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    • 2. 发明申请
    • HARDENABLE COATING RESIN COMPOSITION, COATED MATERIALS AND CONTAINERS, AND PROCESS FOR PRODUCING THEM
    • 耐磨涂料树脂组合物,涂层材料和容器及其生产工艺
    • WO1996023842A1
    • 1996-08-08
    • PCT/JP1996000163
    • 1996-01-29
    • MITSUI PETROCHEMICAL INDUSTRIES, LTD.INAGAKI, HajimeYOSHII, Koji
    • MITSUI PETROCHEMICAL INDUSTRIES, LTD.
    • C09D04/02
    • G06K7/10693C09D4/00Y10T428/1352C08F222/1006
    • A material or container covered with a hardened coating film is obtained by coating the surface of a substrate made of a resin or the like with a hardenable coating resin composition comprising (a) a poly[(meth)acryloyloxyalkyl](iso)cyanurate of general formula (1) or (2) (wherein X , X and X are each (meth)acryloyl, hydrogen or alkyl (at least two of them being (meth)acryloyl); and R , R and R are each oxyalkylene or polyoxyalkylene), (b) a polyoxyalkanepolyol poly(meth)acrylate, (c) 2-methyl-[4-(methyltio)phenyl]-2-morpholino-1-propanone as photopolymerization initiator, (d) a thioxanthone photopolymerization initiator, (e) a monohydroxybenzophenone ultraviolet absorber, and (f) an organic solvent. The material and container thus coated are superior to those of the prior art in hardening characteristics and characteristics of hardened coating film, being suitable for utilization as a re-usable coated material.
    • 用硬化涂料树脂组合物涂覆由树脂等制成的基材的表面可以获得覆盖有硬化涂膜的材料或容器,该组合物包含(a)一般的(a)聚(甲基)丙烯酰氧基烷基(异)氰尿酸酯 式(1)或(2)(其中X 1,X 2和X 3各自为(甲基)丙烯酰基,氢或烷基(其中至少两个为(甲基)丙烯酰基) (b)聚氧化烯多元醇聚(甲基)丙烯酸酯,(c)2-甲基 - [4-(甲基氧)苯基] -2-吗啉代 - (d)噻吨酮光聚合引发剂,(e)单羟基二苯甲酮紫外线吸收剂和(f)有机溶剂。 如此涂覆的材料和容器优于现有技术的硬化涂膜的硬化特性和特性,适用于可再使用的涂覆材料。
    • 8. 发明申请
    • HEAT-RESISTANT RUBBER COMPOSITIONS
    • 耐热橡胶组合物
    • WO1996032442A1
    • 1996-10-17
    • PCT/JP1996000991
    • 1996-04-11
    • MITSUI PETROCHEMICAL INDUSTRIES, LTD.HAKUTA, TakashiTOJO, TetsuoKAWASAKI, MasaakiHOSOYA, Mikio
    • MITSUI PETROCHEMICAL INDUSTRIES, LTD.
    • C08L23/08
    • C08K5/14C08K5/0025C08L23/0815C08L2312/00C08L23/16C08L2666/04
    • A heat-resistant rubber composition that is vulcanizable and comprises a specified ethylene- alpha -olefin-nonconjugated polyene copolymer rubber (A) and an organic peroxide (B). It has a high efficiency of cross-linking with organic peroxides and can provide vulcanized rubber moldings having a high modulus and excellent resistances to environmental deteriorations such as resistance to thermal aging. Another heat-resistant rubber composition that is vulcanizable and comprises 100 parts by weight of a specified ethylene- alpha -olefin-nonconjugated polyene copolymer rubber (A) prepared from ethylene, a C3-C20 alpha -olefin and a vinyl-terminated norbornene compound as the nonconjugated polyene, 0.2-5 parts by weight of an amine age resister (C) and/or a hindered phenol age resister (D), 1-10 parts by weight of a sulfur age resister (E), and an organic peroxide (B). It can provide vulcanized rubber moldings having excellent mechanical and electrical characteristics and remarkably excellent resistance to thermal aging. When the ethylene- alpha -olefin-nonconjugated polyene copolymer rubber (A) is a blend of an ethylene- alpha -olefin-nonconjugated polyene copolymer rubber (A1) having a limiting viscosity [ eta ] of 1-10 dl/g and containing 0.01-2 mol.% of a nonconjugated polyene and another ethylene- alpha -olefin-nonconjugated polyene copolymer rubber (A2) having a limiting viscosity [ eta ] of 0.1-5 dl/g, containing 0.01-2 mol.% of a nonconjugated polyene, and having a limiting viscosity different from that of the component (A), the obtained heat-resistant rubber composition is extremely excellent in flowability and can provide vulcanized moldings having excellent mechanical and electrical characteristics and remarkably excellent resistance to thermal aging.
    • 一种耐硫橡胶组合物,其是可硫化的并且包含特定的乙烯-α-烯烃 - 非共轭多烯共聚物橡胶(A)和有机过氧化物(B)。 它具有与有机过氧化物交联的高效率,并且可以提供具有高模量和优异的耐老化耐热性的耐硫化橡胶模制品。 另一种可硫化的耐热橡胶组合物,其包含100重量份由乙烯,C3-C20α-烯烃和乙烯基封端的降冰片烯化合物制备的特定乙烯-α-烯烃 - 非共轭多烯共聚物橡胶(A) 非共轭多烯,0.2-5重量份的胺抗老化剂(C)和/或受阻酚抗老化剂(D),1-10重量份的硫抗老化剂(E)和有机过氧化物( B)。 它可以提供具有优异机械和电气特性以及非常优异的耐热老化性能的硫化橡胶模制品。 当乙烯-α-烯烃 - 非共轭多烯共聚物橡胶(A)是特性粘度η为1-10dl / g的含乙烯-α-烯烃 - 非共轭多烯共聚物橡胶(A1)和0.01 -2摩尔%的非共轭多烯和另一种乙烯-α-烯烃 - 非共轭多烯共聚物橡胶(A2),其特性粘度η为0.1-5dl / g,含有0.01-2mol%的非共轭多烯 并且具有与(A)成分不同的特性粘度的情况下,得到的耐热橡胶组合物的流动性极其优异,能够提供具有优异的机械特性和电气特性的硫化成形体,耐热老化性优异。
    • 10. 发明申请
    • SEMICONDUCTOR LASER DEVICE
    • 半导体激光器件
    • WO1996012328A1
    • 1996-04-25
    • PCT/JP1995002118
    • 1995-10-16
    • MITSUI PETROCHEMICAL INDUSTRIES, LTD.OKUBO, AtsushiYAMADA, YoshikazuFUJIMOTO, TsuyoshiOKADA, SatoruNAITO, YumiMURO, Kiyofumi
    • MITSUI PETROCHEMICAL INDUSTRIES, LTD.
    • H01S03/18
    • B82Y20/00H01S5/204H01S5/222H01S5/2231H01S5/2238H01S5/3432
    • On a buffer layer (32) composed of n-GaAs are formed, as shown in the Fig., a clad layer (31) composed of n-AlGaAs; a waveguide layer (30); a carrier block layer (29); a side barrier layer (28) composed of non-doped AlGaAs; an active layer (27) including two quantum well layers of non-doped GaAs and a barrier layer of AlGaAs; a side barrier layer (26) composed of non-doped AlGaAs; a carrier block layer (25) composed of p-AlGaAs; a waveguide layer (23), a clad layer (22); and a cap layer (21) composed of p-GaAs in the order mentioned. In the waveguide layer (23) are formed current constriction layers (24), having a low refractive index resulting from its aluminum content more than that in the waveguide layer (23), which sandwich a striped active region (34). Thus, a difference in the refractive index appears between the active region (34) and a buried region (33) in which the current constriction layers (24) exist, thereby to form a refractive index waveguide structure. There is thus obtained a semiconductor laser device of the refractive index waveguide type that features a high output and can be easily fabricated.
    • 如图所示,在由n-GaAs构成的缓冲层(32)上形成由n-AlGaAs构成的覆层(31); 波导层(30); 载体阻挡层(29); 由非掺杂AlGaAs构成的侧面阻挡层(28) 包括两个非掺杂GaAs量子阱层和AlGaAs阻挡层的有源层(27); 由非掺杂AlGaAs构成的侧面阻挡层(26) 由p-AlGaAs构成的载流子阻挡层(25); 波导层(23),覆层(22); 和由p-GaAs组成的覆盖层(21)。 在波导层(23)中形成有电流收缩层(24),其具有由铝的含量高于夹在条形有源区域(34)中的波导层(23)中的低折射率的低折射率。 因此,在有源区域(34)和存在电流收缩层(24)的埋入区域(33)之间出现折射率差异,从而形成折射率波导结构。 由此获得了折射率波导型的半导体激光器件,该半导体激光器具有高输出特性并且可以容易地制造。