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1. 发明授权

US07129383B2 Processes for the preparation of 2-chloro-1,1,1,2,3,3,3-heptafluoropropane, hexafluoropropene and 1,1,1,2,3,3,3-heptafluoropropane 失效
标题翻译：制备2-氯-1,1,1,2,3,3,3-七氟丙烷，六氟丙烯和1,1,1,2,3,3,3-七氟丙烷的方法
公开(公告)号：US07129383B2
公开(公告)日：2006-10-31
申请号：US10523223
申请日：2003-08-21
申请人： Mario J. Nappa , Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Sekhar Subramoney , Munirpallam A. Subramanian , Allen C. Sievert
发明人： Mario J. Nappa , Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Sekhar Subramoney , Munirpallam A. Subramanian , Allen C. Sievert
IPC分类号： C07C17/00 , C07C17/266 , C07C17/10
CPC分类号： C07C19/08 , B01J23/26 , B01J23/866 , B01J35/002 , B01J37/0236 , B01J37/03 , B01J37/26 , C07C17/206 , C07C17/21 , C07C17/23 , C07C17/25 , C07C19/10 , C07C21/18
摘要： A process for the preparation of 2-chloro-1,1,1,3,3,3-heptafluoropropane is disclosed which involves (a) contacting a mixture comprising hydrogen fluoride, chlorine, and at least one starting material selected from the group consisting of halopropenes of the formula CX3CCI═CX2 and halopropanes of the formula the CX3CCIYCX3, wherein each X is independently F or Cl, and Y is H, Cl or F (provided that the number of X and Y which are F totals no more than six) with a chlorofluorination catalyst in a reaction zone to produce a product mixture comprising CF3CCIFCF3, HCI, HF. and underfluorinated halogenated hydrocarbon intermediates. The process is characterized by said chlorofluorination catalyst comprising at least one chromium-containing component selected from (i) a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by nickel, trivalent cobalt or both nickel and trivalent cobalt, provided that no more than 2 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by nickel and that the total amount of chromium atoms in the alpha-chromium oxide lattice that are replaced by nickel and trivalent cobalt is no more than 6 atom %, and (ii) a fluorinated crystalline oxide of (i). Also disclosed is a process for the manufacture of a mixture of HFC-227ea and hexafluoropropene by reacting a starting mixture comprising CFC-217ba and hydrogen in the vapor phase at an elevated temperature, optionally in the presence of a hydrogenation catalyst. This process involves preparing the CFC-217ba by the process described above.
摘要翻译：公开了一种制备2-氯-1,1,1,3,3,3-七氟丙烷的方法，其涉及（a）使包含氟化氢，氯和至少一种起始原料的混合物接触，所述起始材料选自的式CX3CCI-CX2的卤代丙烯和式CX3CCIYCX3的卤代丙烷，其中每个X独立地为F或Cl，Y为H，Cl或F（条件是总计X不超过6的X和Y的数目）与反应区中的氯氟化催化剂反应以产生包含CF 3 CClF 3，HCl，HF的产物混合物。和不完全氟化的卤代烃中间体。该方法的特征在于所述氯氟化催化剂包含至少一种含铬组分，其选自（i）α-氧化铬晶格中至少0.05原子％的铬原子被镍取代的结晶α-氧化铬，三价钴或镍和三价钴，条件是α-铬氧化物晶格中不超过2原子％的铬原子被镍代替，并且α-氧化铬晶格中的铬原子的总量被镍和三价钴不超过6原子％，和（ii）（i）的氟化结晶氧化物。还公开了通过在升高的温度下，任选地在氢化催化剂存在下，使包含CFC-217ba和氢的起始混合物在气相中反应制备HFC-227ea和六氟丙烯的混合物的方法。该方法包括通过上述方法制备CFC-217ba。

2. 发明授权

US07074973B2 Process for the preparation of 1,1,1,2,2-pentafluoroethane 失效
标题翻译：制备1,1,1,2,2-五氟乙烷的方法
公开(公告)号：US07074973B2
公开(公告)日：2006-07-11
申请号：US10523227
申请日：2003-08-21
申请人： Mario J. Nappa , Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Shekhar Subramoney , Munirpallam A. Subramanian , Allen C. Sievert
发明人： Mario J. Nappa , Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Shekhar Subramoney , Munirpallam A. Subramanian , Allen C. Sievert
IPC分类号： C07C17/00
CPC分类号： C07C17/206 , B01J23/864 , B01J35/002 , B01J37/0236 , B01J37/03 , B01J37/26 , C07C17/21 , Y02P20/582 , C07C19/08
摘要： A process for the preparation of pentafluoroethane is disclosed which involves contacting a mixture comprising hydrogen fluoride and at least one starting material selected from haloethanes of the formula CX3CHX2 and haloethanes of the formula CX2═CX2, where each X is independently selected from the group consisting of F and Cl (provided that no more than four of X are F), with a fluorination catalyst in a reaction zone to produce a product mixture comprising HF, HCl, pentafluoroethane, underfluorinated halogenated hydrocarbon intermediates and less than 0.2 mole percent chloropentafluoroethane based on the total moles of halogenated hydrocarbons in the product mixture. The process is characterized by the fluorination catalyst comprising (i) a crystalline cobalt-substituted alpha-chromium oxide where from about 0.05 atom % to about 6 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by trivalent cobalt (Co+3) and/or (ii) a fluorinated crystalline oxide of (i).
摘要翻译：公开了一种制备五氟乙烷的方法，其涉及将包含氟化氢和至少一种选自式CX 3 CHX 2 2的卤代乙烷的起始物质和式CX 2 -CX 2 X，其中每个X独立地选自F和Cl（条件是不超过四个X为F），与反应区中的氟化催化剂，以产生基于产物混合物中卤代烃总摩尔数的HF，HCl，五氟乙烷，过氟化卤代烃中间体和小于0.2摩尔％氯五氟乙烷的产物混合物。该方法的特征在于氟化催化剂，其包含（i）结晶钴取代的α-氧化铬，其中α-氧化铬晶格中约0.05原子％至约6原子％的铬原子被三价钴（Co （ⅰ））和/或（ⅱ）氟化结晶氧化物。

3. 发明授权

US07217678B2 Cobalt-substituted chromium oxide compositions, their preparation, and their use as catalysts and catalyst precursors 有权
标题翻译：钴取代的氧化铬组合物，它们的制备及其作为催化剂和催化剂前体的用途
公开(公告)号：US07217678B2
公开(公告)日：2007-05-15
申请号：US10523228
申请日：2003-08-21
申请人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen C. Sievert , Shekhar Subramoney , Munirpallam Appadorai Subramanian
发明人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen C. Sievert , Shekhar Subramoney , Munirpallam Appadorai Subramanian
IPC分类号： B01J27/06 , B01J23/00
CPC分类号： C07C17/21 , B01J23/864 , B01J35/002 , B01J35/1014 , B01J37/0236 , B01J37/03 , C07C17/00 , C07C17/08 , C07C17/10 , C07C17/20 , C07C17/206 , C07C17/23 , C07C17/25 , C07C17/358 , C07C17/37 , C07C21/18 , C07C21/04 , C07C19/08 , C07C21/06 , C07C19/12 , C07C19/10
摘要： A crystalline alpha-chromium oxide where from about 0.05 atom % to about 6 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by trivalent cobalt (Co+3) atoms is disclosed. Also disclosed is a chromium-containing catalyst composition comprising as a chromium-containing component the crystalline cobalt-substituted alpha-chromium oxide; and a method for preparing a composition comprising the crystalline cobalt-substituted alpha-chromium oxide. The method involves (a) co-precipitating a solid by adding ammonium hydroxide to an aqueous solution of a soluble cobalt salt and a soluble trivalent chromium salt that contains at least three moles of nitrate per mole of chromium in the solution and has a cobalt concentration of from about 0.05 mole % to about 6 mole % of the total concentration of cobalt and chromium in the solution; and after at least three moles E of ammonium per mole of chromium in the solution has been added to the solution, (b) collecting the co-precipitated solid formed in (a); (c) drying the collected solid; and (d) calcining the dried solid. Also disclosed is a chromium-containing catalyst composition comprising a chromium-containing component prepared by treating the crystalline cobalt-substituted alpha-chromium oxide with a fluorinating agent; and a process for changing the fluorine distribution (i.e., content and/or arrangement) in a hydrocarbon or halogenated hydrocarbon in the presence of a catalyst. The process involves using as the catalyst a composition comprising the crystalline cobalt-substituted alpha-chromium oxide and/or the treated cobalt-substituted alpha-chromium oxide.
摘要翻译：公开了一种结晶α-Cr氧化物，其中α-Cr氧化物晶格中约0.05原子％至约6原子％的铬原子被三价钴（Co + O 3+）原子所取代。还公开了含铬催化剂组合物，其包含结晶钴取代的α-氧化铬作为含铬组分; 以及制备包含结晶钴取代的α-氧化铬的组合物的方法。该方法包括（a）通过向可溶性钴盐和可溶性三价铬盐的水溶液中加入氢氧化铵共沉淀固体，该溶液在溶液中每摩尔铬含有至少三摩尔硝酸盐，并且具有钴浓度为溶液中钴和铬的总浓度的约0.05摩尔％至约6摩尔％并且在溶液中每摩尔铬至少三摩尔E之后的铵加入到溶液中，（b）收集（a）中形成的共沉淀固体; （c）干燥收集的固体; 和（d）煅烧干燥的固体。还公开了一种含铬催化剂组合物，其包含通过用氟化剂处理结晶钴取代的α-氧化铬制备的含铬组分; 以及在催化剂存在下改变烃或卤代烃中的氟分布（即含量和/或排列）的方法。该方法包括使用包含结晶钴取代的α-氧化铬和/或经处理的钴取代的α-氧化铬的组合物作为催化剂。

4. 发明授权

US07504358B2 Nickel-substituted and mixed nickel-and cobalt-substituted chromium oxide compositions, their preparation, and their use as catalysts and catalysts precursors 有权
公开(公告)号：US07504358B2
公开(公告)日：2009-03-17
申请号：US10523226
申请日：2003-08-21
申请人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen C. Sievert , Shekhar Subramoney , Munirpallam Appadorai Subramanian
发明人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen C. Sievert , Shekhar Subramoney , Munirpallam Appadorai Subramanian
IPC分类号： B01J23/00 , C07C19/08 , C07C21/00
CPC分类号： C07C17/37 , B01J23/26 , B01J23/866 , B01J35/0013 , B01J35/002 , B01J35/006 , B01J35/023 , B01J35/1014 , B01J37/0236 , B01J37/03 , C07C17/08 , C07C17/10 , C07C17/206 , C07C17/21 , C07C17/23 , C07C17/25 , C07C17/358 , C07C19/10
摘要： A crystalline alpha-chromium oxide where from about 0.05 atom % to about 2 atom % of the chromium atoms in the alpha-chromium oxide lattice are substituted by nickel atoms, and optionally, additional chromium atoms in the alpha-chromium oxide lattice are substituted by trivalent cobalt atoms (provided that the total amount of the nickel atoms and the trivalent cobalt atoms in the alpha-chromium oxide lattice is no more than 6 atom %) is disclosed. Also disclosed is a chromium-containing catalyst composition comprising as a chromium-containing component the crystalline substituted alpha-chromium oxide; and a method for preparing a composition comprising the crystalline substituted alpha-chromium oxide. The method comprises (a) co-precipitating a solid by adding ammonium hydroxide to an aqueous solution of a soluble divalent nickel salt, a soluble trivalent chromium salt, and optionally, a soluble divalent or trivalent cobalt salt, that contains at least three moles of nitrate per mole of chromium in the solution, has a nickel concentration of from about 0.05 mole % to about 2 mole % of the total of nickel, chromium, and cobalt in the solution, and has a combined concentration of nickel and cobalt of no more than 6 mole % of the total of nickel, chromium, and cobalt in the solution; and after at least three moles of ammonium per mole of chromium has been added to the solution; (b) collecting the co-precipitated solid formed in (a); (c) drying the collected solid; and (d) calcining the dried solid. Also disclosed is a chromium-containing catalyst composition comprising a chromium-containing component prepared by treating said crystalline substituted alpha-chromium oxide with a fluorinating agent; and a process for changing the fluorine distribution (i.e., content and/or arrangement) in a hydrocarbon or halogenated hydrocarbon in the presence of a catalyst. The process involves using as the catalyst a composition comprising the crystalline substituted alpha-chromium oxide and/or the treated substituted alpha-chromium oxide.

5. 发明申请

US20110118514A1 Process for the Preparation of 1,1,1,3,3,3-Hexafluoro-Propane and at Least One Of 1,1,1,2,3,3-Hexafluoropropane, Hexafluoropropane and 1,1,1,2,3,3,3-Heptafluoropropane 失效
标题翻译： 1,1,1,3,3,3-六氟丙烷的制备方法和1,1,1,2,3,3-六氟丙烷，六氟丙烷和1,1,1,2,3 ，3,3-七氟丙烷
公开(公告)号：US20110118514A1
公开(公告)日：2011-05-19
申请号：US11988258
申请日：2006-08-04
申请人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
发明人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
IPC分类号： C07C17/23 , C07C17/20
CPC分类号： B01J37/26 , B01J23/868 , C07C17/21 , C07C17/23 , C07C19/08 , C07C21/18 , C07C19/10
摘要： A process is disclosed for the manufacture of 1,1,1,3,3,3-hexafluoropropane and 1,1,1,2,3,3-hexafluoropropane, hexafluoropropene and/or 1,1,1,2,3,3,3-heptafluoropropane. The process involves (a) reacting HF, Cl2, and at least one halopropene of the formula CX3CCI═CCIX (where each X is independently F or CI) to produce a product comprising CF3CCI2CF3 and CF3CCIFCCIF2; (b) reacting CF3CCI2CF3 and CF3CCIFCCIF2 produced in (a) with hydrogen, optionally in the presence of HF, to produce a product comprising CF3CH2CF3 and at least one of CHF2CHFCF3, CF3CF═CF2 and CF3CFHCF3; and (c) recovering from the product produced in (b), CF3CH2CF3 and at least one of CHF2CHFCF3, CF3CF═CF2 and CF3CFHCF3. In (a), the CF3CCI2CF3 and CF3CCIFCCIF2 are produced in the presence of a chlorofluorination catalyst including (i) a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by divalent copper, and/or (ii) a chromium-containing composition of (i) which has been treated with a fluorinating agent.
摘要翻译：公开了用于制造1,1,1,3,3,3-六氟丙烷和1,1,1,2,3,3-六氟丙烷，六氟丙烯和/或1,1,1,2,3， 3,3-七氟丙烷。该方法包括（a）使HF，Cl 2和至少一种式CX3CCI = CCIX（其中每个X独立地为F或Cl）的卤代丙烯反应，以产生包含CF 3 CCl 2 CF 3和CF 3 CClFCCIF 2的产物; （b）任选地在HF存在下使（a）中产生的CF 3 CCl 2 CF 3和CF 3 CClF CIFF 2与氢反应，以产生包含CF 3 CH 2 CF 3和CHF 2 CHFCF 3，CF 3CF≡CF2和CF 3 CFHCF 3中的至少一种的产物; 和（c）从（b）中产生的产物，CF 3 CH 2 CF 3和CHF 2 CHFCF 3，CF 3CF≡CF2和CF 3 CFHCF 3中的至少一种中回收。在（a）中，CF 3 CCl 2 CF 3和CF 3 CClFCCIF 2在氯氟化催化剂存在下制备，包括（i）α-氧化铬晶格中至少0.05原子％的铬原子被二价铜取代的结晶α-氧化铬，和/或（ⅱ）已经用氟化剂处理的（ⅰ）的含铬组合物。

6. 发明授权

US08017817B2 Process for the preparation of 1,1,3,3,3-pentafluoropropene and 1,2,3,3,3-pentafluoropropene 失效
标题翻译：制备1,1,3,3,3-五氟丙烯和1,2,3,3,3-五氟丙烯的方法
公开(公告)号：US08017817B2
公开(公告)日：2011-09-13
申请号：US11988257
申请日：2006-08-04
申请人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
发明人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
IPC分类号： C07C7/00
CPC分类号： B01J37/03 , B01J23/868 , B01J37/0009 , B01J37/26 , C07C17/21 , C07C17/23 , C07C17/25 , C07C21/18 , C07C19/10 , C07C19/08
摘要： A process for the manufacture of CF3CH═CF2 and CF3CF═CHF is disclosed. The process involves (a) reacting HF and chlorine and at least one halopropene of the formula CX3CCI═CCIX (where each X is independently F or Cl) to produce a product including both CF3CCI2CF3 and CF3CCIFCCIF2; (b) reacting CF3CCI2CF3 and CF3CCIFCCIF2 produced in (a) with hydrogen to produce a product including both CF3CH2CF3 and CF3CHFCHF2; (c) dehydrofluorinating CF3CH2CF3 and CF3CHFCHF2 produced in (b) to produce a product including both CF3CH═CF2 and CF3CF═CHF; and (d) recovering CF3CH═CF2 and CF3CF═CHF from the product produced in (c). In (a), both CF3CCI2CF3 and CF3CCIFCCIF2 are produced in the presence of a chlorofluorination catalyst consisting of (i) compositions comprising a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by copper, and (H) compositions of (i) which have been treated with a fluorinating agent.
摘要翻译：公开了制备CF 3 CH 2 CF 2和CF 3 CF = CHF的方法。该方法包括（a）使HF和氯与至少一种式CX3CCI = CCIX的卤代丙烯（其中每个X独立地为F或Cl）反应，以产生包含CF 3 CCl 2 CF 3和CF 3 CClFCCIF 2的产物; （b）使（a）中制备的CF 3 CCl 2 CF 3和CF 3 CClFCCIF 2与氢反应以产生包含CF 3 CH 2 CF 3和CF 3 CHFCHF 2的产物; （c）在（b）中制备的CF 3 CH 2 CF 3和CF 3 CHFCHF 2脱氟化氟化产生包括CF 3 CH 2 CF 2和CF 3 CF = CHF的产物; 和（d）从（c）中制备的产物中回收CF 3CH≡CF2和CF 3 CF = CHF。在（a）中，CF 3 CCl 2 CF 3和CF 3 CClFCCIF 2均在氯氟化催化剂存在下制备，所述氯氟化催化剂由（i）包含α-氧化铬晶格中至少0.05原子％的铬原子的结晶α-氧化铬的组合物组成通过铜和（H）组合物（i）已用氟化剂处理。

7. 发明授权

US07659436B2 Process for the preparation of 1,1,1,3,3-penta-fluoropropane and/or 1,1,1,3,3,3-hexafluoropropane 失效
标题翻译：制备1,1,1,3,3-五氟丙烷和/或1,1,1,3,3,3-六氟丙烷的方法
公开(公告)号：US07659436B2
公开(公告)日：2010-02-09
申请号：US11988436
申请日：2006-08-04
申请人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
发明人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
IPC分类号： C07C17/00 , C07C17/10
CPC分类号： B01J23/868 , B01J37/0009 , B01J37/03 , C07C17/206 , C07C17/21 , C07C17/23 , C07C17/25 , C07C19/08 , C07C21/18 , C07C19/10
摘要： A process for the manufacture of CF3CH2CHF2 and/or CF3CH2CF3 is disclosed. The process involves (a) reacting HF and at least one halopropene of the formula CX3CCI═CCIX (where each X is independently F or Cl) to produce a product including both CF3CCI═CF2 and CF3CHCICF3; (b) reacting CF3CCI═CF2 and/or CF3CHCICF3 produced in (a) with hydrogen to produce a product including CF3CH2CHF2 and/or CF3CH2CF3; and (c) recovering CF3CH2CHF2 and/or CF3CH2CF3 from the product produced in (b). In (a), the CF3CCI═CF2 and CF3CHCICF3 are produced in the presence of a fluorination catalyst comprising at least one chromium-containing component selected from (i) a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by divalent copper, and (ii) a chromium-containing composition of (i) which has been treated with a fluorinating agent.
摘要翻译：公开了制备CF 3 CH 2 CHF 2和/或CF 3 CH 2 CF 3的方法。该方法包括（a）使HF和式CX3CCI-CCIX（其中每个X独立地为F或Cl）至少一种卤代丙烯反应以产生包含CF 3 CCl-CF 2和CF 3 CHCICF 3的产物; （b）使（a）中制备的CF 3 CCl-CF 2和/或CF 3 CHCICF 3与氢反应以产生包含CF 3 CH 2 CHF 2和/或CF 3 CH 2 CF 3的产物; 和（c）从（b）中制备的产物中回收CF 3 CH 2 CHF 2和/或CF 3 CH 2 CF 3。在（a）中，CF 3 CCl-CF 2和CF 3 CHCICF 3在含有至少一种含铬组分的氟化催化剂的存在下制备，所述含铬组分选自（i）结晶α-氧化铬，其中至少0.05原子％所述α-氧化铬晶格被二价铜取代，和（ii）已经用氟化剂处理的（i）的含铬组合物。

8. 发明授权

US08053611B2 Process or the preparation of 1,1,1,3,3,3-hexafluoro-propane and at least one of 1,1,1,2,3,3-hexafluoropropane, hexafluoropropane and 1,1,1,2,3,3,3-heptafluoropropane 失效
标题翻译： 1,1,1,3,3,3-六氟丙烷和1,1,1,2,3,3-六氟丙烷，六氟丙烷和1,1,1,2,3中的至少一种的方法或制备，3,3-七氟丙烷
公开(公告)号：US08053611B2
公开(公告)日：2011-11-08
申请号：US11988258
申请日：2006-08-04
申请人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
发明人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
IPC分类号： C07C17/00
CPC分类号： B01J37/26 , B01J23/868 , C07C17/21 , C07C17/23 , C07C19/08 , C07C21/18 , C07C19/10
摘要： A process is disclosed for the manufacture of 1,1,1,3,3,3-hexafluoropropane and 1,1,1,2,3,3-hexafluoropropane, hexafluoropropene and/or 1,1,1,2,3,3,3-heptafluoropropane. The process involves (a) reacting HF, Cl2, and at least one halopropene of the formula CX3CCl═CClX (where each X is independently F or Cl) to produce a product comprising CF3CCl2CF3 and CF3CClFCClF2; (b) reacting CF3CCl2CF3 and CF3CClFCClF2 produced in (a) with hydrogen, optionally in the presence of HF, to produce a product comprising CF3CH2CF3 and at least one of CHF2CHFCF3, CF3CF═CF2 and CF3CFHCF3; and (c) recovering from the product produced in (b), CF3CH2CF3 and at least one of CHF2CHFCF3, CF3CF═CF2 and CF3CFHCF3. In (a), the CF3CCl2CF3 and CF3CClFCClF2 are produced in the presence of a chlorofluorination catalyst including (i) a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by divalent copper, and/or (ii) a chromium-containing composition of (i) which has been treated with a fluorinating agent.
摘要翻译：公开了用于制造1,1,1,3,3,3-六氟丙烷和1,1,1,2,3,3-六氟丙烷，六氟丙烯和/或1,1,1,2,3， 3,3-七氟丙烷。该方法包括（a）使HF，Cl 2和至少一种式CX3CCl = CClX（其中每个X独立地为F或Cl）的卤代丙烯反应以产生包含CF 3 CCl 2 CF 3和CF 3 CClFCClF 2的产物; （b）使（a）中制备的CF 3 CCl 2 CF 3和CF 3 CClFCClF与任选在HF存在下的氢反应，生成包含CF 3 CH 2 CF 3和CHF 2 CHFCF 3，CF 3CF≡CF2和CF 3 CFHCF 3中的至少一种的产物; 和（c）从（b）中产生的产物，CF 3 CH 2 CF 3和CHF 2 CHFCF 3，CF 3CF≡CF2和CF 3 CFHCF 3中的至少一种中回收。在（a）中，CF 3 CCl 2 CF 3和CF 3 CClFCClF 2在氯氟化催化剂的存在下制备，包括（i）结晶α-氧化铬，其中至少0.05原子％的α-氧化铬晶格中的铬原子被二价铜，和/或（ⅱ）已经用氟化剂处理的（ⅰ）的含铬组合物。

9. 发明申请

US20110105808A1 Process for the Preparation of 1,1,3,3,3-Pentafluoropropene and 1,2,3,3,3-Pentafluoropropene 失效
标题翻译：制备1,1,3,3,3-五氟丙烯和1,2,3,3,3-五氟丙烯的方法
公开(公告)号：US20110105808A1
公开(公告)日：2011-05-05
申请号：US11988257
申请日：2006-08-04
申请人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
发明人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
IPC分类号： C07C17/08
CPC分类号： B01J37/03 , B01J23/868 , B01J37/0009 , B01J37/26 , C07C17/21 , C07C17/23 , C07C17/25 , C07C21/18 , C07C19/10 , C07C19/08
摘要： A process for the manufacture of CF3CH═CF2 and CF3CF═CHF is disclosed. The process involves (a) reacting HF and chlorine and at least one halopropene of the formula CX3CCl═CClX (where each X is independently F or Cl) to produce a product including both CF3CCl2CF3 and CF3CCIFCClF2; (b) reacting CF3CCl2CF3 and CF3CCIFCClF2 produced in (a) with hydrogen to produce a product including both CF3CH2CF3 and CF3CHFCHF2; (c) dehydrofluorinating CF3CH2CF3 and CF3CHFCHF2 produced in (b) to produce a product including both CF3CH═CF2 and CF3CF═CHF; and (d) recovering CF3CH═CF2 and CF3CF═CHF from the product produced in (c). In (a), both CF3CCl2CF3 and CF3CCIFCClF2 are produced in the presence of a chlorofluorination catalyst consisting of (i) compositions comprising a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by copper, and (H) compositions of (i) which have been treated with a fluorinating agent.
摘要翻译：公开了制备CF 3 CH 2 CF 2和CF 3 CF = CHF的方法。该方法包括（a）使HF和氯与至少一种式CX3CCl = CClX（其中每个X独立地为F或Cl）的卤代丙烯反应以产生包含CF 3 CCl 2 CF 3和CF 3 CClFFCClF 2的产物; （b）使（a）中制备的CF 3 CCl 2 CF 3和CF 3 CClFFCClF与氢反应以产生包含CF 3 CH 2 CF 3和CF 3 CHFCHF 2的产物; （c）在（b）中制备的CF 3 CH 2 CF 3和CF 3 CHFCHF 2脱氟化氟化产生包括CF 3 CH 2 CF 2和CF 3 CF = CHF的产物; 和（d）从（c）中制备的产物中回收CF 3CH≡CF2和CF 3 CF = CHF。在（a）中，CF 3 CCl 2 CF 3和CF 3 CClFFCClF 2是在氯氟化催化剂存在下制备的，所述氯氟化催化剂由（i）包含α-氧化铬晶格中至少0.05原子％的铬原子的结晶α-氧化铬的组合物组成通过铜和（H）组合物（i）已用氟化剂处理。

10. 发明申请

US20100152503A1 Copper-Substituted Chromium Oxide Compositions, Their Preparation, and Their Use as Catalysts and Catalyst Precursors 审中-公开
公开(公告)号：US20100152503A1
公开(公告)日：2010-06-17
申请号：US11988256
申请日：2006-08-04
申请人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Sievert , Shekhar Subramoney
发明人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Sievert , Shekhar Subramoney
IPC分类号： C07C17/358 , C07C17/00 , C07C17/37 , C01G37/02 , B01J23/26
CPC分类号： B01J23/868 , B01J37/0009 , B01J37/0236 , B01J37/03 , B01J37/26 , C07C17/206 , C07C17/21 , C07C17/25 , C07C17/358 , C07C17/37 , C07C21/18 , C07C19/10
摘要： A crystalline alpha-chromium oxide where from about 0.05 atom % to about 5 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by divalent copper (Cu+2) atoms is disclosed. Also disclosed is a chromium-containing catalyst composition comprising as a chromium-containing component the crystalline copper-substituted alpha-chromium oxide; and methods for preparing a composition comprising the crystalline copper-substituted alpha-chromium oxide. One method involves (a) co-precipitating a solid by adding ammonium hydroxide to an aqueous solution of a soluble copper salt and a soluble trivalent chromium salt that contains at least three moles of nitrate per mole of chromium in the solution and has a copper concentration of from about 0.05 atom % to about 5 atom % of the total concentration of copper and chromium in the solution; and after at least three moles of ammonium per mole of chromium in the solution has been added to the solution, (b) collecting the co-precipitated solid formed in (a); (c) drying the collected solid; and (d) calcining the dried solid. Another method involves (a) preparing an aqueous solution of a soluble copper salt and a soluble trivalent chromium salt that contains a copper concentration of from about 0.05 atom % to about 5 atom % of the total concentration of copper and chromium in the solution, (b) evaporating the solution to dryness, and (c) calcining the dried solid. Also disclosed is a chromium-containing catalyst composition comprising a chromium-containing component prepared by treating the crystalline copper-substituted alpha-chromium oxide with a fluorinating agent; and a process for changing the fluorine distribution (i.e., content and/or arrangement) in a hydrocarbon or halogenated hydrocarbon in the presence of a catalyst. The process involves using as the catalyst a composition comprising the crystalline copper-substituted alpha-chromium oxide and/or the treated copper-substituted alpha-chromium oxide.

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