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    • 2. 发明授权
    • Method of adhering textiles
    • 粘贴纺织品的方法
    • US4396759A
    • 1983-08-02
    • US381209
    • 1982-05-24
    • Manfred DrawertWolfgang Imoehl
    • Manfred DrawertWolfgang Imoehl
    • C08G69/00C08G69/32C08G69/34C08G69/36C09J177/00C09J177/08C09J3/16
    • C09J177/08C08G69/32C08G69/34C08G69/36C09J177/00
    • What are disclosed are a polyamide polymer and its use as a melt adhesive for adhering textiles, said polymer having a melt viscosity, measured at 220.degree. C., of 5-150 Pas and being the reaction product of approximately equivalent amounts of an acid component and a basic component, said acid component comprising(a) (1) a dimerized fatty acid having a content of 70-100 percent by weight of dimeric fatty acid and, optionally,(a) (2) a monocarboxylic acid, as a molecular weight regulator, having up to 22 carbon atoms, which monocarboxylic acid may be present in an amount up to 50 equivalent percent of the total carboxy groups of the mixture (a) (1) and (a) (2);(b) at least one aliphatic straight chain co-dicarboxylic acid having 6 to 13 carbon atoms, wherein the ratio of carboxylic acid according to (a) (1) and (a) (2) to carboxylic acid according to (b) is from 0.05:1 to 5:1, calculated on the carboxy groups, said basic component comprising(c) an aliphatic straight-chain diprimary diamine having 6 to 12 carbon atoms and(d) from 0.5 to 1.5 mol, per mol of carboxyl groups of said acid component, of a mixture comprising from 95 to 30 mol percent of caprolactam, .epsilon.-aminocaproic acid, or a mixture thereof and 5 to 70 mol percent of 11-aminoundecanoic acid, 12-aminododecanoic acid, lauryl lactam, or a mixture thereof.
    • 所公开的是聚酰胺聚合物及其作为用于粘合纺织品的熔融粘合剂的用途,所述聚合物在220℃下测量的熔体粘度为5-150Pa·s,并且是约等量的酸组分的反应产物 和碱性组分,所述酸组分包含(a)(1)二聚脂肪酸的含量为70-100重量%的二聚脂肪酸,和任选的(a)(2)单羧酸作为分子 重量调节剂,具有多达22个碳原子,该单羧酸可以以混合物(a)(a)和(a)(2)的总羧基的最多50当量的量存在; (b)至少一种具有6至13个碳原子的脂族直链共二羧酸,其中根据(a)(1)和(a)(2)的羧酸与根据(b)的羧酸的比例为 所述碱性组分包含(c)每摩尔羧基具有6至12个碳原子的脂族直链二元二胺和(d)0.5至1.5摩尔的羧酸基团, 的所述酸组分,包含95至30mol%的己内酰胺,ε-氨基己酸或其混合物和5至70mol%的11-氨基十一烷酸,12-氨基十二烷酸,月桂基内酰胺或其混合物 其中。
    • 4. 发明授权
    • Method of adhering textiles with a polyamide melt adhesive
    • 用聚酰胺熔融粘合剂粘合纺织品的方法
    • US4045389A
    • 1977-08-30
    • US709116
    • 1976-07-27
    • Manfred DrawertEugen GriebschWolfgang Imoehl
    • Manfred DrawertEugen GriebschWolfgang Imoehl
    • C08G69/00C08G69/34C08G69/36C09J177/00D04H1/58D04H1/60D06M17/00C09J3/16
    • C08G69/34Y10T428/31739
    • A polyamide melt adhesive having a melt viscosity, measured at 220.degree. C., of 25-600 Pas and adaptable for the adhesion of textiles, said polyamide comprisingA. 1. dimerized fatty acid having a content of 70-100 percent by weight of dimeric fatty acid, and optionally comprising2. a monocarboxylic acid as a molecular-weight regulator (chain stopper), whereby up to 50 equivalent percent of the total carboxy groups of the mixture (a) (1) and (2) can be derived from the monocarboxylic acid; and comprisingB. one or more aliphatic straight chain co-dicarboxylic acids having 6-13 carbon atoms, wherein the ratio of carboxylic acids according to (a) (1) and (2) to carboxylic acid according to (b) is from 0.05:1 to 5:1, calculated on the carboxy groups; and further comprising in an amount approximately equivalent to the acids mentioned under (a) and (b) aboveC. an aliphatic straight chain diprimary diamine having 6-12 carbon atoms, andD. caprolactam and/or .epsilon.-aminocaproic acid, wherein from 0.5 to 1.5 mols of caprolactam and/or .epsilon.-aminocaproic acid are employed per mol of carboxy groups of the acids mentioned under (a) and (b) above.
    • 一种聚酰胺熔融粘合剂,其在220℃下测量的熔体粘度为25-600Pa·s,适用于纺织品的粘合,所述聚酰胺包括A. 1.二甲基脂肪酸,其含量为70-100重量% 二元脂肪酸,并且可选地包含2.作为分子量控制器(链停止剂)的单羧酸,由于混合物(A)(1)和(2)的总碳含量可达50等于或等于百分之一 来自单羟基酸; 并包含B.一种或多种具有6-13碳原子的直链链二碳酸,根据(A)(1)和(2)根据(B)的羧酸与羧酸的比例为0.05 :1至5:1,计算碳素组; 并进一步包含大量等同于上述(A)和(B)以上所述的酸。具有6-12碳原子的氨基酸直链链双键,以及D.卡培拉明和/或ε-氨基酸,从其中 根据(A)和(B)以上所述,0.5至1.5摩尔%的卡波铵和/或ε-氨基酸用量为每个羧酸基团的使用量。