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    • 9. 发明授权
    • Mass spectrometer sampling system for a liquid stream
    • 用于液体流的质谱仪采样系统
    • US4791291A
    • 1988-12-13
    • US885362
    • 1986-07-14
    • James C. Tou
    • James C. Tou
    • H01J49/04B01D59/44
    • H01J49/0431H01J49/049
    • This invention relates to several improvements in mass spectrometric analysis. In accordance with one aspect of this invention, a mass spectrometer sampling system is provided in which a continuous flowing liquid stream can be sampled into a carrier gas stream where it is heated and vaporized. The gas and vapor mixture is transmitted into a plurality of chambers connected in series which have the effects of diluting the concentration of the vaporized liquid injected into the inert gas streams and also shaping the concentration time profile at the exit of the last chamber to be a symmetric peak. These effects have been found to provide several advantages such as prolonging the instrument operation time, and allowing a faster sample injection rate. Once the mixture has exited the last of the chambers, a molecular leak is provided to reduce the pressure to that necessary for the operation of the mass spectrometer. A series of chambers in accordance with this invention has also been found to enable very thorough mixing of reagents.
    • 本发明涉及质谱分析的几个改进。 根据本发明的一个方面,提供一种质谱仪取样系统,其中连续流动的液体流可以被采样到载气流中,在其中被加热和蒸发。 气体和蒸汽混合物被传输到串联连接的多个室中,其具有稀释注入到惰性气体流中的汽化液体的浓度的作用,并且还使最终室的出口处的浓度时间分布形成为 对称峰。 已经发现这些效果提供了几个优点,例如延长仪器操作时间,并允许更快的样品注入速率。 一旦混合物已经离开最后的室,就提供分子泄漏以将压力降低到质谱仪操作所需的压力。 还发现根据本发明的一系列室能够非常充分地混合试剂。