会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 3. 发明授权
    • Continuous preparation of finely divided gel-like crosslinked polymers
    • 连续制备细分的凝胶状交联聚合物
    • US4769427A
    • 1988-09-06
    • US921388
    • 1986-10-22
    • Bernhard H. NowakowskyJuergen BeckHeinrich HartmannChristos Vamvakaris
    • Bernhard H. NowakowskyJuergen BeckHeinrich HartmannChristos Vamvakaris
    • B01J19/18C08F2/00C08F2/10C08F2/24C08F20/00C08F20/02C08F20/06C08F20/10C08F20/28C08F20/52C08F20/56C08F220/04
    • C08F2/10B01J19/18B01J2219/00162B01J2219/00166B01J2219/182Y10S526/92
    • Finely divided, gel-like crosslinked polymers are prepared by a continuous method in which a monomer mixture which contains, per 100 parts by weight of acrylic acid or methacrylic acid, from 50 to 100 mol % of which in each case are neutralized, acrylamide, methacrylamide or N-vinylpyrrolidone, from 0 to 30 parts by weight of other water-soluble monoethylenically unsaturated monomers and from 0 to 20 parts by weight of water-insoluble monoethylenically unsaturated monomers is copolymerized with from 0.01 to 5 parts by weight of a crosslinking agent, in 20-65% strength by weight aqueous solution in the presence of an initiator at from 45.degree. to 95.degree. C. in a single-screw cylindrical mixer whose stirrer shaft possesses disk segments which have, at the outer end, mixing bars which are arranged in a manner such that the substances fed in at the entrance of the mixer are conveyed in the axial direction to the exit of the mixer, the aqueous monomer solution in the mixer is polymerized under from 100 to 800 mbar, and some of the water is removed during the polymerization, so that a crumb-like gel having a solids content of from 30 to 70% by weight is discharged.
    • 精细分割的凝胶状交联聚合物通过连续方法制备,其中每100重量份丙烯酸或甲基丙烯酸中含有50-100摩尔%的每种情况都被中和的单体混合物是丙烯酰胺, 甲基丙烯酰胺或N-乙烯基吡咯烷酮,0〜30重量份的其它水溶性单烯属不饱和单体和0〜20重量份的水不溶性单烯属不饱和单体与0.01〜5重量份的交联剂 ,在45-95℃的引发剂存在下,在20-55%重量的水溶液中,在单螺杆圆柱形混合器中,其搅拌器轴具有在外端具有混合杆的盘段, 以使得在混合器入口处输入的物质沿轴向输送到混合器的出口的方式,将混合器中的单体水溶液聚合在 从100至800毫巴,并且在聚合期间除去一些水,从而排出固体含量为30至70重量%的碎屑状凝胶。
    • 4. 发明授权
    • Batchwise preparation of crosslinked, finely divided polymers
    • 分批制备交联的细碎聚合物
    • US4873299A
    • 1989-10-10
    • US28449
    • 1987-03-20
    • Bernhard H. NowakowskyJuergen BeckHeinrich HartmannChristos Vamvakaris
    • Bernhard H. NowakowskyJuergen BeckHeinrich HartmannChristos Vamvakaris
    • A61L15/60C08F2/10C08F2/18C08F20/00C08F20/06C08F20/56C08F26/10
    • A61L15/60C08F2/10
    • Crosslinked, finely divided, water-absorbing polymers are prepared in a batchwise process by copolymerization of 100 parts by weight of a monomer mixture of acrylic acid or methacrylic acid, each of which is neutralized with from 0 to 100 mol% of an alkali metal or ammonium base,or acrylamide, methacrylamide or N-vinylpyrrolidone with, as a crosslinking agent, from 0.01 to 5 parts by weight of a monomer containing two or more ethylenically unsaturated double bonds in 20-80% by weight aqueous solution in the presence of an initiator in a multistage procedure in a batchwise mixing apparatus wih constant thorough mixing in all stages, in the first stage the aqueous monomer solution being copolymerized at from 45.degree. to 95.degree. C. and under from 0.1 to 0.8 bar with removal of some of the water by distillation, in the second stage the copolymerization being completed at from 100.degree. to 170.degree. C. under a pressure of up to 8 bar, and in the third stage the water content of the resulting finely divided copolymer being decreased to 0.5-10% by weight under reduced pressure.
    • 通过共聚合100重量份的丙烯酸或甲基丙烯酸的单体混合物,各自用0-100mol%的碱金属中和,分批地制备交联的细分吸水聚合物, 铵基或丙烯酰胺,甲基丙烯酰胺或N-乙烯基吡咯烷酮,作为交联剂,在20-80重量%的水溶液中,在存在下,含有0.01至5重量份含有两个或更多个烯键式不饱和双键的单体 引发剂在分批混合装置中,在所有阶段中经常充分混合,在第一阶段中,单体水溶液在45℃至95℃和0.1至0.8巴下共聚,除去一些 通过蒸馏进行水,在第二阶段中,在高达8巴的压力下,在100℃至170℃下完成共聚,在第三阶段中,所得到的粉末的含水量 y分子共聚物在减压下降至0.5-10重量%。