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1. 发明公开

EP0763002A4 PROCESS FOR PRODUCING GASOLINE HAVING LOWER BENZENE CONTENT AND DISTILLATION END POINT 失效
标题翻译：工艺生产燃料与NIEDRIGESM苯含量和DISTILLATIONSENDPUNKT
公开(公告)号：EP0763002A4
公开(公告)日：1998-07-08
申请号：EP94923171
申请日：1994-05-31
申请人： MOBIL OIL CORP
发明人： HARANDI MOHSEN N , OWEN HARTLEY , SCHIPPER PAUL H
IPC分类号： B01J29/06 , C07C2/66 , C10G35/06 , C10G35/095 , C10G45/64 , C10G59/02
CPC分类号： C10G35/095 , C10G45/64 , C10G59/02
摘要： A process is disclosed for upgrading reformate and/or light FCC gasoline by substantially reducing the amount of benzene in the gasoline product while simultaneously reducing the gasoline ASTM distillation End Point. The process comprises the fractionation in fractionator (20) of gasoline or reformate (10) to recover C7-C8 hydrocarbons (16), directly useful in gasoline without further conversion. A heavy bottom fraction comprising C9+ aromatic and non-aromatic hydrocarbons is recovered (14) and a C6 fraction rich in benzene is recovered (18). The total C6 fraction and a portion of the C9+ fraction are converted by alkylation, transalkylation and cracking in contact with acidic metallosilicate catalyst particles to gasoline boiling range materials rich in alkylaromatics in a reactor (30). Following debutanization or depentanization of the conversion product, the fraction containing unconverted benzene is recycled to the fractionator (20).

2. 发明专利

CA2037091A1 PRODUCTION OF ETHYL TERTIARY ALKYL ETHERS 未知
公开(公告)号：CA2037091A1
公开(公告)日：1991-08-29
申请号：CA2037091
申请日：1991-02-26
申请人： HARANDI MOHSEN N , MOBIL OIL CORP
发明人： HARANDI MOHSEN N , HARTLEY OWEN
IPC分类号： B01J31/08 , C07B61/00 , C07C41/06 , C07C43/04 , B01D3/40

3. 发明专利

AU6397490A INTEGRATED PROCESS FOR THE PRODUCTION OF DIISOPROPYL ETHER AND GASOLINE 未知
公开(公告)号：AU6397490A
公开(公告)日：1991-04-26
申请号：AU6397490
申请日：1990-10-10
申请人： MOBIL OIL CORP
发明人： OWEN HARTLEY , HARANDI MOHSEN N
IPC分类号： C07C41/05 , C07B61/00 , C07C1/20 , C07C2/00 , C07C41/06 , C07C41/09 , C07C43/04 , C10G1/00 , C10G3/00 , C10L1/02 , C07C41/01 , C07C2/12

4. 发明专利

CA2031212A1 INTEGRATED PROCESS FOR PRODUCTION OF GASOLINE AND ETHER FROM ALCOHOL WITH FEEDSTOCK EXTRACTION 未知
公开(公告)号：CA2031212A1
公开(公告)日：1990-10-25
申请号：CA2031212
申请日：1990-04-23
申请人： MOBIL OIL CORP
发明人： HARANDI MOHSEN N , OWEN HARTLEY
IPC分类号： C07B61/00 , C07C41/06 , C07C43/04 , C10G3/00 , C10G35/095 , C10L1/02 , C10L1/18
摘要： F-5262 INTEGRATED PROCESS FOR PRODUCTION OF GASOLINE AND ETHER FROM ALCOHOL WITH FEEDSTOCK EXTRACTION Alcohol feedstock containing water is extracted with olefinic liquid and reacted catalytically to produce tertiary ether. Unreacted alcohol and olefin vapor separated from etherification effluent is converted along with aqueous alcoholic raffinate in a zeolite catalysis step to produce gasoline and paraffinic intermediate. By dehydrogenating the C3-C5 paraffins, an olefinic liquid rich in isoalkenes is obtained for recycle to the extractor as solvent for alcohol feedstock.

5. 发明专利

CA2113810A1 HYDROCARBON UPGRADING PROCESS 未知
公开(公告)号：CA2113810A1
公开(公告)日：1993-02-16
申请号：CA2113810
申请日：1992-08-05
申请人： MOBIL OIL CORP
发明人： APELIAN MINAS R , COLLINS NICK A , DEGNAN THOMAS F JR , FLETCHER DAVID L , HARANDI MOHSEN N , HILBERT TIMOTHY L , KONDIS EDWARD F , MCGOVERN STEPHEN J , HARTLEY OWEN , SHIH STUART S , SARLI MICHAEL S , ANGEVINE PHILIP J , DIEZ DOUGLAS S , KEVILLE KATHLEEN M , LISSY DARIA N
IPC分类号： C10G35/04 , B01J29/40 , B01J29/70 , B01J37/00 , C10G35/095 , C10G63/02 , C10G69/02 , C10G69/08
摘要： 2113810 9304146 PCTABS00020 Low sulfur gasoline of relatively high octane number is produced from a catalytically cracked, sulfur-containing naphtha by hydrodesulfurisation followed by treatment over an acidic catalyst, preferably an intermediate pore size zeolite such as ZSM-5. The treatment over the acidic catalyst in the second step restores the octane loss which takes place as a result of the hydrogenative treatment and results in a low sulfur gasoline product with an octane number comparable to that of the feed naphtha. A catalytically cracked naphtha from the FCC main column (10) is first hydrotreated in a hydrotreater (11) which it enters through inlet (12). From hydrotreater (11), the desulfurised naphtha passes through line (13) to the second reactor (14) in which it is contacted with ZSM-5 or another acidic catalyst, for example zeolite beta or MCM-22 where a controlled degree of cracking takes place with an octane, which was lost in the hydrotreater, being restored. The effluents from reactor (14) are separated and further processed.

6. 发明专利

CA2023449A1 PRODUCTION OF AROMATICS-RICH GASOLINE WITH LOW BENZENE CONTENT 未知
公开(公告)号：CA2023449A1
公开(公告)日：1991-02-25
申请号：CA2023449
申请日：1990-08-16
申请人： MOBIL OIL CORP
发明人： HARANDI MOHSEN N , OWEN HARTLEY
IPC分类号： C10G59/04 , C10G63/00 , C10L1/06 , C07C2/66 , C07C15/02
摘要： F-5455 PRODUCTION OF AROMATICS-RICH GASOLINE WITH LOW BENZENE CONTENT A process for the production of high octane gasoline rich in aromatics but containing a relatively low concentration of benzene comprises the separation of C6 fraction of the gasoline feedstock into n-hexane and other C6 isomers. The n-hexane and C7+ streams are catalytically reformed to produce a reformate with a diminished yield of benzene. The reformate is separated and the C6- reformate fraction containing benzene is alkylated employing a zeolite catalyst such as ZSM-5 and preferably methanol or propylene as the alkylating agent. The alkylate comprises high octane C7+ alkylaromatics.

7. 发明专利

CA2031184A1 CONVERSION OF ALCOHOLS TO ETHER-RICH GASOLINE 未知
公开(公告)号：CA2031184A1
公开(公告)日：1990-10-25
申请号：CA2031184
申请日：1990-04-23
申请人： MOBIL OIL CORP
发明人： HARANDI MOHSEN N , OWEN HARTLEY
IPC分类号： C07B61/00 , C07C41/06 , C07C43/04 , C10G3/00 , C10G35/06 , C10G35/095 , C10L1/02 , C10L1/18 , B01J8/04
摘要： F-5342 CONVERSION OF ALCOHOLS TO ETHER-RICH GASOLINE Methanol or other alcohol is converted to high octane gasoline components by an integrated process wherein crude aqueous alcohol feedstock is extracted with a liquid extractant stream containing C4+ iso-olefin and reacted to form tertiary-alkyl ethers, such as MTBE. The aqueous raffinate is converted to olefinic hydrocarbons in a MTO catalytic reactor. Propene from the MTO reaction is reacted with water to produce di-isopropyl ether, which may be blended with MTBE and C6+ MTO hydrocarbons to produce high octane gasoline. Isobutylene and isoamylenes from the MTO reaction can be recovered and recycled as a liquid extractant stream.

8. 发明专利

CA2112119A1 DEHYDROGENATION AND ISOMERIZATION/OLIGOMERIZATION OF LIGHT PARAFFIN FEEDS 未知
公开(公告)号：CA2112119A1
公开(公告)日：1993-02-18
申请号：CA2112119
申请日：1992-07-28
申请人： MOBIL OIL CORP
发明人： HAAG WERNER O , HARANDI MOHSEN N , OWEN HARTLEY
IPC分类号： C10G35/06 , C10G35/095 , C10G59/02 , C10G35/04
摘要： 2112119 9303116 PCTABS00019 The invention relates to a dual catalyst process for increasing the production of total olefin and iso-olefin derivatives in the conversion of alkane containing feeds.

9. 发明专利

CA2027573A1 PROCESS FOR THE PRODUCTION OF ALKYL AROMATIC HYDROCARBONS 未知
公开(公告)号：CA2027573A1
公开(公告)日：1990-09-21
申请号：CA2027573
申请日：1990-03-19
申请人： MOBIL OIL CORP
发明人： HARANDI MOHSEN N , KUSHNERICK JOHN D , OWEN HARTLEY
IPC分类号： C10G35/12 , B01J29/40 , C07B61/00 , C07C2/66 , C07C2/70 , C07C15/02 , C10G35/06 , C07C2/64
摘要： 2027573 9011266 PCTABS00002 A process for the production of gasoline from a C4-fuel gas containing ethene and propene and catalytic reformate containing C6 to C8 aromatic hydrocarbons. The C4-fuel gas in stream (28) is obtained by catalytic cracking of the vacuum gas oil fraction (7) obtained by distillation of a crude feed (1) in a distillation apparatus (2). The reformate C6-C8 aromatic hydrocarbons in stream (15) is obtained by hydrotreating naphta (5) in zone (9), followed by reforming in zone (13). The C4-fuel gas (28) and C6-C8 aromatic reformate (15) are mixed and contacted in a catalytic reactor (29) with a zeolite catalyst to convert ethene and propene in the fuel gas to C5+ aliphatic and aromatic hydrocarbon gasoline and to convert C6 to C8 aromatics in the reformate into C7 to C11 hydrocarbon gasoline. In a preferred embodiment, the process comprises maintaining a fluidized bed of zeolite catalyst particles in a turbulent reactor be at a temperature of 350-900·C and a pressure of 20-650 psig (240-4580 kpa). The weight ratio or aromatics to olefins is at least 5:1.

10. 发明专利

CA2005452A1 METHOD FOR ON-STREAM LOW-PRESSURE REGENERATION OF AN OLIGOMERIZATION CATALYST FROM A FLUID-BED REACTOR OPERATING AT HIGH PRESSURE WITH HYDROCARBONS IN A NON-LIQUID PHASE 未知
公开(公告)号：CA2005452A1
公开(公告)日：1990-06-19
申请号：CA2005452
申请日：1989-12-13
申请人： MOBIL OIL CORP
发明人： HARANDI MOHSEN N , OWEN HARTLEY
IPC分类号： C10G35/14 , B01J29/90 , C07C2/00 , C07C2/12 , C10G50/00 , C10G50/02 , C07C11/02
摘要： F-5105 METHOD FOR ON-STREAM LOW-PRESSURE REGENERATION OF AN OLIGOMERIZATION CATALYST FROM A FLUID-BED REACTOR OPERATING AT HIGH PRESSURE WITH HYDROCARBONS IN A NON-LIQUID PHASE A process is disclosed for stripping and regenerating a zeolite catalyst at relatively low pressure compared to that of an oligomerization reactor operated with a turbulent fluid-bed at above 515 kPa (60 psig). The reactor operates either with hydrocarbons in the gas phase, or, under near-critical or super-critical conditions, when they are in the super-dense phase. The super-dense phase exists outside a critical region in the phase envelope of the hydrocarbon mixture in the reactor, under conditions at which a liquid phase may not form (hence "non-liquid"). Whether the fluid-bed reactor is operated in the C5-C10 gasoline producing mode, the C+10 distillate mode, or, the C+22 lubes mode, continuous operation of a regenerator (for deactivated catalyst withdrawn from the reactor) at relatively low pressure, preferably less than 445 kPa (50 psig), is possible. A variable pressure "lock-stripper" recovers entrained hydrocarbon product from a recirculated catalyst stream before stripped catalyst is regenerated. As an alternative, a purging lock-hopper will step down the pressure and a stripper upstream of the regenerator and can strip the catalyst before it is regenerated. Without the lock-hoppers, attrition of the catalyst would make the process uneconomical. Regenerated catalyst is pressurized with feed in a charging lock-hopper downstream of the regenerator, and flowed to the reactor. The process results in oligomerization of a "light gas" or light naphtha, or other predominantly C3-C5 olefin feed, the remainder being mainly lower alkanes. Depending upon the process conditions, the oligomerized product is either C5-C10 gasoline, or a "heavies" stream (either distillate or lubes), with a minor proportion by weight of gasoline range hydrocarbons.

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