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    • 1. 发明授权
    • Poly(5,5′bis(thiophen-2-yl)-benzo[2,1-b;3,4-b′]dithiophene) and its use as high performance solution processable semiconducting polymer
    • 聚(5,5'-双(噻吩-2-基) - 苯并[2,1-b; 3,4-b']二噻吩)及其作为高性能溶液可加工半导体聚合物
    • US08598304B2
    • 2013-12-03
    • US13002392
    • 2009-06-25
    • Marcel KastlerSilke KoehlerKlaus MuellenMiaoyin LiuDirk BeckmannRalph Rieger
    • Marcel KastlerSilke KoehlerKlaus MuellenMiaoyin LiuDirk BeckmannRalph Rieger
    • C08G75/00
    • H01L51/0036C07D495/04C08G61/126H01B1/127H01L51/0043H01L51/0074H01L51/0541H01L51/0545Y02E10/549
    • Poly(5,5′-bis(thiophen-2-yl)-benzo[2,1-b;3,4-b′]dithiophene) comprising as repeating units the group of the formula (I) wherein R is independently selected from a) a C1-20 alkyl group, b) a C2-20 alkenyl group, c) a C2-20 alkynyl group, d) a C1-20 alkoxy group, e) a —Y—C3-10 cycloalkyl group, f) a —Y—C6-14 aryl group, g) a —Y-3-12 membered cycloheteroalkyl group, or h) a —Y-5-14 membered heteroaryl group, wherein each of the C1-20 alkyl group, the C2-20 alkenyl group, the C2-20 alkynyl group, the C3-10 cycloalkyl group, the C6-14 aryl group, the 3-12 membered cycloheteroalkyl group, and the 5-14 membered heteroaryl group is optionally substituted with 1-4 R1 groups, R1 is independently selected from a) a S(O)m—C1-20 alkyl group, b) a S(O)m—OC1-20 alkyl group, c) a S(O)m—OC6-14 aryl group, d) a C(O)—OC1-20 alkyl group, e) a C(O)—OC6-14 aryl group, f) a C1-20 alkyl group, g) a C2-20 alkenyl group, h) a C2-20 alkynyl group, i) a C1-20 alkoxy group, j) a C3-10 cycloalkyl group, k) a C6-14 aryl group, l) a 3-12 membered cycloheteroalkyl group, or m) a 5-14 membered heteroaryl group, Y is independently selected from a divalent C1-6 alkyl group, or a covalent bond; and m is independently selected from 0, 1, or 2, and having a number average molecular weight Mn in the range of from 5,000 to 200,000 g/mol.
    • 包括作为重复单元的式(I)基团,其中R独立地被选择的聚(5,5'-双(噻吩-2-基) - 苯并[2,1-b; 3,4-b']二噻吩) 从a)C 1-20烷基,b)C 2-20烯基,c)C 2-20炔基,d)C 1-20烷氧基,e)-Y-C 3-10环烷基,f )-Y-C 6-14芳基,g)a -Y-3-12元环杂烷基,或h)-Y-5-14元杂芳基,其中C 1-20烷基,C 2 -20链烯基,C2-20炔基,C3-10环烷基,C6-14芳基,3-12元环杂烷基和5-14元杂芳基任选被1-4个R1 基团,R 1独立地选自a)S(O)m -C 1-20烷基,b)S(O)m OC 1-7-20烷基,c)S(O)m -C 0-6-14芳基 基团,d)C(O)-OC 1-20烷基,e)C(O)-OC 6-14芳基,f)C 1-20烷基,g)C 2-20烯基,h) C 20-20炔基,i)C 1-20烷氧基,j)C 3-10环烷基,k)C 6-14 芳基,l)3-12元环杂烷基,或m)5-14元杂芳基,Y独立地选自二价C 1-6烷基或共价键; m独立地选自0,1或2,数均分子量Mn在5,000至200,000g / mol的范围内。
    • 2. 发明申请
    • POLY(5,5'-BIS(THIOPHEN-2-YL)-BENZO[2,1-B;3,4-B']DITHIOPHENE) AND ITS USE AS HIGH PERFORMANCE SOLUTION PROCESSABLE SEMICONDUCTING POLYMER
    • POLY(5,5'-双(噻吩-2-基) - 苯并[2,1-B; 3,4-B']二苯基),并且可用作高性能溶液可处理的半导体聚合物
    • US20110168264A1
    • 2011-07-14
    • US13002392
    • 2009-06-25
    • Marcel KastlerSilke KoehlerKlaus MuellenMiaoyin LiuDirk BeckmannRalph Rieger
    • Marcel KastlerSilke KoehlerKlaus MuellenMiaoyin LiuDirk BeckmannRalph Rieger
    • H01L51/46H01L51/30H01L51/54C08G75/06C08L81/02
    • H01L51/0036C07D495/04C08G61/126H01B1/127H01L51/0043H01L51/0074H01L51/0541H01L51/0545Y02E10/549
    • Poly(5,5′-bis(thiophen-2-yl)-benzo[2,1-b;3,4-b′]dithiophene) comprising as repeating units the group of the formula (I) wherein R is independently selected from a) a C1-2O alkyl group, b) a C2-20 alkenyl group, c) a C2-20 alkynyl group, d) a C1-20 alkoxy group, e) a —Y—C3-10 cycloalkyl group, f) a —Y—C6-14 aryl group, g) a —Y-3-12 membered cycloheteroalkyl group, or h) a —Y-5-14 membered het-eroaryl group, wherein each of the C1-20 alkyl group, the C2-20 alkenyl group, the C2-20 alkynyl group, the C3-10 cycloalkyl group, the C6-14 aryl group, the 3-12 membered cycloheteroalkyl group, and the 5-14 membered heteroaryl group is optionally substituted with 1-4 R1 groups, R1 is independently selected from a) a S(O)m—C1-20 alkyl group, b) a S(O)m—OC1-20 alkyl group, c) a S(O)m—OC6-14 aryl group, d) a C(O)—OC1-20 alkyl group, e) a C(O)—OC6-14 aryl group, f) a C1-20 alkyl group, g) a C2-20 alkenyl group, h) a C2-20 alkynyl group, i) a C1-20 alkoxy group, j) a C3-10 cycloalkyl group, k) a C6-14 aryl group, I) a 3-12 membered cycloheteroalkyl group, or m) a 5-14 membered heteroaryl group, Y is independently selected from a divalent C1-6 alkyl group, or a covalent bond; and m is independently selected from 0, 1, or 2, and having a number average molecular weight Mn in the range of from 5,000 to 200,000 g/mol.
    • 包括作为重复单元的式(I)基团,其中R独立地被选择的聚(5,5'-双(噻吩-2-基) - 苯并[2,1-b; 3,4-b']二噻吩) 从a)C1-2O烷基,b)C2-20烯基,c)C2-20炔基,d)C1-20烷氧基,e)-Y-C3-10环烷基,f )a -Y-C 6-14芳基,g)-Y-3-12元环杂烷基,或h)-Y-5-14元环芳基,其中每个C 1-20烷基, C2-20烯基,C2-20炔基,C3-10环烷基,C6-14芳基,3-12元环杂烷基和5-14元杂芳基任选被1- 4个R 1基团,R 1独立地选自a)S(O)m -C 1-20烷基,b)S(O)m OC 1-7-20烷基,c)S(O)m OC 1-6 - 14芳基,d)C(O)-OC1-20烷基,e)C(O)-OC6-14芳基,f)C1-20烷基,g)C2-20烯基, h)C 20-20炔基,i)C 1-20烷氧基,j)C 3-10环烷基 烷叉基,k)C 6-14芳基,I)3-12元环杂烷基或m)5-14元杂芳基,Y独立地选自二价C 1-6烷基或共价键 ; m独立地选自0,1或2,数均分子量Mn在5,000至200,000g / mol的范围内。
    • 3. 发明申请
    • HIGH PERFORMANCE SOLUTION PROCESSABLE SEMINCONDUCTOR BASED ON DITHIENO [2,3-D:2',3'-D']BENZO[1,2-B:4,5-B'] DITHIOPHENE
    • 基于DITHIENO [2,3-D:2',3'-D'] BENZO [1,2-B:4,5-B']二氢苯的高性能溶液可处理的SEMINCONUCTOR
    • US20110155248A1
    • 2011-06-30
    • US13002208
    • 2009-06-25
    • Marcel KastlerSilke KoehlerKlaus MuellenPeng GaoDirk BeckmannXinliang FengHoi Nok Tsao
    • Marcel KastlerSilke KoehlerKlaus MuellenPeng GaoDirk BeckmannXinliang FengHoi Nok Tsao
    • C07D333/52H01B1/12H01L51/30H01L51/46H01L51/54
    • H01L51/0074C07D495/22C09K11/06C09K2211/1011C09K2211/1092G02B2006/12069H01L51/0545H01L51/5048H05B33/10H05B33/14Y02E10/549
    • Dithienobenzodithiophenes of general formula (I) in which R1 to R6 are each independently selected from a) H, b) halogen, c) —CN, d) —NO2, e) —OH, f) a C1-20 alkyl group, g) a C2-20 alkenyl group, h) a C2-20 alkynyl group, i) a C1-20 alkoxy group, j) a C1-20 alkylthio group, k) a C1-20 haloalkyl group, I) a —Y—C3-10 cycloalkyl group, m) a —Y—C6-14 aryl group, n) a —Y-3-12 membered cyclo-heteroalkyl group, or o) a —Y-5-14 membered heteroaryl group, wherein each of the C1-20 alkyl group, the C2-20 alkenyl group, the C2-20 alkynyl group, the C3-10 cycloalkyl group, the C6-14 aryl group, the 3-12 membered cyc-loheteroalkyl group, and the 5-14 membered heteroaryl group is optionally substituted with 1-4 R7 groups, wherein R1 and R3 and R2 and R4 may also together form an aliphatic cyclic moiety, Y is independently selected from divalent a C1-6 alkyl group, a divalent C1-6 haloalkyl group, or a covalent bond; and m is independently selected from 0, 1, or 2. The invention also relates to the use of the dithienobenzodithiophenes according to any of claims 1 to 4 as semiconductors or charge transport materials, as thin-film transistors (TFTs), or in semiconductor components for organic light-emitting diodes (OLEDs), for photovoltaic components or in sensors, as an electrode material in batteries, as optical waveguides or for electrophotography applications.
    • 通式(I)的二噻吩并苯并二噻吩,其中R 1至R 6各自独立地选自a)H,b)卤素,c)-CN,d)-NO 2,e)-OH,f)C 1-20烷基, )C2-20烯基,h)C2-20炔基,i)C1-20烷氧基,j)C1-20烷硫基,k)C1-20卤代烷基,I)a -Y- C3-10环烷基,m)-Y-C6-14芳基,n)a -Y-3-12元环杂烷基,或o)-Y-5-14元杂芳基,其中各 C 1-20烷基,C 2-20烯基,C 2-20炔基,C 3-10环烷基,C 6-14芳基,3-12元环 - 卤杂烷基和5-14 任选被1-4个R 7基团取代,其中R 1和R 3以及R 2和R 4也可以一起形成脂族环状部分,Y独立地选自二价C 1-6烷基,二价C 1-6卤代烷基 ,或共价键; 并且m独立地选自0,1或2.本发明还涉及根据权利要求1至4中任一项所述的二噻吩并苯并噻吩作为半导体或电荷传输材料,作为薄膜晶体管(TFT)或半导体 用于有机发光二极管(OLED)的组件,用于光伏组件或传感器,作为电池中的电极材料,作为光波导或电子照相应用。
    • 4. 发明授权
    • High performance solution processable semiconductor based on dithieno [2,3-D:2′, 3′-D′]benzo[1,2-B:4,5-B′] dithiophene
    • 基于二噻吩[2,3-D:2',3'-D']苯并[1,2-B:4,5-B']二噻吩的高性能溶液可加工半导体
    • US08367717B2
    • 2013-02-05
    • US13002208
    • 2009-06-25
    • Marcel KastlerSilke KoehlerKlaus MuellenPeng GaoDirk BeckmannXinliang FengHoi Nok Tsao
    • Marcel KastlerSilke KoehlerKlaus MuellenPeng GaoDirk BeckmannXinliang FengHoi Nok Tsao
    • A61K31/38C07D333/50
    • H01L51/0074C07D495/22C09K11/06C09K2211/1011C09K2211/1092G02B2006/12069H01L51/0545H01L51/5048H05B33/10H05B33/14Y02E10/549
    • Dithienobenzodithiophenes of general formula (I) in which R1 to R6 are each independently selected from a) H, b) halogen, c) —CN, d) —NO2, e) —OH, f) a C1-20 alkyl group, g) a C2-20 alkenyl group, h) a C2-20 alkynyl group, i) a C1-20 alkoxy group, j) a C1-20 alkylthio group, k) a C1-20 haloalkyl group, I) a —Y—C3-10 cycloalkyl group, m) a —Y—C6-14 aryl group, n) a —Y-3-12 membered cyclo-heteroalkyl group, or o) a —Y-5-14 membered heteroaryl group, wherein each of the C1-20 alkyl group, the C2-20 alkenyl group, the C2-20 alkynyl group, the C3-10 cycloalkyl group, the C6-14 aryl group, the 3-12 membered cyc-loheteroalkyl group, and the 5-14 membered heteroaryl group is optionally substituted with 1-4 R7 groups, wherein R1 and R3 and R2 and R4 may also together form an aliphatic cyclic moiety, Y is independently selected from divalent a C1-6 alkyl group, a divalent C1-6 haloalkyl group, or a covalent bond; and m is independently selected from 0, 1, or 2. The invention also relates to the use of the dithienobenzodithiophenes according to any of claims 1 to 4 as semiconductors or charge transport materials, as thin-film transistors (TFTs), or in semiconductor components for organic light-emitting diodes (OLEDs), for photovoltaic components or in sensors, as an electrode material in batteries, as optical waveguides or for electrophotography applications.
    • 通式(I)的二噻吩并苯并二噻吩,其中R 1至R 6各自独立地选自a)H,b)卤素,c)-CN,d)-NO 2,e)-OH,f)C 1-20烷基, )C2-20烯基,h)C2-20炔基,i)C1-20烷氧基,j)C1-20烷硫基,k)C1-20卤代烷基,I)a -Y- C3-10环烷基,m)-Y-C6-14芳基,n)a -Y-3-12元环杂烷基,或o)-Y-5-14元杂芳基,其中各 C 1-20烷基,C 2-20烯基,C 2-20炔基,C 3-10环烷基,C 6-14芳基,3-12元环 - 卤杂烷基和5-14 任选被1-4个R 7基团取代,其中R 1和R 3以及R 2和R 4也可以一起形成脂族环状部分,Y独立地选自二价C 1-6烷基,二价C 1-6卤代烷基 ,或共价键; 并且m独立地选自0,1或2.本发明还涉及根据权利要求1至4中任一项所述的二噻吩并苯并噻吩作为半导体或电荷传输材料,作为薄膜晶体管(TFT)或半导体 用于有机发光二极管(OLED)的组件,用于光伏组件或传感器,作为电池中的电极材料,作为光波导或电子照相应用。