immobilization unit comprising an immobilization vessel and at least one magnet configured to produce high density magnetic flux lines within the immobilization vessel and/or a high field gradient at or near the surface of the magnetizable material when powered, wherein the immobilization vessel contains therein a bed of magnetizable material; and removing from the immobilization unit a product having a second particle concentration less than the first particle concentration.
摘要翻译：一种用于从固体中分离液体的系统，包括固定单元，所述固定单元包括含有可磁化材料床的固定容器和构造成在所述固定化容器内产生磁场的磁体，其中所述固定容器还包括固定容器出口和固定容器入口用于包含液体和含金属颗粒的流体。将包含液体和第一浓度的固体颗粒的流体引入固定单元中的方法，所述固定单元包括固定容器和至少一个构造成在固定化容器内产生高密度磁通线的磁体和/或在可驱动材料的表面处或附近的高场梯度，其中所述固定容器中容纳可磁化材料床; 以及从所述固定单元中除去具有小于所述第一颗粒浓度的第二颗粒浓度的产物。

9. 发明申请

US20110313061A1 PROTECTED FISCHER-TROPSCH CATALYST AND METHOD OF PROVIDING SAME TO A FISCHER-TROPSCH PROCESS 有权
标题翻译：受保护的捕获 - 传递催化剂及其提供给FISCHER-TROPSCH过程的方法
公开(公告)号：US20110313061A1
公开(公告)日：2011-12-22
申请号：US12984902
申请日：2011-01-05
申请人： Harold A. Wright , Belma Demirel , Sergio Mohedas , Bahman Rejai , Ray Huang , Deena Ferdous , Jesse W. Taylor , Dawid J. Duvenhage , Sara L. Rolfe
发明人： Harold A. Wright , Belma Demirel , Sergio Mohedas , Bahman Rejai , Ray Huang , Deena Ferdous , Jesse W. Taylor , Dawid J. Duvenhage , Sara L. Rolfe
IPC分类号： B01J8/18 , C07C1/04 , B01J37/18 , B01J31/02 , B01J37/16
CPC分类号： B01J8/006 , B01J8/18 , B01J8/1809 , B01J23/745 , B01J33/00 , B01J35/023 , B01J37/0045 , B01J37/18 , C10G2/32 , C10G2/33 , C10G2/332 , C10G2300/703
摘要： A method of preparing a spray dried catalyst by combining spray dried catalyst particles with wax so the spray dried catalyst particles are coated with wax, yielding wax coated catalyst particles, and shaping the wax coated catalyst to provide shaped wax coated catalyst. A method of activating Fischer-Tropsch catalyst particles containing oxides by contacting the catalyst particles with a reducing gas in an activation vessel to produce an activated catalyst, wherein contacting is performed in the absence of a liquid medium under activation conditions. A system for activating a Fischer-Tropsch catalyst containing an activation reactor configured to introduce an activation gas to a fixed or fluidized bed of the Fischer-Tropsch catalyst in the absence of a liquid medium and at least one separation device configured to separate a gas stream comprising entrained catalyst fines having an average particle size below a desired cutoff size from the activation reactor.
摘要翻译：通过将喷雾干燥的催化剂颗粒与蜡组合来制备喷雾干燥的催化剂的方法，使喷雾干燥的催化剂颗粒用蜡涂覆，产生蜡涂覆的催化剂颗粒，并使蜡涂覆的催化剂成形以提供成形的涂蜡催化剂。通过使催化剂颗粒与活化容器中的还原气体接触以产生活化的催化剂来活化含有氧化物的费 - 托催化剂颗粒的方法，其中在不存在液体介质的条件下进行接触。一种用于活化费 - 托催化剂的系统，其包含活化反应器，所述活化反应器配置成在没有液体介质的情况下将活化气体引入费 - 托催化剂的固定或流化床，以及至少一个分离装置，其被配置为分离气流包括夹带的催化剂细粒，其具有低于来自活化反应器的所需截留尺寸的平均粒度。

10. 发明授权

US09074148B2 Hydrogen and carbon utilization in synthetic fuels production plants 有权
标题翻译：合成燃料生产厂的氢和碳利用
公开(公告)号：US09074148B2
公开(公告)日：2015-07-07
申请号：US13248547
申请日：2011-09-29
申请人： Sergio Mohedas , Mark Ibsen
发明人： Sergio Mohedas , Mark Ibsen
IPC分类号： C01B3/34 , C01B3/56 , B01J37/16 , C10G49/02 , C10J3/00 , B01J37/18 , C10G2/00 , C10G45/60 , C10G47/02 , C10K3/00
CPC分类号： C10J3/00 , B01J37/16 , B01J37/18 , C01B3/34 , C01B3/56 , C01B2203/0405 , C01B2203/043 , C01B2203/046 , C01B2203/0485 , C01B2203/049 , C01B2203/062 , C10G2/332 , C10G45/60 , C10G47/02 , C10G49/02 , C10G2300/1011 , C10G2300/703 , C10J2300/0916 , C10J2300/093 , C10J2300/0943 , C10J2300/1618 , C10J2300/1659 , C10J2300/1823 , C10K3/00 , Y02P20/145 , Y02P20/52 , Y02P30/20
摘要： A system including at least one hydrogen extraction unit comprising an inlet for a synthesis feedgas from a synthesis feedgas line and adapted to remove at least one hydrogen-rich gas and at least one hydrogen-lean gas from the synthesis feedgas to yield a refined synthesis gas; and at least one hydrocarbon synthesis reactor, at least one dedicated activation reactor, or both, wherein the at least one hydrocarbon synthesis reactor is fluidly connected with the at least one hydrogen extraction unit and configured to provide liquid hydrocarbons and a first byproduct gas from a synthesis reactor feedstream comprising at least a portion of the refined synthesis gas; and wherein the at least one dedicated activation reactor is fluidly connected with the at least one hydrogen extraction unit, the at least one hydrocarbon synthesis reactor, or both, and configured for activation of hydrocarbon synthesis catalyst via an activation gas.
摘要翻译：一种包括至少一个氢气提取单元的系统，其包括用于从合成进料气管线合成进料气的入口，并适于从合成进料气中除去至少一种富氢气体和至少一种贫贫气体，以产生精制合成气 ; 和至少一个烃合成反应器，至少一个专用活化反应器或两者，其中所述至少一个烃合成反应器与所述至少一个氢提取单元流体连接并且构造成提供液体烃和来自第一副产物气体的第一副产物气体合成反应器进料流，其包含至少一部分精制合成气; 并且其中所述至少一个专用活化反应器与所述至少一个氢提取单元，所述至少一个烃合成反应器或两者流体连接，并且被配置为经由活化气体活化烃合成催化剂。

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