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1. 发明授权

US5256526A Cyan image forming method and silver halide color photographic material containing cyan coupler 失效
标题翻译：青色成像方法和含有青色成色剂的卤化银彩色照相材料
公开(公告)号：US5256526A
公开(公告)日：1993-10-26
申请号：US800082
申请日：1991-11-29
申请人： Makoto Suzuki , Tadahisa Sato , Kozo Sato , Yoshio Ishii , Hideaki Naruse , Yasuhiro Shimada
发明人： Makoto Suzuki , Tadahisa Sato , Kozo Sato , Yoshio Ishii , Hideaki Naruse , Yasuhiro Shimada
IPC分类号： G03C7/305 , G03C7/38 , G03C7/407
CPC分类号： G03C7/30529 , G03C7/383
摘要： A silver halide color photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer containing at least one 1H-pyrrolo[1,2-b][1,2,4]triazole cyan coupler represented by the following general formula (I) or (II): ##STR1## wherein R.sub.1 and R.sub.2 each represents an electron withdrawing group having a Hammett's substituent constant .sigma.p value of 0.20 or more; R.sub.1 and R.sub.2 may be bonded to form a ring; the sum of a Hammett's substituent constant .sigma.p value of R.sub.1 and R.sub.2 is 0.65 or more; R.sub.3 represents a hydrogen atom or a substituent; and X represents a hydrogen atom or a substituent capable of being released upon coupling with an oxidation product of an aromatic primary amine color developing agent; said coupler may be in a form of a bis-compound or a polymer formed at R.sub.1, R.sub.2, R.sub.3 or X; and a cyan image forming method comprising imagewise exposing a silver halide color photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer and subjecting the exposed photographic material to color development with an aromatic primary amine color dveloping agent at the presence of the above-described 1H-pyrrolo[1,2-b][1,2,4]triazole cyan coupler.

2. 发明授权

US5162196A Color coupler for photography and silver halide photographic material comprising the same 失效
标题翻译：用于摄影和银色摄影材料的彩色耦合器
公开(公告)号：US5162196A
公开(公告)日：1992-11-10
申请号：US615797
申请日：1990-11-20
申请人： Kozo Sato , Yasuhiro Shimada , Hideaki Naruse
发明人： Kozo Sato , Yasuhiro Shimada , Hideaki Naruse
IPC分类号： C07C255/23 , C07C255/30 , C07C255/34 , C07C255/35 , C07C255/41 , C07C255/44 , C07C255/45 , G03C7/36
CPC分类号： C07C255/45 , C07C255/23 , C07C255/30 , C07C255/34 , C07C255/35 , C07C255/41 , C07C255/44 , G03C7/36
摘要： The present invention relates to a novel color coupler for photography and a silver halide color photographic material comprising the same, wherein the color coupler is one of the .beta.,.gamma.-unsaturated nitriles represented by formula (I). The invention provides for a color coupler, particularly a cyan coupler, which forms color images less in subsidiary absorption, good in color reproduction, and excellent in fastness, and a silver halide color photographic material having color images as described above. Further the color coupler can be synthesized from inexpensive raw material at a low cost ##STR1## wherein W represents a hydrogen atom or a group capable of being released when the compound is subjected to a coupling reaction with the oxidized product of an aromatic primary amine derivative, R.sub.1 represents a represents a nitrogen atom, R.sub.2 represents a substituent, if V represents ##STR2## R.sub.2 and R.sub.3 each represent substituent, provided that at least one of R.sub.2 and R.sub.3 represents an electron attractive substituent, and provided that if R.sub.2 or R.sub.3 represents an aliphatic group or an aromatic group, the other does not represent an acyl group, and R.sub.1 and R.sub.2 may bond together to form a ring.

3. 发明授权

US5362882A Pyrrolotriazole derivative and heat transfer dye providing material containing a pyrrolotriazole azomethine dye 失效
标题翻译：吡咯并三唑衍生物和含有吡咯并三唑甲脒染料的热转印染料
公开(公告)号：US5362882A
公开(公告)日：1994-11-08
申请号：US894573
申请日：1992-06-05
申请人： Makoto Suzuki , Yasuhiro Shimada , Koushin Matsuoka , Shigeru Yamazaki , Katsuyoshi Yamakawa , Kozo Sato
发明人： Makoto Suzuki , Yasuhiro Shimada , Koushin Matsuoka , Shigeru Yamazaki , Katsuyoshi Yamakawa , Kozo Sato
IPC分类号： C07D487/04 , C09B55/00 , G03C7/38 , C07D487/14 , G03C7/36
CPC分类号： C07D487/04 , C09B55/009 , G03C7/383
摘要： A novel pyrrolotriazole derivative is disclosed, represented by any one of formulae (I), (II), (III), (IV), or (V): ##STR1## A heat transfer dye providing material is also disclosed, comprising a support having thereon a dye providing layer containing a heat migrating dye, said dye providing layer containing at least one pyrrolotriazole azomethine dye represented by any one of formulae (I), (II), (III), or (IV).
摘要翻译：公开了由式（I），（II），（III），（IV）或（V）中的任一个表示的新颖的吡咯并三唑衍生物：其中（IMA）（V）还公开了一种传热染料提供材料，其包括其上具有含有热迁移染料的染料提供层的载体，所述染料提供层含有至少一种吡咯并三唑甲脒染料由式（I），（II），（III）或（IV）中的任一个表示。

4. 发明授权

US5508421A Pyrrolotriazole azomethine dye, and heat transfer dye providing material containing a pyrrolotriazole azomethine dye 失效
标题翻译：吡咯三唑偶氮甲碱染料和含有吡咯并三唑甲脒染料的热转印染料
公开(公告)号：US5508421A
公开(公告)日：1996-04-16
申请号：US279191
申请日：1994-07-22
申请人： Makoto Suzuki , Hisashi Mikoshiba , Seiiti Kubodera , Osamu Takahashi , Yasuhiro Shimada , Koushin Matsuoka , Shigeru Yamazaki , Katsuyoshi Yamakawa , Kozo Sato
发明人： Makoto Suzuki , Hisashi Mikoshiba , Seiiti Kubodera , Osamu Takahashi , Yasuhiro Shimada , Koushin Matsuoka , Shigeru Yamazaki , Katsuyoshi Yamakawa , Kozo Sato
IPC分类号： C07D487/04 , C09B55/00 , G03C7/38 , G03C7/36
CPC分类号： C07D487/04 , C09B55/009 , G03C7/383
摘要： A pyrrolotriazole azomethine dye represented by formula (I), (II) or (IV) is disclosed: ##STR1## Also, a heat transfer dye providing material is disclosed, in which the material includes a support having thereon a dye providing layer containing a heat migrating dye, with the dye providing layer containing at least one pyrrolotriazole azomethine dye represented by any of the above formulae (I), (II) and (IV).
摘要翻译：（I），（II）或（IV）表示的吡咯并三氮唑代甲基染料被公开：公开了一种传热染料提供材料，其中所述材料包括其上具有含有热迁移染料的染料提供层的载体，所述染料提供层含有至少一种由上述式（I），（II）和（IV）中的任何一种表示的吡咯并三唑甲脒染料。

5. 发明授权

US5164289A Dye forming coupler and silver halide color photographic material containing the same and method for forming color image 失效
标题翻译：含有它的成色偶联剂和银色彩色摄影材料和形成彩色图像的方法
公开(公告)号：US5164289A
公开(公告)日：1992-11-17
申请号：US696848
申请日：1991-05-07
申请人： Yasuhiro Shimada , Yoshio Ishii , Jiro Tsukahara , Makoto Suzuki , Koushin Matsuoka
发明人： Yasuhiro Shimada , Yoshio Ishii , Jiro Tsukahara , Makoto Suzuki , Koushin Matsuoka
IPC分类号： C07D487/04 , G03C7/305 , G03C7/38 , G03C7/42
CPC分类号： C07D487/04 , G03C7/30529 , G03C7/3825
摘要： A silver halide photographic material containing at least one dye forming coupler represented by formula (I): ##STR1## wherein R.sub.0 represents a hydrogten atom or a substituent; R.sub.1 and R.sub.3 each represents a substituent; R.sub.2 represents an electron attracting group; X represents a hydrogen atom or a group releasable on coupling with an oxidation product of an aromatic primary amine derivative, and a silver halide photographic material containing the same are disclosed. The coupler of formula (I) exhibits excellent coupling activity and provides a dye which has a sharp absorption spectrum with no side absorption in the blue and green light regions and exhibits stability to light, heat and moisture and improved color reproducibility.

6. 发明授权

US5292630A Silver halide color photographic material containing an imidazotriazole cyan coupler 失效
标题翻译：含有咪唑并三唑青色成色剂的卤化银彩色照相材料
公开(公告)号：US5292630A
公开(公告)日：1994-03-08
申请号：US18454
申请日：1993-02-16
申请人： Yasuhiro Shimada , Kozo Sato
发明人： Yasuhiro Shimada , Kozo Sato
IPC分类号： G03C7/305 , G03C7/38
CPC分类号： G03C7/30529 , G03C7/3835
摘要： A silver halide color photographic material containing one or more imidazotriazole cyan couplers each having an electron attracting group with a .sigma.p of 0.35 or more in at least one layer on the support. The material provides a cyan color image having a sharp light absorption characteristic absorbing light having a relatively long wavelength falling within a narrow wavelength range. The imidazotriazole cyan coupler is of the following structural formula (I): ##STR1## where R.sub.1 represents a hydrogen atom or a substituent; R.sub.2 represents an electron attracting group having a Hammett's constant value .sigma.p of 0.35 or ore; X represents a hydrogen atom or a group released by coupling with an oxidation product of an aromatic primary amine color developing agent; and R.sub.1 or R.sub.2 may also be a divalent group forming a dimer or higher polymer, or they each may be bonded to a polymer chain to form a homopolymer or copolymer.
摘要翻译：含有一种或多种咪唑并三唑青色成色剂的卤化银彩色照相材料，其各自具有在载体上的至少一层中（Sigma）p为0.35以上的吸电子基团。该材料提供了具有吸收特征的清晰吸收特征的青色图像，该特征吸收了波长较小的较长波长的光。咪唑并三唑青色成色剂具有以下结构式（I）：（*化学结构*）（I）其中R1表示氢原子或取代基; R2表示哈米特常数值（Sigma）p为0.35或矿石的吸电子基团; X表示氢原子或通过与芳族伯胺显色剂的氧化产物偶联而释放的基团; 并且R 1或R 2也可以是形成二聚体或更高级聚合物的二价基团，或者它们各自可以与聚合物链结合以形成均聚物或共聚物。

7. 发明授权

US5272051A Silver halide color photographic material 失效
标题翻译：卤化银彩色照相材料
公开(公告)号：US5272051A
公开(公告)日：1993-12-21
申请号：US788432
申请日：1991-11-06
申请人： Yasuhiro Shimada , Yoshio Ishii
发明人： Yasuhiro Shimada , Yoshio Ishii
IPC分类号： G03C7/38
CPC分类号： G03C7/383
摘要： A silver halide color photographic material is disclosed, which comprises a support thereon having at least one red-sensitive silver halide emulsion layer, in which the red-sensitive silver halide emulsion layer contains at least one cyan coupler of the general formula (I): ##STR1## wherein R represents a substituent;EWG represents an electron-attracting substituent which does not substantially split off from the formula on reaction of the coupler with an oxidation product of an aromatic primary amine developing agent; EWG' represents an electron-attracting substituent having a Hammett's substituent constant .sigma..sub.p of 0.3 or more, other than a perfluoroalkyl group; andW represents a hydrogen atom or a releasable group which splits off on reaction of the coupler with an oxidation product of an aromatic primary amine developing agent.
摘要翻译：公开了一种卤化银彩色照相材料，其包含其上具有至少一种感红卤化银乳剂层的载体，其中红敏卤化银乳剂层含有至少一种通式（I）的青色成色剂：（I）其中R表示取代基; EWG表示电子吸引取代基，其在偶联剂与芳族伯胺显影剂的氧化产物反应时基本上不脱离式; EWG'表示除了全氟烷基之外的哈米特取代基常数σp为0.3以上的吸电子取代基; W表示氢原子或在偶合剂与芳族伯胺显影剂的氧化产物反应时分解的可释放基团。

8. 发明授权

US5187055A Silver halide color photographic material 失效
公开(公告)号：US5187055A
公开(公告)日：1993-02-16
申请号：US284047
申请日：1988-12-14
申请人： Hidetoshi Kobayashi , Yasuhiro Shimada , Seiji Ichijima , Yoshio Ishii
发明人： Hidetoshi Kobayashi , Yasuhiro Shimada , Seiji Ichijima , Yoshio Ishii
IPC分类号： G03C7/36 , G03C7/305
CPC分类号： G03C7/30558 , G03C7/30535
摘要： A silver halide color photographic material having at least one silver halide emulsion layer on a support, said photographic material containing at least one coupler represented by the following general formula (I) in a constituent layer, ##STR1## wherein R.sub.1 and R.sub.2, which may be the same or different, each represents an alkyl, alkoxy, alkylthio, alkylsulfonyl, alkoxycarbonyl, alkoxysulfonyl, aryl, aryloxy, arylthio, arylsulfonyl and aryloxycarbonyl group; R.sub.3 and R.sub.4, which may be the same or different, each represents a group by which benzene can be substituted; Z represents nonmetal atoms necessary to form a 5- to 7-membered single or condensed hetero ring together with the nitrogen atom; and m and n each represents an integer of from 0 to 4, and when they are each a plural number, a plural R.sub.3 or a plural R.sub.4 may be the same or different.

9. 发明授权

US5206130A Cyan coupler, cyan image forming method using the same and silver halide color photographic material containing the same 失效
标题翻译：青色耦合器，使用相同的青色成像方法和含有相同的卤化银彩色照相材料
公开(公告)号：US5206130A
公开(公告)日：1993-04-27
申请号：US788416
申请日：1991-11-06
申请人： Yasuhiro Shimada , Yoshio Ishii
发明人： Yasuhiro Shimada , Yoshio Ishii
IPC分类号： G03C7/30 , G03C7/38
CPC分类号： G03C7/383
摘要： Disclosed is a silver halide color photographic material comprising a support thereon having at least one silver halide emulsion layer containing at least one cyan coupler of the general formula (I): ##STR1## where R represents a group capable of being an imidazo[1,2-b]pyrazole skeletal substituent;EWG represents an electron-attracting substituent which does not substantially split off from the formula on reaction of the coupler with an oxidation product of an aromatic primary amine developing agent;X represents a hydrogen atom or a releasable group which splits off from the formula on reaction of the coupler with an oxidation product of an aromatic primary amine developing agent; andn represents an integer of from 1 to 7,providing an excellent cyan dye and cyan image having satisfactory absorption characteristic and color fastness.
摘要翻译：公开了一种卤化银彩色照相材料，其上含有至少一个含有至少一个通式（I）的青色成色剂的卤化银乳剂层的载体：其中R表示可以是咪唑的基团 [1,2-b]吡唑骨架取代基; EWG表示电子吸引取代基，其在偶联剂与芳族伯胺显影剂的氧化产物反应时基本上不脱离式; X表示氢原子或可与该芳香族伯胺显影剂的氧化产物反应的分子式的可释放基团; n表示1〜7的整数，提供了具有令人满意的吸收特性和色牢度的优异的青色染料和青色图像。

10. 发明授权

US5691125A Silver halide color photographic material 失效
标题翻译：卤化银彩色照相材料
公开(公告)号：US5691125A
公开(公告)日：1997-11-25
申请号：US665897
申请日：1996-06-19
申请人： Takefumi Hara , Kazuyoshi Yamakawa , Sadanobu Shuto , Mitsuru Yamamoto , Makoto Suzuki , Yasuhiro Shimada , Katsuro Nagaoka , Satoshi Nagaoka , Yoshihiko Shibahara , Hideo Ikeda
发明人： Takefumi Hara , Kazuyoshi Yamakawa , Sadanobu Shuto , Mitsuru Yamamoto , Makoto Suzuki , Yasuhiro Shimada , Katsuro Nagaoka , Satoshi Nagaoka , Yoshihiko Shibahara , Hideo Ikeda
IPC分类号： G03C1/015 , G03C1/035 , G03C1/14 , G03C1/16 , G03C1/18 , G03C1/20 , G03C7/30 , G03C7/305 , G03C7/38 , G03C1/46
CPC分类号： G03C7/3041 , G03C1/14 , G03C7/30511 , G03C7/382 , G03C1/16 , G03C1/18 , G03C1/20
摘要： There is disclosed a silver halide color photographic material having a red-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer, a blue-sensitive silver halide emulsion layer, which comprises a cyan dye-forming coupler represented by formula (I) and (a) a monodisperse silver halide emulsion, (b) non-photosensitive silver halide emulsion wherein the inside or the surface of grains is fogged, (c) a colloidal silver, (d) negative-type interval latent image-type silver halide grains chemically sensitized to a defined depth from the surface, (e) a sensitizing dye containing a sulfonamide group, (f) three separated layers of high, medium, and low sensitivities, (g) two separated layers each having different content of iodine, (h) grains each having a defined spectral sensitivity distribution and a DIR-hydroquinone, or (i) a DIR-hydroquinone: formula (I) ##STR1## wherein R.sup.1 represents a hydrogen atom or a substituent, R.sup.2 represents a substituent, X represents a hydrogen atom or a group capable of being released upon a coupling reaction of the coupler represented by formula (I) with the oxidized product of a color-developing agent, and Z.sup.1 represents a group of nonmetallic atoms required for forming a nitrogen-containing 6-membered heterocyclic ring, which contains at least one group capable of being dissociated.
摘要翻译：公开了具有感红卤化银乳剂层，感绿卤化银乳剂层，感蓝卤化银乳剂层的卤化银彩色照相材料，其包含由式（I）表示的青色染料形成成色剂）和（a）单分散卤化银乳剂，（b）非感光卤化银乳剂，其中颗粒的内部或表面起雾，（c）胶态银，（d）负型间隔潜像型银（e）含有磺酰胺基团的敏化染料，（f）三种高，中，低灵敏度的分离层，（g）两个分开的层，每层具有不同的碘含量，（h）各自具有限定的光谱灵敏度分布的颗粒和DIR-氢醌，或（i）DIR-氢醌：式（I）其中R 1表示氢原子或取代基，R 2表示取代基，X 代表氢原子或能够由式（I）表示的成色剂与显色剂的氧化物偶联反应后释放的基团，Z1表示形成含氮6的所需非金属原子团含有至少一个能够解离的基团。

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