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1. 发明授权

US5091066A Electrochemical synthesis of 2-methyl-5-pyrazinoic acid 失效
标题翻译： 2-甲基-5-吡嗪酸的电化学合成
公开(公告)号：US5091066A
公开(公告)日：1992-02-25
申请号：US707310
申请日：1991-05-29
申请人： Marco Foa , Fabrizio Forlini , Norberto Gatti , Giampiero Borsotti
发明人： Marco Foa , Fabrizio Forlini , Norberto Gatti , Giampiero Borsotti
IPC分类号： C07D241/24 , C25B3/02
CPC分类号： C25B3/02
摘要： There is disclosed a process for the preparation of 2-methyl-5-pyrazinoic acid consisting of electrochemically oxidizing a compound having formula: ##STR1## wherein X is --OH, Cl, Br, --O--CO--R, --O--SO.sub.2 --R, in which R is a C.sub.1 -C.sub.5 alkyl radical, optionally substituted with F or Cl, or it is a C.sub.6 -C.sub.12 aryl radical, in an aqueous alkaline medium, at a temperature ranging from 20.degree. C. to 90.degree. C., using anodes coated with nickel oxide-hydroxide.

2. 发明授权

US5098531A Electrochemical synthesis of 2-aryl-hydroquinones 失效
标题翻译： 2-ARYL-HYDROQUINONES的电化学合成
公开(公告)号：US5098531A
公开(公告)日：1992-03-24
申请号：US618025
申请日：1990-11-28
申请人： Norberto Gatti , Marco Foa
发明人： Norberto Gatti , Marco Foa
IPC分类号： C07C37/60 , C07C39/08 , C07C39/15 , C25B3/02
CPC分类号： C25B3/02 , C07C37/60
摘要： Preparation of 2-aryl-hydroquinones of formula (I) by oxidizing by an electrochemical route a compound of formula (II): ##STR1## wherein A represents an aryl group optionally substituted with groups compatible with the reaction conditions in an acidic aqueous reaction medium, at temperatures within the range of from 10.degree. to 100.degree. C., and with anodes of graphite or PbO.sub.2. The products are used in photography and in the field of liquid-crystal polymers.

3. 发明授权

US4351952A Process for preparing phenyl pyruvic acids 失效
标题翻译：制备苯基丙酮酸的方法
公开(公告)号：US4351952A
公开(公告)日：1982-09-28
申请号：US165019
申请日：1980-07-01
申请人： Marco Foa , Alessandro Moro , Andrea Gardano , Luigi Cassar
发明人： Marco Foa , Alessandro Moro , Andrea Gardano , Luigi Cassar
IPC分类号： C07C51/10
CPC分类号： C07C51/10
摘要： Phenyl pyruvic acid and substituted derivatives thereof are synthesized by catalytic carbonylation of a benzyl halide in the presence of a catalytic system based on carbonyl complexes of cobalt or precursors thereof.
摘要翻译：苯基丙酮酸及其取代的衍生物通过在基于钴或其前体的羰基络合物的催化体系的存在下，通过苄基卤的羰基化催化合成。

4. 发明授权

US4128572A Process for preparing phenylacetic acid 失效
标题翻译：制备苯乙酸的方法
公开(公告)号：US4128572A
公开(公告)日：1978-12-05
申请号：US870324
申请日：1978-01-18
申请人： Luigi Cassar , Marco Foa
发明人： Luigi Cassar , Marco Foa
IPC分类号： C07C57/32 , B01J31/00 , C07B61/00 , C07C51/00 , C07C51/10 , C07C67/00 , C07C63/54
CPC分类号： C07C51/10
摘要： This invention relates to a process for preparing phenylacetic acid. In particular, the present invention relates to a catalytic process for the synthesis of the alkaline salts of phenylacetic acid by carbonylation of benzyl halides in a diphase system in the presence of cobalt carbonyl complexes. More particularly, the present invention relates to a process for preparing alkaline salts of phenylacetic acid by reacting a benzyl halide selected from chloride and bromide with carbon monoxide in the presence of a catalyst consisting in a salt of cobalt hydrocarbonyl, characterized in that the reaction is conducted in an aqueous/organic diphase system consisting of (a) an aqueous solution of an inorganic alkaline base, and (b) the benzyl halide in an organic solvent, in the presence of a catalyst system composed by a quaternary alkylammonium salt and by a cobalt hydrocarbonyl salt, at atmospheric pressure and at a temperature ranging from 20.degree. to 70.degree. C about.
摘要翻译：本发明涉及一种制备苯乙酸的方法。特别地，本发明涉及通过在羰基钴络合物存在下在双相体系中羰基化苄基卤化物来合成苯乙酸的碱性盐的催化方法。更具体地说，本发明涉及一种通过在选自氯化物和溴化物的苄基卤与一氧化碳在钴烃基的盐存在下反应制备苯乙酸的碱性盐的方法，其特征在于反应是在由（a）无机碱性碱的水溶液和（b）苄基卤在有机溶剂中，在由季烷基铵盐组成的催化剂体系存在下的水/有机双相体系中进行，钴烃基盐，在大气压和约20℃至70℃的温度下。

5. 发明授权

US5336793A Preparing carboxylic acids or esters by oxidative cleavage of unsaturated fatty acids or esters 失效
标题翻译：通过不饱和脂肪酸或酯的氧化裂解制备羧酸或酯
公开(公告)号：US5336793A
公开(公告)日：1994-08-09
申请号：US988671
申请日：1992-12-10
申请人： Andrea Gardano , Giampiero Sabarino , Marco Foa
发明人： Andrea Gardano , Giampiero Sabarino , Marco Foa
IPC分类号： B01J31/34 , C07C51/285 , C07C53/126 , C07C55/18 , C07C67/333 , C07C69/24 , C07C69/48 , C07D20060101 , C11C1/00 , C07C51/25 , C07C67/00
CPC分类号： C07C51/285 , C07C67/333
摘要： A method of preparing carboxylic acids or esters thereof by the oxidative cleavage of unsaturated fatty acids or esters thereof is carried out in a two-phase aqueous-organic system in which the organic phase contains the unsaturated fatty acid and/or the esters thereof and the aqueous phase contains hydrogen peroxide. The oxidative cleavage is carried out in the presence of a catalytic system including a catalyst belonging to the group constituted by tungstic and molybdic acids and alkaline salts thereof, and an onium salt which acts as a phase-transfer agent for the catalyst, and has the formula:(R.sub.2 R.sub.3 R.sub.4 R.sub.5 M).sup.+ Y.sup.-in which R.sub.2, R.sub.3, R.sub.4 and R.sub.5 represent hydrocarbon groups of which at least one must have more than 10 carbon atoms,M is N or P, andY.sup.- is an inorganic anion.
摘要翻译：通过不饱和脂肪酸或其酯的氧化裂解制备羧酸或其酯的方法是在有机相含有不饱和脂肪酸和/或其酯的两相水 - 有机体系中进行的，水相含有过氧化氢。氧化裂解在催化体系存在下进行，催化体系包括属于由钨酸和钼酸及其碱式盐构成的组的催化剂，以及作为催化剂的相转移剂的鎓盐，式（R 2 R 3 R 4 R 5 M）+ Y-，其中R 2，R 3，R 4和R 5表示至少必须具有多于10个碳原子的烃基，M是N或P，Y-是无机阴离子。

6. 发明授权

US5326801A Polymer compositions containing organic phosphite stabilizers 失效
标题翻译：含有机磷酸酯稳定剂的聚合物组合物
公开(公告)号：US5326801A
公开(公告)日：1994-07-05
申请号：US921952
申请日：1992-07-28
申请人： Marco Foa , Sauro Strologo
发明人： Marco Foa , Sauro Strologo
IPC分类号： C07F9/6574 , C08K5/52 , C08K5/524 , C08K5/527 , C08L101/00 , C08K5/529
CPC分类号： C08K5/527 , C07F9/65746
摘要： New organic phosphites of a specific formula are used as stabilizers for polymers and other organic materials.
摘要翻译：新型有机亚磷酸酯可用作聚合物和其他有机材料的稳定剂。

7. 发明授权

US5146008A Process for the synthesis of aromatic phenyl substituted diols 失效
标题翻译：芳基苯基取代二醇的合成方法
公开(公告)号：US5146008A
公开(公告)日：1992-09-08
申请号：US672092
申请日：1991-03-19
申请人： Andrea Gardano , Alfredo Coassolo , Francesco Casagrande , Marco Foa , Larry L. Chapoy
发明人： Andrea Gardano , Alfredo Coassolo , Francesco Casagrande , Marco Foa , Larry L. Chapoy
IPC分类号： C07B61/00 , C07C37/06 , C07C39/14
CPC分类号： C07C37/06 , B01J23/44 , B01J35/08 , B01J37/06
摘要： A process for the synthesis of phenyl substituted aromatic diols, obtained by dehydrogenation of the corresponding substituted cyclohexyl derivatives in the presence of a palladium supported catalyst, said palladium supported catalyst being prepared by a process which comprises treating a palladium hydrolysis compound with reducing agents.
摘要翻译：合成苯基取代芳族二醇的方法，其通过在钯负载催化剂存在下脱氢相应的取代的环己基衍生物而获得，所述钯负载型催化剂通过包括用还原剂处理钯水解化合物的方法制备。

8. 发明授权

US4034004A Process for the preparation of carboxylic acids from organic halides 失效
标题翻译：从有机卤化物制备羧酸的方法
公开(公告)号：US4034004A
公开(公告)日：1977-07-05
申请号：US585756
申请日：1975-06-10
申请人： Luigi Cassar , Marco Foa , Andrea Gardano
发明人： Luigi Cassar , Marco Foa , Andrea Gardano
IPC分类号： C07C53/00 , B01J31/00 , B01J31/24 , C07B61/00 , C07C51/00 , C07C51/10 , C07C51/145 , C07C53/126 , C07C57/32 , C07C57/44 , C07C63/00 , C07C63/06 , C07C63/10 , C07C67/00
CPC分类号： B01J31/2404 , B01J31/0239 , B01J31/0267 , B01J31/24 , B01J31/2409 , C07C51/10 , C07C51/145 , B01J2231/34 , B01J2531/824 , B01J2531/96 , B01J31/2295
摘要： A process for preparing carboxylic acids by reaction of carbon monoxide with aromatic and aliphatic organic halides, optionally further substituted by groups inert under the reaction conditions, and catalyzed by phosphinic palladium complexes and in the presence of quaternary alkyl-ammonium salts, characterized in that said process is conducted in a double liquid phase consisting essentially of (a) the organic halide and the catalytic palladium complex or their solutions in at least one hydrocarbon solvent immiscible with H.sub.2 O, and (b) an aqueous inorganic alkaline solution containing the quaternary alkyl-ammonium salt, at a temperature between about 50.degree. and 150.degree. C. More particularly, the reaction is conducted in the presence of at least one catalyst selected from among:A. at least one palladium complex of the formula:Pd[P(R).sub.3 ].sub.mwherein m is a whole number from 2 to 4, and (R).sub.3 represents a homogeneous or a heterogeneous group consisting of phenyl and/or alkyl radicals which may also be further substituted by inert groups;B. at least one palladium complex of the general formula:Pd[P(R).sub.2 -- (CH.sub.2).sub.n -- P(R).sub.2 ].sub.pwherein (R).sub.2 has the same meaning indicated above for (R).sub.3, p is a whole number from 1 to 2, and n is a whole number from 1 to 6; orC. at least one palladium complex of the general formula: ##STR1## wherein the groups (R).sub.3, equal to or different from each other, have the same meaning as indicated above, and Y is a halogen atom and/or an aryl radical.
摘要翻译：通过一氧化碳与芳族和脂肪族有机卤化物的反应制备羧酸的方法，任选进一步被反应条件下惰性的基团取代，并通过次膦酸钯络合物和季烷基铵盐的存在进行催化，其特征在于所述方法在基本上由（a）有机卤化物和催化钯络合物或它们的溶液在至少一种与H 2 O不混溶的烃溶剂中组成的双液相中进行，和（b）含有季烷基铵的含水无机碱溶液盐，在约50℃至150℃的温度下进行。更具体地说，反应在至少一种选自以下的催化剂存在下进行：

9. 发明授权

US5352830A Phosphorous organic amides suitable as stabilizers and polymer compositions which comprise them 失效
标题翻译：适合作为稳定剂的磷酸有机酰胺和包含它们的聚合物组合物
公开(公告)号：US5352830A
公开(公告)日：1994-10-04
申请号：US967892
申请日：1992-10-28
申请人： Marco Foa , Sauro Strologo , Giampiero Sabarino
发明人： Marco Foa , Sauro Strologo , Giampiero Sabarino
IPC分类号： C07F9/6574 , C07F9/6571 , C08K5/49 , C08K5/52 , C08K5/5399 , C08L23/00 , C08L101/00 , C07F9/02
CPC分类号： C07F9/657154 , C08K5/5399
摘要： New phosphorous organic amides of a specific formula and their use as stabilizers for polymers and, other organic materials.
摘要翻译：新的具有特定配方的有机有机酰胺及其用作聚合物和其他有机材料的稳定剂。

10. 发明授权

US4985533A Termotropic liquid-crystalline aromatic polyester from hydroquinone/substituted hydroquinone mixture 失效
标题翻译：来自氢醌/取代氢醌混合物的定向液晶芳族聚酯
公开(公告)号：US4985533A
公开(公告)日：1991-01-15
申请号：US358512
申请日：1989-05-30
申请人： Alfredo Coassolo , L. Lawrence Chapoy , Marco Foa , Giampiero Sabarino
发明人： Alfredo Coassolo , L. Lawrence Chapoy , Marco Foa , Giampiero Sabarino
IPC分类号： C08G63/18 , C08G63/19 , C09K19/38
CPC分类号： C08G63/19 , C09K19/3809
摘要： Thermotropic liquid-crystalline aromatic polyesters processable in the molten state, comprising units derived from at least one dicarboxylic aromatic acid and from mono- and di-substituted (1-phenyl-ethyl)-hydroquinones in admixture with hydroquinone, and/or hydroquinones substituted with halogen or alky, aryl or cycloalkyl groups.

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