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1. 发明授权

US06329555B1 Preparation of substituted butenes 失效
标题翻译：取代丁烯的制备
公开(公告)号：US06329555B1
公开(公告)日：2001-12-11
申请号：US09432202
申请日：1999-11-02
申请人： Maik Aron , Ralf Böhling , Peter Zehner
发明人： Maik Aron , Ralf Böhling , Peter Zehner
IPC分类号： C07C4106
CPC分类号： C07C41/06 , C07C45/513 , C07C47/02 , C07C43/046
摘要： Described is a process for preparing substituted butenes of the formula I and/or II, where the radical R is unsubstituted or mono- or di-C1-C10-alkoxy-substituted or mono- or dihydroxy-substituted C2-C20-alkyl or alkenyl or is C6-C10-aryl, C7-C11-aralkyl or methyl by reacting 1,3-butadiene with an alcohol of the formula ROH in which R is as defined in the presence of an acidic particulate catalyst insoluble in the reaction medium, which involves contacting the butadiene, the alcohol and the catalyst in a fluidized bed reactor which is flow-approached from below and is operated at above the loosening point.
摘要翻译：描述了制备式I和/或II的取代丁烯的方法，其中基团R是未取代的或单或二-C 1 -C 10 - 烷氧基取代的或单或二羟基取代的C 2 -C 20 - 烷基或烯基或者是C 13 -C 10 - 芳基，C 7 -C 11 - 芳烷基或甲基，通过使1,3-丁二烯与式ROH的醇反应，其中R在不溶于反应介质的酸性颗粒催化剂存在下如上所定义，其中R 包括在流化床反应器中使丁二烯，醇和催化剂接触，流化床反应器从下方流动接近并在松动点之上操作。

2. 发明授权

US5919987A Preparation of alcohols and/or aldehydes 失效
标题翻译：醇和/或醛的制备
公开(公告)号：US5919987A
公开(公告)日：1999-07-06
申请号：US716216
申请日：1996-09-13
申请人： Heinz-Josef Kneuper , Maik Aron , Frank-Michael Korgitzsch , Michael Nilles , Wolfgang Harder , Michael Roper , Rocco Paciello
发明人： Heinz-Josef Kneuper , Maik Aron , Frank-Michael Korgitzsch , Michael Nilles , Wolfgang Harder , Michael Roper , Rocco Paciello
IPC分类号： B01J23/46 , B01J31/40 , C07B61/00 , C07C27/22 , C07C29/141 , C07C29/16 , C07C31/02 , C07C45/50 , C07C45/80 , C07C47/02 , C07C51/235 , C07C209/00 , C07C45/00
CPC分类号： B01J31/20 , B01J31/4046 , C07C209/00 , C07C29/141 , C07C29/16 , C07C45/50 , C07C45/80 , C07C51/235 , B01J2231/321 , B01J23/464 , B01J2531/822 , B01J31/181 , B01J31/1815 , B01J31/1825 , B01J31/183 , Y02P20/584
摘要： An industrial preparation of aldehydes and/or alcohols from olefins of more than 3 carbon atoms by a catalytic hydroformylation of the olefin reactant at a pressure of from 50 to 1000 bar and a temperature of from 50 to 180.degree. C. in the presence of an uncomplexed rhodium catalyst homogeneously dissolved in the reaction medium. The catalytic activity of the rhodium is maintained, first by extracting it from the initially discharged reaction mixture by means of an aqueous solution of a nitrogen-containing complexing agent such as sulfonated or carboxylated pyridines, quinolines or the like. In a recycle of the complexed rhodium to be reused in the hydroformylation reaction, the aqueous rhodium-containing extract is fed to a precarbonylation stage where it subjected to a required precarbonylation in the presence of an essentially water-insoluble organic liquid and in the presence of carbon monoxide, synthesis gas or another gas mixture containing carbon monoxide at from 50 to 1000 bar and from 50 to 180.degree. C. The mixture discharged from this precarbonylation stage is then separated into an organic phase containing the main part of the rhodium and an aqueous phase containing the complexing agent. The resulting rhodium-containing organic phase with the regenerated catalyst is then fed into the hydroformylation stage to complete its recycle.
摘要翻译： PCT No.PCT / EP95 / 00825 Sec。 371日期1996年9月13日 102（e）日期1996年9月13日PCT 1995年3月6日PCT公布。 WO95 / 25080 PCT公开日期1995年9月21日通过在50至1000巴的压力和50至180℃的温度下通过烯烃反应物的催化加氢甲酰化来工业制备大于3个碳原子的烯烃的醛和/或醇。在均匀溶解在反应介质中的未络合的铑催化剂存在下进行。保持铑的催化活性，首先通过含氮络合剂如磺化或羧化吡啶，喹啉等的水溶液从最初排出的反应混合物中提取铑的催化活性。在加氢甲酰化反应中重复使用的复合铑的再循环中，含水铑萃取物进料到预羰化阶段，其中在基本上不溶于水的有机液体存在下进行所需的预羰基化，一氧化碳，合成气或含有一氧化碳的另一种气体混合物，从50至1000巴和50至180℃。然后将从该预羰化阶段排出的混合物分离成含有主要部分铑的有机相，相含有络合剂。然后将所得到的含再生催化剂的含铑有机相进料到加氢甲酰化阶段以完成其再循环。

3. 发明授权

US5985100A Process for separating butanol and dibutyl ether by means of dual-pressure distillation 失效
标题翻译：通过双压蒸馏分离丁醇和二丁醚的方法
公开(公告)号：US5985100A
公开(公告)日：1999-11-16
申请号：US11700
申请日：1998-02-17
申请人： Maik Aron , Harald Rust
发明人： Maik Aron , Harald Rust
IPC分类号： C07C27/28 , C07C29/80 , C07C31/12 , C07C41/42 , C07C43/04 , B01D3/00
CPC分类号： C07C41/42 , C07C29/80 , Y10S203/20
摘要： Butanol and dibutyl ether are separated from a mixture containing water, dibutyl ether and n-butanol, 2-butanol and/or isobutanol by a process in whicha) the mixture is introduced into a first distillation column, essentially butanol is separated off at the bottom of this distillation column and the mixture taken off at the top of the distillation columnb) is introduced into a second distillation column and essentially dibutyl ether is separated off at the bottom of this second distillation column and the mixture formed at the top of the second distillation column is removed,c) the second distillation column being operated at a higher pressure than the first distillation column and at least one of the two mixtures taken off via the top of the distillation columns being subjected to phase separation, only the organic phase separated off being fed to the second distillation column in the case of phase separation downstream of the first distillation column, and separation into an aqueous and an organic phase also being effected in the case of phase separation downstream of the second distillation column, a part stream being recycled from the top or rectification section of the second distillation column to the first distillation column.
摘要翻译： PCT No.PCT / EP96 / 03762 Sec。 371日期1998年2月17日 102（e）1998年2月17日PCT 1995年8月26日PCT PCT。公开号WO97 / 08120 日期1997年3月6日丁醇和二丁醚由含有水，二丁醚和正丁醇，2-丁醇和/或异丁醇的混合物分离，其中a）将混合物引入第一蒸馏塔，基本上为丁醇在该蒸馏塔的底部分离，将在蒸馏塔b）顶部排出的混合物引入第二蒸馏塔中，并且在该第二蒸馏塔的底部基本上分离出二丁基醚，并形成混合物在第二蒸馏塔的顶部被除去，c）第二蒸馏塔在比第一蒸馏塔高的压力下操作，并且通过蒸馏塔的顶部排出的两种混合物中的至少一种经受相分离在第一蒸馏塔下游相分离的情况下，仅分离出分离的有机相进入第二蒸馏塔，分离在第二蒸馏塔下游的相分离的情况下也进行水和有机相的离子化，将一部分物流从第二蒸馏塔的顶部或精馏段再循环到第一蒸馏塔。

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