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1. 发明授权

US6121393A Process for polymerizing alpha-olefins 失效
标题翻译： α-烯烃聚合方法
公开(公告)号：US6121393A
公开(公告)日：2000-09-19
申请号：US418879
申请日：1995-04-07
申请人： Mamoru Kioka , Norio Kashiwa , Tomohiko Kimura , Mitsuo Tomura , Toshiki Sotoyama
发明人： Mamoru Kioka , Norio Kashiwa , Tomohiko Kimura , Mitsuo Tomura , Toshiki Sotoyama
IPC分类号： C08F2/18
CPC分类号： C08F10/00
摘要： A process for polymerizing an alpha-olefin using either a catalyst formed by contacting a highly active solid titanium catalyst component, an organo-metallic compound of a metal of Group 1 to 3 of the periodic table, an organic halogen compound or a transition metal compound, and an organosilicon compound or a sterically hindered amine in an inert medium in the absence of an alpha olefin, or a catalyst prepared by preliminarily polymerizing an alpha olefin in the presence of a catalyst comprising the above four catalyst components, provided that the last one is an optional component. This process achieves the industrially advantage that the catalysts are highly active, and give a polymer having excellent stereoregularity.
摘要翻译：使用通过使高活性固体钛催化剂组分，元素周期表第1族至第3族的金属的有机金属化合物，有机卤素化合物或过渡金属化合物接触而形成的催化剂聚合α-烯烃的方法，以及在不存在α-烯烃的惰性介质中的有机硅化合物或空间位阻胺，或在包含上述四种催化剂组分的催化剂存在下通过预先聚合α-烯烃制备的催化剂，条件是最后一个是一个可选组件。该工艺实现了工业上的优点，即催化剂具有高活性，并产生具有优异的立构规整性的聚合物。

2. 发明授权

US5091353A Process for producing ethylene copolymer 失效
标题翻译：生产乙烯共聚物的方法
公开(公告)号：US5091353A
公开(公告)日：1992-02-25
申请号：US423586
申请日：1989-10-17
申请人： Mamoru Kioka , Norio Kashiwa
发明人： Mamoru Kioka , Norio Kashiwa
IPC分类号： C08F4/00 , C08F4/60 , C08F4/638 , C08F4/64 , C08F4/654 , C08F10/00 , C08F210/02 , C08F210/16
CPC分类号： C08F210/16 , Y10S526/909
摘要： An improved process for producing an ethylene copolymer composed of a major proportion of ethylene and a minor proportion of an alpha-olefin having 3 to 10 carbon atoms and having a density of 0.910 to 0.945 g/cm.sup.3 and an ethylene content of 85 to 99.5 mole %. The use of a titanium catalyst component (A) which meets a parametric combination of specific requirements is essential in this process. The process can industrially advantageously give a low to medium density ethylene copolymer of high quality with high productivity while advantageously circumventing the operational troubles which have been difficult to avoid by conventional processes.
摘要翻译：一种制备乙烯共聚物的改进方法，该乙烯共聚物由主要比例的乙烯和少量的具有3-10个碳原子的α-烯烃组成，密度为0.910至0.945g / cm3，乙烯含量为85-99.5摩尔％。使用符合特定要求的参数组合的钛催化剂组分（A）在该方法中是至关重要的。该方法可以在工业上有利地以高生产率产生高质量的低至中密度乙烯共聚物，同时有利地避免了常规方法难以避免的操作麻烦。

3. 发明授权

US4673719A Process for producing olefin polymers and catalyst composition therefor 失效
标题翻译：制备烯烃聚合物的方法及其催化剂组合物
公开(公告)号：US4673719A
公开(公告)日：1987-06-16
申请号：US563320
申请日：1983-12-20
申请人： Mamoru Kioka , Norio Kashiwa
发明人： Mamoru Kioka , Norio Kashiwa
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F4/658 , C08F10/00 , C08F10/02
CPC分类号： C08F10/00
摘要： In a process for producing olefin polymers or copolymers which comprises polymerizing olefins or copolymerizing olefins with each other or with dienes in the presence of [A] a solid titanium catalyst component containing magnesium, titanium and halogen as essential ingredients and [B] an organometallic compound of a metal selected from the group consisting of metals of Groups I to III of the periodic table; the improvement wherein said catalyst component [A] is obtained by contacting (i) a magnesium compound in the liquid state with (ii) a titanium compound in the liquid state to form a solid product or first preparing a liquid mixture of the magnesium compound (i) and the titanium compound (ii) and then forming a solid product therefrom, said reaction of forming the solid product being carried out in the presence of at least one electron donor (iii) selected from the group consisting of aliphatic carboxylic acids with 1 to 6 carbon atoms, aryloxy group-containing alcohols, alkylene glycol diethers, aluminum trialkoxides and aluminum triaryloxides, said solid product being not contacted, during or after its formation, with an ester selected from the group consisting of esters of polycarboxylic acids and esters of polyhydroxy compounds.
摘要翻译：在制备烯烃聚合物或共聚物的方法中，其包括在[A]含有镁，钛和卤素作为必需成分的固体钛催化剂组分的存在下彼此聚合烯烃或共聚烯烃或与二烯共聚，[B]有机金属化合物的选自元素周期表第I至III族的金属的金属; 其中所述催化剂组分[A]是通过使（i）液态镁化合物与（ii）液态的钛化合物接触形成固体产物或首先制备镁化合物的液体混合物 i）和钛化合物（ii），然后由其形成固体产物，所述形成固体产物的反应在至少一种选自脂肪族羧酸与1族的电子给体（iii）的存在下进行，至少6个碳原子，含芳氧基的醇，亚烷基二醇二醚，三烷氧基铝和三芳基铝，所述固体产物在其形成期间或之后不与选自以下的酯接触：多羧酸和酯的酯多羟基化合物。

4. 发明授权

US5075396A Process and catalyst composition for producing olefin polymers 失效
标题翻译：用于生产烯烃聚合物的方法和催化剂组合物
公开(公告)号：US5075396A
公开(公告)日：1991-12-24
申请号：US331221
申请日：1989-03-31
申请人： Norio Kashiwa , Akinori Toyota , Mamoru Kioka
发明人： Norio Kashiwa , Akinori Toyota , Mamoru Kioka
IPC分类号： C08F4/00 , C08F4/46 , C08F4/60 , C08F4/64 , C08F4/658 , C08F10/00
CPC分类号： C08F10/00
摘要： A process for producing a polymer or copolymer of an olefin which comprises polymerizing or copolymerizing at least one olefin with or without a diolefin in the presence of a catalyst composed of (A) a magnesium-containing solid titanium catalyst component containing magnesium, titanium, a halogen and an electron donor as essential ingredients and (B) an organoaluminum compound catalyst component; characterized in that(1) said catalyst further comprises (C) an organic silicon compound catalyst component having an Si--O--C or Si--N--C bond, and(2) said electron donor in the catalyst component (A) is a cyclic mono- or poly-ester such as diethyl furane-3,4-dicarboxylate, di-n-butyl 3,4-dihydro-2H-pyrane-5,6-dicarboxylate, di-isobutyl pyrrole-2,3-dicarboxylic, di-n-butyl thiophene-2,3-dicarboxylate, n-octyl pyrrolidine-2,3-dicarboxylate, and so on.

5. 发明授权

US5055528A Process for producing propylene copolymers 失效
标题翻译：生产丙烯共聚物的方法
公开(公告)号：US5055528A
公开(公告)日：1991-10-08
申请号：US465648
申请日：1990-01-22
申请人： Mamoru Kioka , Akinori Toyota , Norio Kashiwa
发明人： Mamoru Kioka , Akinori Toyota , Norio Kashiwa
IPC分类号： C08F4/64 , C08F4/42 , C08F4/60 , C08F10/06 , C08F210/06 , C08F297/08 , C08L23/10 , C08L23/16
CPC分类号： C08F297/083 , C08L23/10 , C08L2205/02 , C08L23/16
摘要： A process for producing a propylene polymer having good flowability with an MFR of at least 10 g/10 minutes comprises a first polymerization stage consisting of at least two steps and a subsequent second polymerization stage. It is important to control the intrinsic viscositites of a crystalline propylene polymer obtained from the first step of the first polymerization stage and a crystalline propylene polymer obtained from the final step of the first polymerization stage.

6. 发明授权

US4952540A Finely divided aluminoxane, process for producing same and its use 失效
标题翻译：细分铝氧烷，生产方法及其用途
公开(公告)号：US4952540A
公开(公告)日：1990-08-28
申请号：US155075
申请日：1988-02-11
申请人： Mamoru Kioka , Norio Kashiwa
发明人： Mamoru Kioka , Norio Kashiwa
IPC分类号： C10G57/02 , C07F5/06 , C08F4/52 , C08F4/60 , C08F4/6192 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08G79/00 , C08G79/10 , C10G50/00
CPC分类号： C08G79/10 , C07F5/068 , C08F10/00 , C08F4/65912 , C08F4/6592 , Y10S526/904 , Y10S526/908 , Y10S526/943
摘要： A finely divided aluminoxane comprising an aluminoxane represented by formula [I] or [II] ##STR1## wherein R denotes a hydrocarbon group having 1 to 10 carbon atoms and m denotes an integer of 2 to 50,an average particle size being 5 to 200 .mu.m and a specific an average particle size being 5 to 200 .mu.m and a specific surface area being 20 to 1000 m.sup.2 /g, a process for producing same, and a catalyst component for polymerization of olefins being said finely divided aluminoxane.

7. 发明授权

US4921825A Solid catalyst for olefin polymerization and processes for its production 失效
标题翻译：用于烯烃聚合的固体催化剂及其生产方法
公开(公告)号：US4921825A
公开(公告)日：1990-05-01
申请号：US245399
申请日：1988-08-23
申请人： Mamoru Kioka , Norio Kashiwa
发明人： Mamoru Kioka , Norio Kashiwa
IPC分类号： C08F4/642 , C08F4/60 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F210/16
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , C08F4/65912 , C08F4/65916 , C08F4/6592 , Y10S526/943
摘要： This invention is a catalyst for polymerization of olefins, comprising a compound of a transition metal of Group IVB of the periodic table, an aluminoxane and a particulate organic or inorganic compound carrier.This catalyst shows very high activity in the polymerization and copolymerization of olefins and gives polymers having a high bulk density, a uniform particle size, a low content of fine particles and a narrow molecular weight distribution and in the case of copolymers, a narrow composition distribution as well.
摘要翻译： PCT No.PCT / JP87 / 01047 Sec。 371日期1988年8月23日 102（e）日期1988年8月23日PCT提交1987年12月28日PCT公布。公开号WO88 / 05058 日本特许公报1988年7月14日。本发明是烯烃聚合催化剂，其包括周期表第IVB族过渡金属的化合物，铝氧烷和有机或无机化合物颗粒。该催化剂在烯烃的聚合和共聚中显示出非常高的活性，并且得到具有高堆积密度，均匀粒径，低含量的细颗粒和窄分子量分布的聚合物，在共聚物的情况下，组成分布窄以及。

8. 发明授权

US4668753A Film-forming propylene copolymer, film thereof and process for production of the film 失效
标题翻译：成膜丙烯共聚物，其膜及其制造方法
公开(公告)号：US4668753A
公开(公告)日：1987-05-26
申请号：US899796
申请日：1986-08-25
申请人： Norio Kashiwa , Mamoru Kioka , Masaki Kohyama , Masanobu Ishiyama
发明人： Norio Kashiwa , Mamoru Kioka , Masaki Kohyama , Masanobu Ishiyama
IPC分类号： C08F210/06 , C08F210/16 , C08J5/18 , C08F10/06
CPC分类号： C08J5/18 , C08F210/06 , C08F210/16 , C08J2323/16
摘要： A film-forming propylene copolymer composed of a major amount of propylene and a minor amount of ethylene, characterized by having(A) an ethylene content (Ec) of from 0.1 mole % to 2.0 mole % based on the total amount of propylene and ethylene, and(B) an isotactic value (Iso) in the range represented by the following formula (1) or (2),(i) when 0.1.ltoreq.Ec.ltoreq.0.3,Iso.gtoreq.-5Ec30 96.3 (%) (1),and(ii) when 0.3
摘要翻译：由主要量的丙烯和少量乙烯组成的成膜丙烯共聚物，其特征在于（A）乙烯含量（Ec）为丙烯和乙烯的总量的0.1摩尔％至2.0摩尔％，和（B）当由下式（1）或（2）表示的范围内的全同立构度值（Iso）：（i）当0.1≤Eu≤0.3时，Iso> = -5_E + 96.3（％）（1）和（ii）当0.3 / = - 0.67_E + 95.0（％）（2）其中_E表示Ec（摩尔％）的数值; 共聚物膜; 以及该膜的制造方法。

9. 发明授权

US6063726A Catalyst for polymerizing alpha-olefins and process for polymerization 失效
标题翻译：用于聚合α-烯烃的催化剂和聚合方法
公开(公告)号：US6063726A
公开(公告)日：2000-05-16
申请号：US862174
申请日：1997-05-22
申请人： Mamoru Kioka , Akinori Toyota , Norio Kashiwa , Toshiyuki Tsutsui
发明人： Mamoru Kioka , Akinori Toyota , Norio Kashiwa , Toshiyuki Tsutsui
IPC分类号： C08F4/02 , C08F4/655 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/10 , C08F110/02 , C08F4/64
CPC分类号： C08F10/00 , C08F10/10 , C08F110/02 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65925 , Y10S526/901 , Y10S526/943
摘要： The invention relates to a polymerization catalyst for alpha-olefins and a process for polymerizing alpha-olefins. The catalyst comprises a component having a transition metal compound supported on a carrier and an aluminoxane. The carrier may be pre-treated with an organometallic compound, a halogen-containing silicon compound or an aluminoxane. Alternatively, the above two catalyst components are subjected to preliminary polymerization of olefins. The catalyst of this invention enables the production of a spherical polymer having a good particle size distribution, an excellent bulk density and a narrow molecular weight distribution in a slurry polymerization method or a vapor-phase polymerization method, particulary the vapor-phase polymerization method. When applied to the copolymerization of at least two olefins, the catalyst has excellent polymerization activity such that an olefin copolymer having a narrow molecular weight distribution and a narrrow composition distribution is obtained.
摘要翻译：本发明涉及α-烯烃的聚合催化剂和α-烯烃的聚合方法。催化剂包含负载在载体上的过渡金属化合物和铝氧烷的组分。载体可以用有机金属化合物，含卤素的硅化合物或铝氧烷进行预处理。或者，将上述两种催化剂组分进行烯烃的预聚合。本发明的催化剂能够制备在淤浆聚合法或气相聚合法中具有良好的粒度分布，优异的堆积密度和窄分子量分布的球形聚合物，特别是气相聚合法。当应用于至少两种烯烃的共聚时，催化剂具有优异的聚合活性，从而获得具有窄分子量分布和叙述组成分布的烯烃共聚物。

10. 发明授权

US5206199A Catalyst for polymerizing an olefin and process for polymerizing an olefin 失效
标题翻译：用于聚合烯烃的催化剂和烯烃聚合方法
公开(公告)号：US5206199A
公开(公告)日：1993-04-27
申请号：US860014
申请日：1992-03-30
申请人： Mamoru Kioka , Norio Kashiwa , Toshiyuki Tsutsui , Akinori Toyota
发明人： Mamoru Kioka , Norio Kashiwa , Toshiyuki Tsutsui , Akinori Toyota
IPC分类号： C08F4/659 , C08F4/6592 , C08F10/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/6592 , Y10S526/943
摘要： An olefin is polymerized or copolymerized under the presence of an olefin-polymerizing catalyst prepared from (A) a transition-metal compound or (A') a transition-metal compound loaded on a fine-particle carrier, said transition metal being selected from group IVB in the periodic table; (B) an aluminoxane; and (C) an organoaluminum compound represented by the general formula [I] or [II]:R.sup.1.sub.m Al(OR.sup.2).sub.3-m [I]R.sup.3.sub.n Al(OSiR.sup.4.sub.3).sub.3-n [II]wherein R.sup.1, R.sup.2, and R.sup.3 are selected from hydrocarbon radicals, R.sup.4 is selected from the group consisting of hydrocarbon, alkoxy, and aryloxy radicals, and m and n are positive numbers of 0
摘要翻译：在由（A）过渡金属化合物或（A'）负载在细颗粒载体上的过渡金属化合物制备的烯烃聚合催化剂存在下，烯烃聚合或共聚，所述过渡金属选自 IVB在周期表中; （B）铝氧烷; 和（C）由通式[I]或[II]表示的有机铝化合物：R1mA1（OR2）3-m [I] R3nAl（OSiR43）3-n [II]其中R1，R2和R3选自烃基，R 4选自烃，烷氧基和芳氧基，m和n是0

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