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1. 发明申请

US20100105901A1 SYNTHESIS METHOD OF POLYMER COMPLEX CRYSTAL 有权
标题翻译：聚合物复合晶体的合成方法
公开(公告)号：US20100105901A1
公开(公告)日：2010-04-29
申请号：US12530240
申请日：2009-03-07
申请人： Makoto Fujita , Masaki Kawano , Tsuyoshi Haneda , Kiyoshi Nakanishi , Takahiro Kojima
发明人： Makoto Fujita , Masaki Kawano , Tsuyoshi Haneda , Kiyoshi Nakanishi , Takahiro Kojima
IPC分类号： C07F3/06
CPC分类号： C07D401/14 , C09K19/3475 , C09K19/40
摘要： Disclosed is a synthesis method for synthesizing in a short time and selectively a microcrystal of a polymer complex having three three-dimensionally and regularly arranged channels.Specifically disclosed is a synthesis method of a polymer complex crystal wherein (1) a metallic solution, which is a mixture of zinc halide(II) and a solvent A that can dissolve the zinc halide, is mixed with (2) a ligand solution, which is a mixture of a tridentate ligand that has three coordination sites coordinated to zinc of the zinc halide and a solvent B that can dissolve the tridentate ligand, to be a single-phase solution, thereby synthesizing a microcrystal of a polymer complex having a three-dimensional coordination network formed by coordinating the tridentate ligand to the zinc and having channels that are three-dimensionally and regularly arranged in the three-dimensional coordination network.
摘要翻译：公开了一种用于在短时间内合成具有三个三维和规则排列的通道的聚合物复合物的微晶体的合成方法。具体公开了一种聚合物络合物晶体的合成方法，其中（1）将卤化锌（II）和可溶解卤化锌的溶剂A的混合物的金属溶液与（2）配体溶液混合，其是具有与卤化锌的锌配位的三个配位点和能够溶解三齿配体的溶剂B的三齿配体的混合物，作为单相溶液，由此合成具有三元组分的聚合物配合物的微晶体通过将三齿配体与锌配位并且具有三维和规则地排列在三维协调网络中的通道形成的三维配位网络。

2. 发明授权

US08288535B2 Synthesis method of polymer complex crystal 有权
标题翻译：聚合物复合晶体的合成方法
公开(公告)号：US08288535B2
公开(公告)日：2012-10-16
申请号：US12530240
申请日：2008-03-07
申请人： Makoto Fujita , Masaki Kawano , Tsuyoshi Haneda , Kiyoshi Nakanishi , Takahiro Kojima
发明人： Makoto Fujita , Masaki Kawano , Tsuyoshi Haneda , Kiyoshi Nakanishi , Takahiro Kojima
IPC分类号： C07F3/06
CPC分类号： C07D401/14 , C09K19/3475 , C09K19/40
摘要： Disclosed is a synthesis method for synthesizing in a short time and selectively a microcrystal of a polymer complex having three three-dimensionally and regularly arranged channels.Specifically disclosed is a synthesis method of a polymer complex crystal wherein (1) a metallic solution, which is a mixture of zinc halide(II) and a solvent A that can dissolve the zinc halide, is mixed with (2) a ligand solution, which is a mixture of a tridentate ligand that has three coordination sites coordinated to zinc of the zinc halide and a solvent B that can dissolve the tridentate ligand, to be a single-phase solution, thereby synthesizing a microcrystal of a polymer complex having a three-dimensional coordination network formed by coordinating the tridentate ligand to the zinc and having channels that are three-dimensionally and regularly arranged in the three-dimensional coordination network.
摘要翻译：公开了一种用于在短时间内合成具有三个三维和规则排列的通道的聚合物复合物的微晶体的合成方法。具体公开了一种聚合物络合物晶体的合成方法，其中（1）将卤化锌（II）和可溶解卤化锌的溶剂A的混合物的金属溶液与（2）配体溶液混合，其是具有与卤化锌的锌配位的三个配位点和能够溶解三齿配体的溶剂B的三齿配体的混合物，作为单相溶液，由此合成具有三元组分的聚合物配合物的微晶体通过将三齿配体与锌配位并且具有三维和规则地排列在三维协调网络中的通道形成的三维配位网络。

3. 发明授权

US08236867B2 Polymer complex having channels and method for chemically modifying inner surfaces of channels of polymer complex 有权
标题翻译：具有通道的聚合物复合物和用于化学改性聚合物复合物通道内表面的方法
公开(公告)号：US08236867B2
公开(公告)日：2012-08-07
申请号：US12449925
申请日：2008-03-07
申请人： Makoto Fujita , Masaki Kawano , Takehide Kawamichi , Kiyoshi Nakanishi , Takahiro Kojima , Tomoki Kodama
发明人： Makoto Fujita , Masaki Kawano , Takehide Kawamichi , Kiyoshi Nakanishi , Takahiro Kojima , Tomoki Kodama
IPC分类号： C08G79/00 , C07C249/02 , C08L101/02 , C08K5/3492
CPC分类号： C07D401/14 , C08G83/008 , C08K5/0091 , C08K5/34926
摘要： An embodiment of the present invention includes a method for chemically modifying inner surfaces of channels capable of further regulating characteristics of the internal environment of channels, by forming a polymer complex having a specific channel group B, the channel environmental characteristics of which are regulated by substituents A, followed by utilizing the channels of the channel group B as a reaction field to convert the substituent A to a different substituent. The method may comprise including a guest molecule in the channel of the channel group B in which the substituents A are arranged; and reacting the guest molecule with the substituent A in the channel to convert the substituent A to a substituent A′, and to arrange the substituent A′ regularly directing to the inside of the channel of the channel group B or any channel of other channel groups.
摘要翻译：本发明的一个实施方案包括通过形成具有特定通道基团B的通道环境特性由取代基调节的具有特定通道基团B的聚合物络合物来化学改性通道内表面的方法，该方法能够进一步调节通道内部环境的特性 A，然后利用通道组B的通道作为将取代基A转化为不同取代基的反应场。该方法可以包括在其中排列取代基A的通道基团B的通道中包含客体分子; 并使客体分子与通道中的取代基A反应，以将取代基A转化成取代基A'，并且将取代基A'定期地引导到通道组B的通道的内部或其它通道组的任何通道。

4. 发明申请

US20100324249A1 POLYMER COMPLEX HAVING CHANNELS AND METHOD FOR CHEMICALLY MODIFYING INNER SURFACES OF CHANNELS OF POLYMER COMPLEX 有权
公开(公告)号：US20100324249A1
公开(公告)日：2010-12-23
申请号：US12449925
申请日：2008-03-07
申请人： Makoto Fujita , Masaki Kawano , Takehide Kawamichi , Kiyoshi Nakanishi , Takahiro Kojima , Tomoki Kodama
发明人： Makoto Fujita , Masaki Kawano , Takehide Kawamichi , Kiyoshi Nakanishi , Takahiro Kojima , Tomoki Kodama
IPC分类号： C08G79/00
CPC分类号： C07D401/14 , C08G83/008 , C08K5/0091 , C08K5/34926
摘要： The present invention is to provide a method for chemically modifying the inner surfaces of channels capable of further regulating characteristics of the internal environment of channels, by forming a polymer complex having a specific channel group B, the channel environmental characteristics of which are regulated by a specific substituent A, followed by utilizing the channels of the channel group B as a reaction field to convert the substituent A to a different substituent, and also to provide a polymer complex having highly specific channel environmental characteristics obtained by the chemical modification method. A method for chemically modifying inner surfaces of channels of at least one kind of channel group in a polymer complex provided with two or more kinds of channel groups each composed of channels identical with one another and having inherent affinity for a guest molecule, wherein the polymer complex comprises an aromatic compound; has two or more coordinating sites as a ligand, a metal ion as a central metal, and an uncoordinating aromatic compound, has a three-dimensional lattice-like structure containing a stack structure comprising the uncoordinating aromatic compound intercalated between aromatic compound ligands in a three-dimensional coordination network formed by coordinating the aromatic compound ligands to the central metal ion, and is provided with two or more kinds of the channel groups in the three-dimensional coordination network, and the uncoordinating aromatic compound has a specific substituent A at a specific position on the aromatic ring thereof, and is arranged regularly such that the substituent A is directed to the inside of a specific channel group B out of the two or more kinds of channel groups, the method comprising the steps of: including the guest molecule in the channel of the channel group B in which the substituent A is arranged; and reacting the guest molecule with the substituent A in the channel to convert the substituent A to a substituent A′, and to arrange the substituent A′ regularly directing to the inside of the channel of the channel group B or any channel of other channel groups.

5. 发明申请

US20110098414A1 Polymer Complex 有权
标题翻译：聚合物复合物
公开(公告)号：US20110098414A1
公开(公告)日：2011-04-28
申请号：US12224805
申请日：2007-03-02
申请人： Makoto Fujita , Masaki Kawano , Takehide Chou , Takahiro Kojima
发明人： Makoto Fujita , Masaki Kawano , Takehide Chou , Takahiro Kojima
IPC分类号： C08F26/06
CPC分类号： C07D401/14 , A61K47/6949 , B01J31/1691 , B01J31/1815 , B01J2531/26 , B82Y5/00 , C07C29/76 , C07C205/06 , C07C211/61 , C07C2603/42 , C08G83/00 , C07C31/10
摘要： The invention provides a polymer complex having two or more kinds of channel groups through which specific compounds ranging from gaseous small molecules to large molecules such as proteins and other biomolecules can be selectively incorporated and/or released and/or transported. The polymer complex comprises an aromatic compound having two or more coordinating sites as a ligand, a metal ion as a central metal, and an uncoordinating aromatic compound, wherein the polymer complex has a three-dimensional lattice-like structure containing a stack structure comprising the uncoordinating aromatic compound intercalated between aromatic compound ligands in a three-dimensional coordination network formed by coordinating the aromatic compound ligands to the central metal ion, the three-dimensional lattice-like structure is provided with two or more kinds of channel groups each composed of channels identical with one another and having inherent affinity for guest components, the uncoordinating aromatic compound has a specific substituent A at a specific position on the aromatic ring thereof, and the uncoordinating aromatic compound is arranged regularly such that the substituent A is directed to the inside of a specific channel group B out of the two or more kinds of channel groups.
摘要翻译：本发明提供了一种具有两种或更多种通道基团的聚合物络合物，通过其可以选择性地并入和/或释放和/或输送从气态小分子到大分子（例如蛋白质和其它生物分子）的特定化合物。聚合物配合物包括具有两个或更多个配体位点作为配体，金属离子作为中心金属的芳族化合物和不协调的芳族化合物，其中所述聚合物配合物具有包含堆叠结构的三维格子状结构，通过将芳香族化合物配体与中心金属离子配位而形成的三维配位网络中的芳香族化合物配位体之间嵌入的不协调的芳香族化合物，三维格子状结构具有两个以上的通道，每个通道由通道彼此相同并且对客体成分具有固有的亲和性，所述非配位芳香族化合物在其芳香环上的特定位置具有特定的取代基A，并且所述不协调的芳香族化合物规则地排列，使得取代基A指向一个特定的渠道B组出来两种以上的cha nnel组。

6. 发明授权

US08530649B2 Polymer complex 有权
标题翻译：聚合物复合物
公开(公告)号：US08530649B2
公开(公告)日：2013-09-10
申请号：US12224805
申请日：2007-03-02
申请人： Makoto Fujita , Masaki Kawano , Takehide Chou , Takahiro Kojima
发明人： Makoto Fujita , Masaki Kawano , Takehide Chou , Takahiro Kojima
IPC分类号： C07F9/80
CPC分类号： C07D401/14 , A61K47/6949 , B01J31/1691 , B01J31/1815 , B01J2531/26 , B82Y5/00 , C07C29/76 , C07C205/06 , C07C211/61 , C07C2603/42 , C08G83/00 , C07C31/10
摘要： A polymer complex having two or more kinds of channel groups through which specific compounds ranging from gaseous small molecules to large molecules such as proteins and other biomolecules can be selectively incorporated and/or released and/or transported is provided. The polymer complex includes an aromatic compound ligand, a central metal ion, and an uncoordinating aromatic compound. In the polymer complex, the uncoordinating aromatic compound is intercalated between aromatic compound ligands in a three-dimensional coordination network. Each of two or more kinds of channel groups contains channels identical with one another and having inherent affinity for guest components. The uncoordinating aromatic compound has a specific substituent A at a specific position on the aromatic ring thereof, and the uncoordinating aromatic compound is arranged regularly such that the substituent A is directed to the inside of a specific channel group B out of the two or more kinds of channel groups.
摘要翻译：提供了具有两种或更多种通道基团的聚合物复合物，通过其可以选择性地并入和/或释放和/或输送从气态小分子到大分子（例如蛋白质和其它生物分子）的特定化合物。聚合物配合物包括芳香族化合物配体，中心金属离子和不协调的芳族化合物。在聚合物络合物中，不协调的芳族化合物插入在三维配位网络中的芳族化合物配体之间。两种或多种通道组中的每一个包含彼此相同的通道，并且对于客体组件具有固有的亲和性。不协调的芳香族化合物在其芳香环上的特定位置具有特定的取代基A，并且不均匀的芳香族化合物规则地排列，使得取代基A指向两种或更多种的特定通道群B的内部的频道组。

7. 发明授权

US08043730B2 Part for rotary machine, and manufacturing method therefor 有权
标题翻译：旋转机械的部件及其制造方法
公开(公告)号：US08043730B2
公开(公告)日：2011-10-25
申请号：US12320474
申请日：2009-01-27
申请人： Masaki Kawano , Toyoaki Yasui , Yuya Konno , Kyoichi Ikeno
发明人： Masaki Kawano , Toyoaki Yasui , Yuya Konno , Kyoichi Ikeno
IPC分类号： B32B9/00
CPC分类号： C23C14/06 , C23C28/044 , C23C30/00 , Y10T428/24975 , Y10T428/265
摘要： In a part for a rotary machine, a ceramic hard film is formed on a surface of a base material, the density of droplets which exist in a surface of the ceramic hard film is set to be within 1000 pieces/mm2, and the density of droplets whose mean particle diameter is 1 μm or less is set to be within 550 pieces/mm2. A method for manufacturing the part of a rotary machine is a method for forming the ceramic hard film by at least an ion plating method or a sputtering method.
摘要翻译：在旋转机械的一部分中，在基材的表面上形成陶瓷硬膜，将陶瓷硬质膜的表面存在的液滴的密度设定在1000个/ mm 2以下，密度平均粒径为1μm以下的液滴设定在550个/ mm 2以下。用于制造旋转机器的一部分的方法是通过至少离子镀法或溅射法形成陶瓷硬质膜的方法。

8. 发明授权

US07226658B2 Electrical sheet having insulating coating and insulating coating 有权
标题翻译：电工板具有绝缘涂层和绝缘涂层
公开(公告)号：US07226658B2
公开(公告)日：2007-06-05
申请号：US10297656
申请日：2002-04-10
申请人： Kazumichi Sashi , Yuka Komori , Masaki Kawano , Atsuhito Honda
发明人： Kazumichi Sashi , Yuka Komori , Masaki Kawano , Atsuhito Honda
IPC分类号： B32B5/14 , B32B15/08 , B32B15/18 , B32B27/18
CPC分类号： H01F1/14783 , B05D5/083 , C21D8/1283 , C22C38/02 , H01F1/14791 , Y10S428/90 , Y10T428/265 , Y10T428/31511 , Y10T428/31533 , Y10T428/3154 , Y10T428/31544 , Y10T428/31678 , Y10T428/31692 , Y10T428/31721 , Y10T428/31725 , Y10T428/31935
摘要： A magnetic steel sheet with an insulating coating having a good punchability, high sliding performance, excellent handleability in processing, and good uniformity and adhesiveness is achieved by forming a chromium-free insulating coating containing 20 parts by mass or more and 90 parts by mass or less of fluorocarbon resin as a top layer coating of the magnetic steel sheet, and preferably making the kinetic friction coefficient of a surface of the insulating coating 0.3 or less.
摘要翻译：通过形成含有20质量份以上且90质量份以下的无铬绝缘涂层，可以实现具有良好冲切性，高滑动性，加工性优异，均匀性和粘合性良好的绝缘性涂层的电磁钢板，较少的氟碳树脂作为电磁钢板的顶层涂层，并且优选使绝缘涂层的表面的动摩擦系数为0.3以下。

9. 发明申请

US20050064107A1 Method for producing coated steel sheet 有权
标题翻译：涂层钢板的制造方法
公开(公告)号：US20050064107A1
公开(公告)日：2005-03-24
申请号：US10502670
申请日：2003-01-24
申请人： Yuka Komori , Masaki Kawano , Kazumichi Sashi , Akio Fujita
发明人： Yuka Komori , Masaki Kawano , Kazumichi Sashi , Akio Fujita
IPC分类号： B05D3/02 , B05D7/14 , C21D8/02 , C21D8/04 , C21D8/12 , C23C22/74 , H01F1/147 , H01F1/18
CPC分类号： C23C22/74 , B05D3/0209 , B05D7/14 , B05D2202/10 , C21D8/0284 , C21D8/0484 , C21D8/1233 , C21D8/1283 , H01F1/14725 , H01F1/18
摘要： In a process for manufacturing a coated steel sheet such as a coated electromagnetic steel sheet using a water-based coating liquid containing an organic resin, to perform steps subsequent to an annealing step continuously at high speed without causing appearance defects such as coating unevenness; to provide an electromagnetic steel sheet having an insulating film thereon, in which properties of the film are satisfactory, superior weldability and punchability can be obtained without deteriorating the space factor, and the satisfactory film properties can be maintained even if the electromagnetic steel sheet having the insulating film thereon is temper-rolled. A coating liquid is applied onto an untreated steel sheet. The applied liquid is heated on the side close to the steel sheet in such a manner that the time elapsed until the steel sheet temperature is increased to 100° C. after the application is completed is 10 seconds or less, thereby drying the coating liquid. The steel sheet temperature is further increased to a predetermined temperature, thereby forming a coating film. When insulating films for electromagnetic steel sheets are formed, the coating liquid preferably further contains a water based inorganic component.
摘要翻译：在使用含有有机树脂的水性涂布液的涂布电磁钢板的涂布钢板的制造方法中，高速连续地进行退火工序后的工序，不会引起涂布不均匀等的外观缺陷; 为了提供一种其上具有绝缘膜的电磁钢板，其中膜的性能令人满意，可以获得优异的焊接性和冲压性，而不会使空间因素变差，并且即使具有对其上的绝缘膜进行回火。将涂布液施加到未处理的钢板上。所施加的液体在靠近钢板的一侧被加热，使得在施加完成之后直到钢板温度升高到100℃的时间为10秒以下，从而使涂布液干燥。钢板温度进一步提高到预定温度，从而形成涂膜。当形成用于电磁钢板的绝缘膜时，涂布液优选还含有水基无机组分。

10. 发明授权

US06531001B2 Non-oriented magnetic steel sheet having low iron loss and high magnetic flux density and manufacturing method therefor 有权
标题翻译：铁损低，磁通密度高的非取向磁钢板及其制造方法
公开(公告)号：US06531001B2
公开(公告)日：2003-03-11
申请号：US10140207
申请日：2002-05-08
申请人： Yasuyuki Hayakawa , Mitsumasa Kurosawa , Masaki Kawano , Michiro Komatsubara , Yuka Komori , Kazuaki Tamura
发明人： Yasuyuki Hayakawa , Mitsumasa Kurosawa , Masaki Kawano , Michiro Komatsubara , Yuka Komori , Kazuaki Tamura
IPC分类号： H01F1147
CPC分类号： C21D8/1261 , C21D8/1233 , H01F1/14775
摘要： Non-oriented magnetic steel sheets, which are mainly used as materials for iron cores for use in electric apparatuses, have a low iron loss and a high magnetic flux density at the same time. The non-oriented magnetic steel sheet comprises from about 1.5 to about 8.0 weight % Si, from about 0.005 to about 2.50 weight % Mn, and not more than about 50 ppm each of C, S, N, O, and B, in which a crystal orientation parameter is 0.200 or less. In addition, the average crystal grain diameter is preferably from about 50 to about 500 &mgr;m, and an areal ratio of crystal grains on a surface of the steel sheet is preferably 20% and less, in which crystal plane orientations of the crystal grains are within 15° from the axis. In addition, the non-oriented magnetic steel sheet preferably contains small amounts of elements such as Al, Sb, Ni, Sn, Cu, P, and Cr. The manufacturing method for the non-oriented magnetic steel is also described.
摘要翻译：主要用作电气设备用铁芯材料的非取向磁钢板同时具有低铁损和高磁通密度。未取向的磁性钢板包含约1.5至约8.0重量％的Si，约0.005至约2.50重量％的Mn，以及不超过约50ppm的C，S，N，O和B，其中晶体取向参数为0.200以下。此外，平均晶粒直径优选为约50〜约500μm，并且钢板表面的晶粒的面积率优选为20％以下，其中晶粒的晶面取向在其内距离<111>轴为15°。此外，无取向电磁钢板优选含有少量的元素，例如Al，Sb，Ni，Sn，Cu，P和Cr。还描述了用于非取向磁钢的制造方法。

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