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    • 3. 发明专利
    • DE3588107D1
    • 1996-06-27
    • DE3588107
    • 1985-02-01
    • MITSUI PETROCHEMICAL IND
    • KAJIURA HIROKAZUODA HIDEKUNIMINAMI SYUJI
    • C08F210/02C08G61/08C08L65/00C08F232/08
    • A random copolymer composed of ethylene, a 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene and optionally an alpha-olefin having at least three carbon atoms or cycloolefin. The mole ratio of polymerized units from the 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene to polymerized units from ethylene is from 3:97 to 95:5 and the 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene is incorporated in the polymer chain as polymerized units without ring-opening.The copolymer is prepared by copolymerizing ethylene, optionally the alpha-olefin of at least 3 carbon atoms or cycloolefin, with the 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene in a hydrocarbon medium in the presence of a catalyst formed from a vanadium compound and an organoaluminum compound which are soluble in the hydrocarbon medium.The copolymer has excellent transparency and a well balanced-combination of heat resistance, heat aging resistance, chemical and solvent resistance, dielectric properties and mechanical properties such as rigidity.