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1. 发明授权

US4209499A Crystalline zeolite ZSM-43 synthesis thereof 失效
标题翻译：结晶沸石ZSM-43的合成
公开(公告)号：US4209499A
公开(公告)日：1980-06-24
申请号：US844168
申请日：1977-10-21
申请人： Mae K. Rubin , Edward J. Rosinski , Charles J. Plank
发明人： Mae K. Rubin , Edward J. Rosinski , Charles J. Plank
IPC分类号： C08F4/00 , B01J29/00 , B01J29/70 , C01B39/04 , C01B39/48 , C07B61/00 , C07C1/00 , C07C1/20 , C07C2/00 , C07C2/12 , C07C4/06 , C07C7/167 , C07C9/14 , C07C11/02 , C07C67/00 , C01B33/28
CPC分类号： C07C1/20 , B01J29/70 , C01B39/48 , C07C2/00 , C07C2529/70 , Y02P30/42
摘要： A new crystalline zeolite, designated ZSM-43, a method of making same and the use thereof in catalytic conversion of organic compounds is the subject of this application. The new zeolite has a composition, in the anhydrous state, expressed in terms of mole ratios of oxides, as follows:(0.6 to 2.1)M.sub.2/n O : Al.sub.2 O.sub.3 : xSiO.sub.2wherein M is at least one cation having a valence n and x is at least 5, and is characterized by a specified X-ray powder diffraction pattern.
摘要翻译：一种名为ZSM-43的新型结晶沸石，其制备方法及其在有机化合物的催化转化中的应用是本申请的主题。新沸石具有无水状态的氧化物摩尔比表示的组成：（0.6-2.1）M2 / nO：Al2O3：xSiO2其中M是至少一个价数为n的阳离子，x是至少5个，其特征在于指定的X射线粉末衍射图。

2. 发明授权

US4199556A Method for producing zeolites 失效
标题翻译：生产沸石的方法
公开(公告)号：US4199556A
公开(公告)日：1980-04-22
申请号：US23856
申请日：1979-03-26
申请人： Charles J. Plank , Edward J. Rosinski , Mae K. Rubin
发明人： Charles J. Plank , Edward J. Rosinski , Mae K. Rubin
IPC分类号： B01J29/40 , C01B39/36 , C01B39/38 , C01B33/28
CPC分类号： B01J29/40 , C01B39/365 , C01B39/38 , Y10S423/22 , Y10S423/29
摘要： As synthesized by previous methods, ZSM-5 or ZSM-11 zeolites are crystallized in the presence of substantial amounts of a nitrogen-containing compound. When synthesized in this way, they contain an organic ammonium cation as well as a metal cation such as sodium. To obtain a more active form, the sodium ion must be exchanged out. Such exchange, especially with ZSM-5 and ZSM-11, is difficult unless there is calcination of the zeolite to remove the obstructing organo compounds. By making these zeolites in the presence of (1) seeds of the desired zeolite, (2) mixtures of them with ammonium hydroxide and/or alcohol, (3) the alcohol per se or (4) mixtures of the alcohol with ammonium hydroxide, a product substantially deficient in organic ammonium cation is obtained. These products can be exchanged directly without any calcination.
摘要翻译：通过以前的方法合成，ZSM-5或ZSM-11沸石在大量含氮化合物的存在下结晶。当以这种方式合成时，它们含有有机铵阳离子以及诸如钠的金属阳离子。要获得更活跃的形式，必须将钠离子交换出来。这种交换，尤其是与ZSM-5和ZSM-11的交换是困难的，除非有煅烧沸石去除阻碍的有机化合物。在（1）所需沸石的种子存在下制备这些沸石，（2）它们与氢氧化铵和/或醇的混合物，（3）醇本身或（4）醇与氢氧化铵的混合物，获得了有机铵阳离子基本上不足的产物。这些产品可直接进行交换而无需任何煅烧。

3. 发明授权

US4081490A Hydrocarbon conversion over ZSM-35 失效
标题翻译： ZSM-35碳氢转化
公开(公告)号：US4081490A
公开(公告)日：1978-03-28
申请号：US739413
申请日：1976-11-08
申请人： Charles J. Plank , Edward J. Rosinski , Mae K. Rubin
发明人： Charles J. Plank , Edward J. Rosinski , Mae K. Rubin
IPC分类号： B01J29/65 , C01B39/44 , C07C5/41 , C10G11/04 , C07C15/02 , B01J8/24
CPC分类号： C07C5/41 , B01J29/65 , C01B39/445
摘要： Catalytic conversion of hydrocarbon compounds in the presence of crystalline zeolite ZSM-35, or a thermal decomposition product thereof, is provided. Zeolite ZSM-35 has a composition, in the anhydrous state, expressed in terms of mole ratios of oxides as follows:(0.3-2.5)R.sub.2 O:(0-0.8)M.sub.2 O : Al.sub.2 O.sub.3 : (x) SiO.sub.2wherein R is an organic nitrogen-containing cation derived from ethylenediamine or pyrrolidine, M is an alkali metal cation and x is greater than 8, and is characterized by a specified X-ray powder diffraction pattern.
摘要翻译：提供了在结晶沸石ZSM-35或其热分解产物存在下烃化合物的催化转化。沸石ZSM-35具有无水状态的组成，以氧化物的摩尔比表示如下：

4. 发明授权

US4076842A Crystalline zeolite ZSM-23 and synthesis thereof 失效
标题翻译：结晶沸石ZSM-23及其合成
公开(公告)号：US4076842A
公开(公告)日：1978-02-28
申请号：US739414
申请日：1976-11-08
申请人： Charles J. Plank , Edward J. Rosinski , Mae K. Rubin
发明人： Charles J. Plank , Edward J. Rosinski , Mae K. Rubin
IPC分类号： C10G57/02 , B01J29/00 , B01J29/70 , C01B33/40 , C01B39/04 , C01B39/48 , C07B61/00 , C07C1/00 , C07C1/20 , C07C2/00 , C07C2/12 , C07C2/42 , C07C4/06 , C07C67/00 , C10G50/00 , C01B33/28
CPC分类号： C07C2/12 , B01J29/70 , C01B39/48 , C07C1/20 , C07C2/00 , B01J2229/36 , C07C2529/70 , Y10S423/36
摘要： A new crystalline zeolite, designated ZSM-23, a method of making same and the use thereof in catalytic conversion of organic compounds is the subject of this application. The new zeolite has a composition, in the anhydrous state, expressed in terms of mole ratios of oxides, as follows;(0.58-3.4)M.sub.2/n O : Al.sub.2 O.sub.3 : (40-250)SiO.sub.2wherein M is at least one cation having a valence n, and is characterized by a specified X-ray powder diffraction pattern.
摘要翻译：一种名为ZSM-23的新型结晶沸石，其制备方法及其在有机化合物催化转化中的应用是本申请的主题。新沸石具有以无水状态以氧化物的摩尔比表示的组成，如下所述：（0.58-3.4）M2 / nO：Al2O3：（40-250）SiO2，其中M是至少一种价数为n的阳离子，其特征在于规定的X射线粉末衍射图。

5. 发明授权

US4175114A Method for producing zeolites 失效
公开(公告)号：US4175114A
公开(公告)日：1979-11-20
申请号：US841622
申请日：1977-10-13
申请人： Charles J. Plank , Edward J. Rosinski , Mae K. Rubin
发明人： Charles J. Plank , Edward J. Rosinski , Mae K. Rubin
IPC分类号： B01J29/40 , C01B39/36 , C01B39/38 , C01B33/28
CPC分类号： C01B39/38 , B01J29/40 , C01B39/365 , Y10S423/21 , Y10S423/29
摘要： As synthesized by previous methods, ZSM-5 or ZSM-11 zeolites are crystallized in the presence of substantial amounts of a nitrogen-containing compound. When synthesized in this way, they contain an organic ammonium cation as well as a metal cation such as sodium. To obtain a more active form, the sodium ion must be exchanged out. Such exchange, especially with ZSM-5 and ZSM-11, is difficult unless there is calcination of the zeolite to remove the obstructing organo compounds. By making these zeolites in the presence of (1) seeds of the desired zeolite, (2) mixtures of them with ammonium hydroxide and/or alcohol, (3) the alcohol per se or (4) mixtures of the alcohol with ammonium hydroxide, a product substantially deficient in organic ammonium cation is obtained. These products can be exchanged directly without any calcination.

6. 发明授权

US4116813A Hydrocarbon conversion with crystalline zeolite ZSM-34 失效
标题翻译：使用结晶沸石ZSM-34进行烃转化
公开(公告)号：US4116813A
公开(公告)日：1978-09-26
申请号：US852167
申请日：1977-11-16
申请人： Mae K. Rubin , Edward J. Rosinski , Charles J. Plank
发明人： Mae K. Rubin , Edward J. Rosinski , Charles J. Plank
IPC分类号： C07C43/04 , B01J29/00 , B01J29/50 , B01J29/70 , C01B39/30 , C07B61/00 , C07C1/00 , C07C1/20 , C07C2/12 , C07C4/06 , C07C5/27 , C07C6/12 , C07C9/00 , C07C11/02 , C07C15/02 , C07C41/00 , C07C67/00 , C10G11/05 , C10G11/04 , B01J8/24
CPC分类号： C10G11/05 , B01J29/50 , B01J29/70 , B01J29/7049 , C01B39/305 , C07C1/20 , C07C2/12 , C07C4/06 , B01J2229/26 , B01J2229/36 , B01J2229/42 , C07C2529/06
摘要： A crystalline zeolite, designated ZSM-34, having the composition as synthesized and in anhydrous form, expressed as mole ratios of oxides as follows:(0.5-1.3)R.sub.2 O : (0-0.15)Na.sub.2 0 : (0.10-0.50)K.sub.2 O : Al.sub.2 O.sub.3 : XSiO.sub.2where R is the organic nitrogen-containing cation, [(CH.sub.3).sub.3 NCH.sub.2 CH.sub.2 OH], derived from choline, and X is 8 to 50, said zeolite having an X-ray diffraction pattern, identifying it as a member of the offretite-erionite family and the ability, after calcination at 1000.degree. F for at least a period of time to remove the organic cation, to sorb at least 9.5 weight percent of n-hexane at ambient temperature and a n-hexane pressure of 20 mm. Organic compound conversion is carried out in the presence of a catalytically-active form of said zeolite.
摘要翻译：称为ZSM-34的结晶沸石，具有合成和无水形式的组成，表示为氧化物的摩尔比如下：

7. 发明授权

US4105541A Hydrocarbon conversion over ZSM-38 失效
标题翻译： ZSM-38油气转换
公开(公告)号：US4105541A
公开(公告)日：1978-08-08
申请号：US850876
申请日：1977-11-14
申请人： Charles J. Plank , Mae K. Rubin , Edward J. Rosinski
发明人： Charles J. Plank , Mae K. Rubin , Edward J. Rosinski
IPC分类号： B01J29/65 , B01J29/68 , B01J8/24 , C07C15/02
CPC分类号： B01J29/655 , B01J29/65 , B01J29/68
摘要： Catalytic conversion of hydrocarbon compounds in the presence of crystalline zeolite ZSM-38, or a thermal decomposition product thereof, is provided. Zeolite ZSM-38 has a composition, in the anhydrous state, expressed in terms of mole ratios of oxides as follows:(0.3-2.5)R.sub.2 O:(0-0.8)M.sub.2 O:Al.sub.2 O.sub.3 :(x)SiO.sub.2wherein R is an organic cation, especially an organic nitrogen-containing cation, M is an alkali metal cation and x is greater than 8, and is characterized by a specified X-ray powder diffraction pattern.

8. 发明授权

US4021447A Synthesis of zeolite ZSM-4 失效
标题翻译：沸石ZSM-4的合成
公开(公告)号：US4021447A
公开(公告)日：1977-05-03
申请号：US572979
申请日：1975-04-30
申请人： Mae K. Rubin , Charles J. Plank , Edward J. Rosinski
发明人： Mae K. Rubin , Charles J. Plank , Edward J. Rosinski
IPC分类号： B01J29/70 , C01B39/34 , C01B33/28 , C07D295/00
CPC分类号： C01B39/34 , B01J29/7011 , Y10S423/26
摘要： As synthesized by previous methods, ZSM-4 zeolites are crystallized in the presence of substantial amounts of a tetramethylammonium hydroxide or halide. When synthesized in this way, they contain the tetramethylammonium cation as well as a metal cation such as sodium. To obtain a more catalytically active form, the sodium ion must be exchanged to very low levels. Catalysts prepared in this manner have been found to be quite low in stability. By synthesizing these zeolites in the presence of pyrrolidine or choline salts, ZSM-4 having a different organic nitrogen containing cation but the same crystal structure as previously prepared ZSM-4 is obtained. Catalysts made therefrom are, surprisingly, much more stable than those prepared from ZSM-4 made by previous methods.
摘要翻译：通过以前的方法合成，ZSM-4沸石在大量的四甲基氢氧化铵或卤化物存在下结晶。当以这种方式合成时，它们含有四甲基铵阳离子以及诸如钠的金属阳离子。为了获得更具催化活性的形式，钠离子必须交换到非常低的水平。发现以这种方式制备的催化剂的稳定性相当低。通过在吡咯烷或胆碱盐的存在下合成这些沸石，得到具有不同有机含氮阳离子但具有与先前制备的ZSM-4相同的晶体结构的ZSM-4。令人惊奇地，由其制备的催化剂比由先前方法制备的ZSM-4制备的催化剂更加稳定。

9. 发明授权

US4016245A Crystalline zeolite and method of preparing same 失效
标题翻译：结晶沸石及其制备方法
公开(公告)号：US4016245A
公开(公告)日：1977-04-05
申请号：US528061
申请日：1974-11-29
申请人： Charles J. Plank , Edward J. Rosinski , Mae K. Rubin
发明人： Charles J. Plank , Edward J. Rosinski , Mae K. Rubin
IPC分类号： B01J29/65 , C01B39/44 , C01B33/28 , C07F7/02
CPC分类号： C01B39/445 , B01J29/65 , C07C2529/65 , Y10S423/23
摘要： A new crystalline zeolite, designated ZSM-35, a method of making same and the use thereof in catalytic conversion of hydrocarbons is the subject of this application. The new zeolite has a composition, in the anhydrous state, expressed in terms of mole ratios of oxides as follows:(0.3-2.5)R.sub.2 O:(0-0.8)M.sub.2 O:Al.sub.2 O.sub.3 :>8 SiO.sub.2wherein R is an organic nitrogen-containing cation and M is an alkali metal cation, and is characterized by a specified X-ray powder diffraction pattern.
摘要翻译：命名为ZSM-35的新型结晶沸石，其制备方法及其在烃的催化转化中的应用是本申请的主题。新沸石具有无水状态的组成，以氧化物的摩尔比表示如下：

10. 发明授权

US5102644A Method for producing zeolites 失效
标题翻译：生产沸石的方法
公开(公告)号：US5102644A
公开(公告)日：1992-04-07
申请号：US701314
申请日：1985-02-13
申请人： Charles J. Plank , Edward J. Rosinski , Mae K. Rubin
发明人： Charles J. Plank , Edward J. Rosinski , Mae K. Rubin
IPC分类号： B01J29/40 , C01B39/36 , C01B39/38
CPC分类号： C01B39/38 , B01J29/40 , C01B33/2876 , C01B39/365 , Y10S423/22 , Y10S423/29
摘要： A method of producing zeolites particularly ZSM-5 and ZSM-11 by strictly controlling the composition of the forming bath such that no organic is required. In a preferred embodiment the forming bath can contain seeds, lower aliphatic alcohols and/or ammonium hydroxide. The as-crystallized product has no organic in its pore structures and has a relatively low silica to alumina ratio.
摘要翻译：通过严格控制成型浴的组成使得不需要有机物来生产特别是ZSM-5和ZSM-11的沸石的方法。在优选的实施方案中，成型浴可以含有种子，低级脂族醇和/或氢氧化铵。结晶产物在其孔结构中没有有机物，并且具有相对较低的二氧化硅与氧化铝的比例。

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