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1. 发明授权

US07932407B2 Olefin epoxidation process and a catalyst for use in the process 有权
标题翻译：烯烃环氧化方法和用于该方法的催化剂
公开(公告)号：US07932407B2
公开(公告)日：2011-04-26
申请号：US10816080
申请日：2004-04-01
申请人： Marek Matusz , Ruth Mary Kowaleski
发明人： Marek Matusz , Ruth Mary Kowaleski
IPC分类号： C07D301/10 , C07D301/03
CPC分类号： C07C29/106 , B01J21/04 , B01J23/66 , B01J23/687 , B01J23/688 , B01J35/1009 , B01J37/0203 , C07D301/10 , Y02P20/52 , C07C31/202
摘要： A process for the epoxidation of an olefin, which process comprises reacting a feed comprising an olefin, oxygen and an organic halide, in the presence of a catalyst comprising silver and rhenium deposited on a carrier, wherein the catalyst comprises rhenium in a quantity of at most 1.5 mmole/kg, relative to the weight of the catalyst, and at most 0.0015 mmole/m2, relative to the surface area of the carrier, and in which process the reaction temperature is increased to at least partly reduce the effect of loss of activity of the catalyst while the organic halide is present in a relative quantity Q which is maintained constant as defined herein.
摘要翻译：一种烯烃环氧化方法，该方法包括在包含沉积在载体上的银和铼的催化剂存在下使包含烯烃，氧和有机卤化物的进料反应，其中催化剂包含一定量的铼相对于催化剂的重量，最多为1.5mmol / kg，相对于载体的表面积为至多0.0015mmole / m 2，并且在该过程中，反应温度升高至少部分降低损失的影响有机卤化物存在的相对量Q保持恒定的催化剂的活性，如本文所定义的。

2. 发明授权

US10532989B2 Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine 有权
公开(公告)号：US10532989B2
公开(公告)日：2020-01-14
申请号：US12116905
申请日：2008-05-07
申请人： Marek Matusz
发明人： Marek Matusz
IPC分类号： C07D301/10 , C07C213/04 , B01J23/68 , B01J27/188 , C07C68/04 , B01J23/00 , C07C29/10 , B01J27/055
摘要： A catalyst for the epoxidation of an olefin comprising a carrier and, deposited on the carrier, silver, a rhenium promoter, a first co-promoter, and a second co-promoter; wherein the quantity of the rhenium promoter deposited on the carrier is greater than 1 mmole/kg, relative to the weight of the catalyst;the first co-promoter is selected from sulfur, phosphorus, boron, and mixtures thereof; the second co-promoter is selected from tungsten, molybdenum, chromium, and mixtures thereof; andthe total quantity of the first co-promoter and the second co-promoter deposited on the carrier is at most 3.8 mmole/kg, relative to the weight of the catalyst;a process for preparing the catalyst; a process for preparing an olefin oxide by reacting a feed comprising an olefin and oxygen in the presence of the catalyst; and a process for preparing a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine.

3. 发明授权

US09527787B2 Process for the preparation of alkylene carbonate and/or alkylene glycol 有权
标题翻译：制备碳酸亚烷基酯和/或亚烷基二醇的方法
公开(公告)号：US09527787B2
公开(公告)日：2016-12-27
申请号：US13462490
申请日：2012-05-02
申请人： Wayne Errol Evans , Marek Matusz , Eugene Marie Godfried Andre Van Kruchten , Martin Lysle Hess
发明人： Wayne Errol Evans , Marek Matusz , Eugene Marie Godfried Andre Van Kruchten , Martin Lysle Hess
IPC分类号： B01J19/00 , C07C29/12 , B01D53/02 , B01D53/70 , C07C29/10
CPC分类号： C07C29/12 , B01D53/02 , B01D53/70 , B01D2253/112 , B01D2255/104 , B01D2257/2068 , C07C29/106 , Y02P20/154 , Y02P20/52 , C07C31/202
摘要： The invention provides a reaction system for the production of an alkylene carbonate and/or an alkylene glycol comprising: an epoxidation zone containing an epoxidation catalyst located within an epoxidation reactor; a carboxylation zone containing an iodide-containing carboxylation catalyst located within an alkylene oxide absorber; and one or more purification zones containing a purification absorbent capable of reducing the quantity of iodide-containing impurities in a feed comprising a recycle gas, which purification zones are located upstream from the epoxidation zone; and a process for the production of an alkylene carbonate and/or an alkylene glycol.
摘要翻译：本发明提供了一种用于生产碳酸亚烷基酯和/或亚烷基二醇的反应体系，包括：含有位于环氧化反应器内的环氧化催化剂的环氧化区; 含有位于烯化氧吸收剂内的含碘化物羧化催化剂的羧化区; 以及一个或多个纯化区，其含有能够减少包含循环气体的进料中的含碘化物杂质的净化吸收剂，该净化区位于环氧化区的上游; 以及制备碳酸亚烷基酯和/或亚烷基二醇的方法。

4. 发明授权

US08937031B2 Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide 有权
标题翻译：环氧化催化剂，制备催化剂的方法以及生产烯烃氧化物的方法
公开(公告)号：US08937031B2
公开(公告)日：2015-01-20
申请号：US13581641
申请日：2011-02-24
申请人： John Robert Lockemeyer , Marek Matusz , Randall Clayton Yeates
发明人： John Robert Lockemeyer , Marek Matusz , Randall Clayton Yeates
IPC分类号： B01J21/00 , B01J23/00 , B01J25/00 , B01J29/00 , B01J31/00 , B01J27/047 , C07C213/04 , B01J27/051 , B01J27/188 , B01J27/19 , B01J35/10 , B01J37/02 , C07D301/10
CPC分类号： B01J27/051 , B01J27/047 , B01J27/188 , B01J27/19 , B01J35/108 , B01J35/1095 , B01J37/0201 , C07C213/04 , C07D301/10 , Y02P20/142 , C07C215/08
摘要： A catalyst for the epoxidation of an olefin comprising a carrier and, deposited thereon, silver, a rhenium promoter, a first co-promoter, and a second co-promoter; wherein the quantity of the rhenium promoter deposited on the carrier is greater than 1 mmole/kg, relative to the weight of the catalyst; the first co-promoter is selected from sulfur, phosphorus, boron, and mixtures thereof; the second co-promoter is selected from tungsten, molybdenum, chromium, and mixtures thereof; the total quantity of the first co-promoter and the second co-promoter deposited on the carrier is at most 5.0 mmole/kg, relative to the weight of the catalyst; and wherein the carrier has a monomodal, bimodal or multimodal pore size distribution, a pore diameter of 0.01-200 μm, a specific surface area of 0.03-10 m2/g, a pore volume of 0.2-0.7 cm3/g, wherein the median pore diameter is 0.1-100 μm, and a water absorption of 10-80%.
摘要翻译：一种用于环氧化包含载体并在其上沉积有银，铼助催化剂，第一共助催化剂和第二共助催化剂的烯烃的催化剂; 其中沉积在载体上的铼助催化剂的量相对于催化剂的重量大于1mmol / kg; 第一共助催化剂选自硫，磷，硼及其混合物; 第二共助催化剂选自钨，钼，铬及其混合物; 沉积在载体上的第一助催化剂和第二助催化剂的总量相对于催化剂的重量为至多5.0mmol / kg; 并且其中所述载体具有单峰，双峰或多峰孔径分布，孔径为0.01-200μm，比表面积为0.03-10m 2 / g，孔体积为0.2-0.7cm 3 / g，其中中值孔径为0.1〜100μm，吸水率为10-80％。

5. 发明授权

US08921586B2 Process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine 有权
标题翻译：制备烯烃氧化物，1,2-二醇，1,2-二醇醚，1,2-碳酸酯或链烷醇胺的方法
公开(公告)号：US08921586B2
公开(公告)日：2014-12-30
申请号：US12437258
申请日：2009-05-07
申请人： Marek Matusz
发明人： Marek Matusz
IPC分类号： C07D301/10
CPC分类号： C07D301/10
摘要： A process for the epoxidation of an olefin comprising contacting a reactor feed comprising an olefin, oxygen, and carbon dioxide, with a catalyst comprising a carrier and, deposited on the carrier, silver, a rhenium promoter, and a potassium promoter; wherein the carbon dioxide is present in the reactor feed in a quantity of at most 3 mole percent based on the total epoxidation reactor feed; the potassium promoter is deposited on the carrier in a quantity of at least 0.5 mmole/kg, relative to the weight of the catalyst; and the carrier contains water leachable potassium in a quantity of less than 55 parts per million by weight, relative to the weight of the carrier; a process for preparing a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine.
摘要翻译：一种烯烃的环氧化方法，包括使包含烯烃，氧和二氧化碳的反应器进料与包含载体的催化剂接触，并沉积在载体上，银，铼促进剂和钾促进剂; 其中基于总环氧化反应器进料，二氧化碳以至多3摩尔％的量存在于反应器进料中; 相对于催化剂的重量，钾促进剂以至少0.5mmol / kg的量沉积在载体上; 载体含有相对于载体重量小于55重量份的水可浸出钾; 制备1,2-二醇，1,2-二醇醚，1,2-碳酸酯或链烷醇胺的方法。

6. 发明申请

US20090281345A1 PROCESS FOR THE PRODUCTION OF AN OLEFIN OXIDE, A 1,2-DIOL, A 1,2-DIOL ETHER, A 1,2-CARBONATE, OR AN ALKANOLAMINE 有权
标题翻译：生产氧化烯，1,2-二醇，1,2-二醇醚，1,2-二碳酸酯或烷醇胺的方法
公开(公告)号：US20090281345A1
公开(公告)日：2009-11-12
申请号：US12437258
申请日：2009-05-07
申请人： Marek Matusz
发明人： Marek Matusz
IPC分类号： C07C29/48 , C07C69/96 , C07C41/02 , C07C209/68
CPC分类号： C07D301/10
摘要： A process for the epoxidation of an olefin comprising contacting a reactor feed comprising an olefin, oxygen, and carbon dioxide, with a catalyst comprising a carrier and, deposited on the carrier, silver, a rhenium promoter, and a potassium promoter; wherein the carbon dioxide is present in the reactor feed in a quantity of at most 3 mole percent based on the total epoxidation reactor feed; the potassium promoter is deposited on the carrier in a quantity of at least 0.5 mmole/kg, relative to the weight of the catalyst; and the carrier contains water leachable potassium in a quantity of less than 55 parts per million by weight, relative to the weight of the carrier; a process for preparing a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine.
摘要翻译：一种烯烃的环氧化方法，包括使包含烯烃，氧和二氧化碳的反应器进料与包含载体的催化剂接触，并沉积在载体上，银，铼促进剂和钾促进剂; 其中基于总环氧化反应器进料，二氧化碳以至多3摩尔％的量存在于反应器进料中; 相对于催化剂的重量，钾促进剂以至少0.5mmol / kg的量沉积在载体上; 载体含有相对于载体重量小于55重量份的水可浸出钾; 制备1,2-二醇，1,2-二醇醚，1,2-碳酸酯或链烷醇胺的方法。

7. 发明申请

US20090275764A1 OLEFIN EPOXIDATION PROCESS, A CATALYST FOR USE IN THE PROCESS, A CARRIER FOR USE IN PREPARING THE CATALYST, AND A PROCESS FOR PREPARING THE CARRIER 有权
标题翻译：烯烃环氧化方法，在该方法中使用的催化剂，用于制备催化剂的载体和用于制备载体的方法
公开(公告)号：US20090275764A1
公开(公告)日：2009-11-05
申请号：US12502850
申请日：2009-07-14
申请人： Randall Clayton YEATES , John Robert Lockemeyer , Marek Matusz
发明人： Randall Clayton YEATES , John Robert Lockemeyer , Marek Matusz
IPC分类号： C07D301/03 , B01J23/10 , C07C41/02 , C07C29/10
CPC分类号： B01J21/04 , B01J23/02 , B01J23/10 , B01J23/50 , B01J23/688 , B01J27/138 , B01J35/002 , C07C29/106 , C07D301/10 , Y02P20/142 , C07C31/20
摘要： A process is provided for preparing a carrier which process comprises incorporating into the carrier at any stage of the carrier preparation a strength-enhancing additive. Also provided is the resultant carrier having incorporated therein a strength-enhancing additive and a catalyst comprising the carrier. Also provided is a process for the epoxidation of an olefin employing the catalyst. Also provided is a method of using the olefin oxide so produced for making a 1,2-diol, a 1,2-diol ether or an alkanolamine.
摘要翻译：提供了一种制备载体的方法，该方法包括在载体制备的任何阶段在载体中引入强度增强添加剂。还提供了其中结合有强度增强添加剂的所得载体和包含载体的催化剂。还提供了使用该催化剂对烯烃进行环氧化的方法。还提供了使用如此制备的用于制备1,2-二醇，1,2-二醇醚或链烷醇胺的烯烃氧化物的方法。

8. 发明授权

US08858893B2 Process for the preparation of an alkylene carbonate and an alkylene glycol 有权
标题翻译：制备碳酸亚烷基酯和亚烷基二醇的方法
公开(公告)号：US08858893B2
公开(公告)日：2014-10-14
申请号：US13591982
申请日：2012-08-22
申请人： Wayne Errol Evans , Martin Lysle Hess , Marek Matusz , Eugene Marie Godfried Andre Van Kruchten
发明人： Wayne Errol Evans , Martin Lysle Hess , Marek Matusz , Eugene Marie Godfried Andre Van Kruchten
IPC分类号： B01J8/00 , C07C29/12 , C07C29/10 , C07D301/10
CPC分类号： C07D301/10 , B01D2255/104 , B01D2255/2022 , B01D2255/2092 , B01D2257/2062 , B01D2259/40 , C07C29/106 , C07C29/12 , Y02C10/08 , Y02P20/52 , C07C31/202
摘要： The invention provides a reaction system for the production of an alkylene carbonate comprising: an epoxidation zone containing an epoxidation catalyst located within an epoxidation reactor; a carboxylation zone containing an bromide-containing carboxylation catalyst located within an alkylene oxide absorber; and one or more purification zones containing a purification absorbent capable of reducing the quantity of bromide-containing impurities in a feed comprising a recycle gas, which purification zones are located upstream from the epoxidation zone; and a process for the production of an alkylene carbonate and an alkylene glycol.
摘要翻译：本发明提供了一种用于生产碳酸亚烷基酯的反应体系，包括：含有位于环氧化反应器内的环氧化催化剂的环氧化区; 含有位于烯化氧吸收剂内的含溴化羧化催化剂的羧化区; 以及一个或多个净化区，其含有能够减少包含循环气体的进料中的含溴化物杂质的净化吸收剂，该净化区位于环氧化区的上游; 以及制备碳酸亚烷基酯和亚烷基二醇的方法。

9. 发明授权

US08273912B2 Process for the preparation of an alkylene carbonate and an alkylene glycol 有权
标题翻译：制备碳酸亚烷基酯和亚烷基二醇的方法
公开(公告)号：US08273912B2
公开(公告)日：2012-09-25
申请号：US12464972
申请日：2009-05-13
申请人： Wayne Errol Evans , Martin Lysle Hess , Marek Matusz , Eugene Marie Godfried Andre Van Kruchten
发明人： Wayne Errol Evans , Martin Lysle Hess , Marek Matusz , Eugene Marie Godfried Andre Van Kruchten
IPC分类号： C07C69/00
CPC分类号： C07D301/10 , B01D2255/104 , B01D2255/2022 , B01D2255/2092 , B01D2257/2062 , B01D2259/40 , C07C29/106 , C07C29/12 , Y02C10/08 , Y02P20/52 , C07C31/202
摘要： The invention provides a reaction system for the production of an alkylene carbonate comprising: an epoxidation zone containing an epoxidation catalyst located within an epoxidation reactor; a carboxylation zone containing an bromide-containing carboxylation catalyst located within an alkylene oxide absorber; and one or more purification zones containing a purification absorbent capable of reducing the quantity of bromide-containing impurities in a feed comprising a recycle gas, which purification zones are located upstream from the epoxidation zone; and a process for the production of an alkylene carbonate and an alkylene glycol.
摘要翻译：本发明提供了一种用于生产碳酸亚烷基酯的反应体系，包括：含有位于环氧化反应器内的环氧化催化剂的环氧化区; 含有位于烯化氧吸收剂内的含溴化羧化催化剂的羧化区; 以及一个或多个净化区，其含有能够减少包含循环气体的进料中的含溴化物杂质的净化吸收剂，该净化区位于环氧化区的上游; 以及制备碳酸亚烷基酯和亚烷基二醇的方法。

10. 发明申请

US20110105771A1 PROCESS FOR THE PRODUCTION OF AN OLEFIN OXIDE, A 1,2-DIOL, A 1,2-DIOL ETHER, A 1,2-CARBONATE, OR AN ALKANOLAMINE 有权
标题翻译：生产氧化烯，1,2-二醇，1,2-二醇醚，1,2-二碳酸酯或烷醇胺的方法
公开(公告)号：US20110105771A1
公开(公告)日：2011-05-05
申请号：US12988903
申请日：2008-05-07
申请人： Marek Matusz
发明人： Marek Matusz
IPC分类号： C07D301/04 , C07C29/48 , C07C41/02 , C07C68/00 , C07C213/00
CPC分类号： C07D301/10 , Y02P20/142
摘要： A process for the epoxidation of an olefin comprising contacting a reactor feed comprising an olefin, oxygen, and carbon dioxide, with a catalyst comprising a carrier and, deposited on the carrier, silver, a rhenium promoter, a first co-promoter, and a second co-promoter; wherein the carbon dioxide is present in the reactor feed in a quantity of at most 3 mole percent based on the total epoxidation reactor feed; the first co-promoter is selected from sulfur, phosphorus, boron, and mixtures thereof; and the second co-promoter is selected from tungsten, molybdenum, chromium, and mixtures thereof; a process for preparing a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine.
摘要翻译：一种烯烃的环氧化方法，包括将包含烯烃，氧和二氧化碳的反应器进料与包含载体的催化剂接触，并沉积在载体上，银，铼促进剂，第一共助催化剂和第二共同启动子; 其中基于总环氧化反应器进料，二氧化碳以至多3摩尔％的量存在于反应器进料中; 第一共助催化剂选自硫，磷，硼及其混合物; 并且第二共助催化剂选自钨，钼，铬及其混合物; 制备1,2-二醇，1,2-二醇醚，1,2-碳酸酯或链烷醇胺的方法。

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