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1. 发明授权

US3697656A Insecticidal method using 3-methylenedioxy-phenyl substituted rhodanines 失效
标题翻译：使用3-亚甲基二苯基取代的枸橼烷的杀虫剂方法
公开(公告)号：US3697656A
公开(公告)日：1972-10-10
申请号：US3697656D
申请日：1969-10-22
申请人： MONSANTO CHEMICALS
发明人： BROWN JOSEPH PATRICK
IPC分类号： A01N43/78 , C07D417/04 , A01N9/12
CPC分类号： C07D417/04 , A01N43/78
摘要： An insecticidal method comprising contacting insects with an insecticidally effective amount of a compound having the formula

WHERE R'' is alkyl of not more than eight carbon atoms and R2 is selected from the group consisting of hydrogen and alkyl of not more than eight carbon atoms.

2. 发明授权

US3639305A Flame-retardant resin compositions and method of making same 失效
标题翻译：阻燃树脂组合物及其制备方法
公开(公告)号：US3639305A
公开(公告)日：1972-02-01
申请号：US3639305D
申请日：1968-07-18
申请人： MONSANTO CHEMICALS
发明人： FOSTER WILLIAM REES , BROWN JOSEPH PATRICK
IPC分类号： C08J9/00 , C08K5/095 , C08J1/18
CPC分类号： C08K5/095 , C08J9/0023 , C08K5/09 , C08K5/12 , Y10S521/907 , C08L23/02 , C08L25/06
摘要： AR-HALO AR-ALKENYLOXY AROMATIC ACIDS AND DERIVATIVES THEREOF, SUCH AS THE ESTER, SALT HALIDE, AND ANHYDRIDE DERIVATIVES; PROCESSES FOR PREPARING SUCH COMPOUNDS BY REACTING AN ALKENYL HALIDE WITH AN APPROPRIATE AR-HALOAR-HYDROXY AROMATIC ACID OR DERIVATIVE THEREOF; AND THE USE OF SUCH COMPOUNDS AS FLAME-RETARDANT AGENTS FOR NORMALLY FLAMMABLE SYNTHETIC RESINS, ESPECIALLY FOAMED SYNTHETIC RESINS.

3. 发明授权

US3639302A Flame-retardant resin compositions 失效
标题翻译：阻燃树脂组合物
公开(公告)号：US3639302A
公开(公告)日：1972-02-01
申请号：US3639302D
申请日：1968-05-16
申请人： MONSANTO CHEMICALS
发明人： BROWN JOSEPH PATRICK , FOSTER WILLIAM REES
IPC分类号： C08K5/06 , C08J1/18
CPC分类号： C08K5/06 , Y10S521/907 , C08L25/06
摘要： BIS(AR-HALO-AR-ALKENYLOXPHENYL) COMPOUNDS WHEREIN THE AROMATIC RINGS ARE LINKED BY A COVALENT BOND, A SULFUR OR OXYGEN ATOM, A SECONDARY OR TERTIARY AMINO GROUP, OR A DIVALENT ALIPHATIC GROUP; PROCESSES FOR PREPARING SUCH COMPOUNDS BY REACTING AN ALKENYL HALIDE WITH AN APPROPRIATE BIS(AR-HALO-AR-HYDROXPHENYL) COMPOUND OR WITH A SALT THEREOF; AND THE USE OF SUCH COMPOUNDS AS FLAMERETARDANT AGENTS FOR NORMALLY FLAMMABLE SYNTHETIC RESINS, ESPECIALLY FORMED SYNTHETIC RESINS.

4. 发明授权

US3576792A Dithiolethionesulfenamides as vulcanization accelerators 失效
标题翻译：作为增压加速器的脱硫烷基化反应
公开(公告)号：US3576792A
公开(公告)日：1971-04-27
申请号：US3576792D
申请日：1968-09-25
申请人： MONSANTO CHEMICALS
发明人： BROWN JOSEPH PATRICK
IPC分类号： C07D339/04 , C08K5/00 , C08F27/06
CPC分类号： C07D339/04 , C08K5/0025 , C08L21/00
摘要： NEW COMPOUNDS OF THE FORMULA

3-(S=),4-R3,5-(R1-N(-R2)-)-3H-1,2-DITHIOLE

WHERE R1 REPRESENTS A HYDROGEN ATOM OR AN ALIPHTIC GROUP, R2 REPRESENTS AN ALIPHATIC GROUP, OR WHERE R1 AND R2 TAKEN TOGETHER WITH THE NITROGEN ATOM REPRESENT A SATURATED RING, AND R3 REPRESENTS AN ALIPHATIC OR AROMATIC GROUP ARE DESCRIBED WHICH ARE USEFUL FOR ACCELERATING THE VULCANIZATION OF RUBBER.

5. 发明授权

US3539578A Herbicidal 1,2-dihydroquinolines and 1,2,3,4-tetrahydroquinolines 失效
标题翻译：除草剂1,2-二氢喹啉和1,2,3,4-四氢喹啉
公开(公告)号：US3539578A
公开(公告)日：1970-11-10
申请号：US3539578D
申请日：1968-03-27
申请人： MONSANTO CHEMICALS
发明人： BROWN JOSEPH PATRICK
IPC分类号： C07D215/08 , C07D215/18 , C07D215/20 , C07D215/26 , C07D33/46
CPC分类号： C07D215/26 , C07D215/08 , C07D215/18 , C07D215/20

6. 发明专利

GB1206171A ALKENYLOXY SUBSTITUTED HALO-AROMATIC COMPOUNDS AND THEIR USE AS FLAME RETARDANTS IN RESIN COMPOSITIONS 未知
公开(公告)号：GB1206171A
公开(公告)日：1970-09-23
申请号：GB2699667
申请日：1967-06-12
申请人： MONSANTO CHEMICALS
发明人： FOSTER WILLIAM REES , BROWN JOSEPH PATRICK
IPC分类号： C08F12/04 , C08J9/36 , C08K5/06
摘要： 1,206,171. Flame-retardant coatings. MONSANTO CHEMICALS Ltd. 15 May, 1968 [12 June, 1967], No. 26996/67. Heading B2E. [Also in Divisions C2 and C3] Foamed resin materials are rendered flameretardant by coating with a composition containing a compound having two aromatic rings linked by an aliphatic residue, each ring being substituted by a halogen atom and an alkenyloxy group (see Division C2). In Example 4 a sheet of foamed polystyrene is sprayed with an aq. dispersion of 2, 2-bis (4-allyloxy-3, 5-dibromophenyl)-propane.

7. 发明专利

GB1188858A Sulphur-Containing Heterocyclic Compounds 未知
公开(公告)号：GB1188858A
公开(公告)日：1970-04-22
申请号：GB4377067
申请日：1967-09-26
申请人： MONSANTO CHEMICALS
发明人： BROWN JOSEPH PATRICK
IPC分类号： C07D339/04 , C08K5/00
摘要： 1,188,858. Sulphenamide derivatives. MONSANTO CHEMICALS Ltd. 3 Sept., 1968 [26 Sept., 1967], No. 43770/67. Heading C2C. [Also in Division C3] Novel compounds of the general formula where R 1 represents hydrogen or an aliphatic or cycloaliphatic group, R 2 represents an aliphatic or cyclo-aliphatic group or R 2 and R 1 together with the nitrogen atom form a saturated ring, and R 3 represents an aliphatic or aromatic group, are prepared by reacting an N-halo-amine of formula R 1 R 2 NX, where X is halogen, with a mercaptan of formula in the presence of an acid acceptor which is preferably the amine corresponding to the haloamine reactant. The compounds are accelerators for the vulcanization of rubbers.

8. 发明专利

GB1183645A Sulphur-Containing Heterocyclic Compounds 未知
公开(公告)号：GB1183645A
公开(公告)日：1970-03-11
申请号：GB5452067
申请日：1967-11-30
申请人： MONSANTO CHEMICALS
发明人： BROWN JOSEPH PATRICK
IPC分类号： C07D339/04
摘要： 1,183,645. Pesticides containing dithioles. MONSANTO CHEMICALS Ltd. 6 Nov., 1968 [30 Nov., 1967], No. 54520/67. Heading A5E. [Also in Divisions C2 and C3] Insecticidal and fungicidal compositions comprise dithioles of formula where R is an aliphatic or aromatic group and X is:- (a) -(A) n -COOR 1 , where A is alkylene, n is 0 or 1 and R 1 is alkyl; (b) where m is 1, 2 or 3, or (c) where X 1 is hydrogen or halogen, not more than 3 being halogen.

9. 发明专利

DE1217960B 未知
公开(公告)号：DE1217960B
公开(公告)日：1966-06-02
申请号：DEM0045033
申请日：1960-04-16
申请人： MONSANTO CHEMICALS
发明人： BROWN JOSEPH PATRICK

10. 发明专利

GB996706A Mycobacteriostatic biguanides and compositions containing them 未知
公开(公告)号：GB996706A
公开(公告)日：1965-06-30
申请号：GB4427861
申请日：1961-12-11
申请人： MONSANTO CHEMICALS
发明人： BROWN JOSEPH PATRICK
IPC分类号： C07C279/26
摘要： The invention comprises an aliphatic-oxyphenyl biguanide of the formula or a salt of such a biguanide where either (a) R is an aliphatic group having at least 2 carbon atoms and the aliphatic-oxyphenyl group contains a halogen atom, or (b) no such halogen atom is present and R if an n-alkyl group contains from 5 to 7 carbon atoms and if not an n-alkyl group is a hydrocarbon substituent containing from 5 to 9 carbon atoms, and where in each instance the phenyl nucleus can be further substituted. The aliphatic group may be an alkyl, alkenyl, cycloalkyl or aralkyl group. The phenyl nucleus may contain a halogen atom, a nitro group, an amino group, an aliphatic group or an aryl group. The biguanides may be made by reacting an appropriate aromatic amine with dicyandiamide. The reaction is normally carried out in the presence of acid, e.g. hydrochloric or sulphuric acid, so the initial product is a salt. The reaction may take place in an aqueous medium which can optionally contain a water-miscible solvent, for example a lower alcohol. The temperature is preferably in the range 50-150 DEG C. The free biguanide can be obtained by the action of an alkali, such as sodium or potassium hydroxide. Salts are formed by treating the free biguanide with an inorganic acid, e.g. hydrochloric or sulphuric, or an organic acid such as acetic, oxalic or picric acid, or with an alkyl halide to form a quaternary halide. Examples describe the preparation of 4-n-heptyloxy-; 4-n-amyloxy-; 4-n-hexyloxy; 4-(21-ethylhexoxy)-; 3 - chloro - 4 - n - heptoxy-; 3 - chloro - 4 - n - amyloxy -; 3 - chloro - 4 - ethoxy -; 2,5 - dichloro - 4 - ethoxy -; 2,5 - dibromo - 4 - ethoxy -; and 4 - (21 - chloro-ethoxy)-phenylbiguanides.ALSO:The invention comprises a mycobacteriostatic composition containing as an active ingredient a compound having linked to a nitrogen atom of a biguanide either a halogen-containing aliphatic-oxyphenyl group, the aliphatic-oxy group of which has at least 2 carbon atoms, or an aliphatic-oxyphenyl group in which the aliphatic substituent is a hydrocarbon substituent containing from 5 to 9 carbon atoms, or a salt of such a compound, in admixture with an inert diluent. The composition may be in the form of a suspension or emulsion, preferably aqueous, or a solid. Preferred ingredients are biguanides which have the general formula and their salts, where either (a) R is an aliphatic group having at least 2 carbon atoms and the aliphatic-oxyphenyl group contains a halogen atom or (b) no such halogen atom is present and R is a hydrocarbon substituent containing from 5 to 9 carbon atoms, and in either case the phenyl nucleus can be further substituted. The compositions can be used to protect a variety of materials including cloth, leather and agricultural products.

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