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    • 5. 发明公开
    • SOLAR BATTERY ENCAPSULANT AND SOLAR BATTERY MODULE
    • SOLARBATTERIEVERKAPSELUNGSSTOFF UND SOLARBATTERIEMODUL
    • EP2637217A4
    • 2014-12-24
    • EP11837740
    • 2011-10-31
    • MITSUI CHEMICALS INCMITSUI CHEMICALS TOHCELLO INC
    • IKENAGA SHIGENOBUTAKEUCHI FUMITOWATANABE KEIJIITO TOMOAKI
    • H01L31/042C08F210/16C08K5/00C08K5/14C08K5/54C08L23/08C09K3/10
    • H01L31/0481C08F210/16C08K5/14C08K5/5425C08L23/0815C08L2023/40C08L2023/42C08L2203/204C08L2205/025C09D123/0815Y02E10/50C08F210/08C08F2500/08C08F2500/12C08F2500/26C08F210/14
    • The present invention is to provide an encapsulating material for solar cell excellent in a balance among general properties such as transparency, flexibility, adhesiveness, heat resistance, appearance, crosslinking properties, electrical properties and calender moldability. To achieve the above object, the encapsulating material for solar cell comprising an ethylene/±-olefin copolymer satisfying the following requirements (a1) to (a4): Disclosed is an encapsulating material for solar cell containing an ethylene/±-olefin copolymer satisfying the following requirements (a1) to (a4): (a1) the content ratio of structural units derived from ethylene is from 80 to 90 mol% and the content ratio of structural units derived from ±-olefin having 3 to 20 carbon atoms is from 10 to 20 mol%; (a2) MFR is equal to or more than 2 g/10 minutes and less than 10 g/10 minutes as measured under the conditions of a temperature of 190 degrees centigrade and a load of 2.16 kg in accordance with ASTM D1238; (a3) the density is from 0.865 to 0.884 g/cm 3 as measured in accordance with ASTM D1505; and (a4) the shore A hardness is from 60 to 85 as measured in accordance with ASTM D2240.
    • 本发明提供一种太阳能电池用封装材料,其透明性,柔软性,粘合性,耐热性,外观,交联性,电性能和砑光成型性等一般性能之间的平衡优异。 为了实现上述目的,包含满足以下要求(a1)至(a4)的乙烯/α-烯烃共聚物的太阳能电池用封装材料:公开了一种含有满足下述条件的乙烯/α-烯烃共聚物的太阳能电池用封装材料: 以下要求(a1)〜(a4):(a1)来自乙烯的结构单元的含有比例为80〜90摩尔%,来自碳原子数为3〜20的α-烯烃的结构单元的含有比例为10 至20mol%; (a2)根据ASTM D1238,在190℃的温度和2.16kg的负荷条件下测定,MFR等于或大于2g / 10分钟且小于10g / 10分钟; (a3)根据ASTM D1505测量的密度为0.865至0.884g / cm 3; 和(a4)根据ASTM D2240测量的肖氏A硬度为60至85。
    • 10. 发明公开
    • SOLAR-CELL SEAL MATERIAL AND SOLAR CELL MODULE
    • SOLARZELLENMODUL公司的DICHTUNGSMATERIALFÜRSOLARZELLEN
    • EP2924741A4
    • 2016-06-15
    • EP13857078
    • 2013-11-18
    • MITSUI CHEMICALS TOHCELLO INC
    • IKENAGA SHIGENOBUTAKEUCHI FUMITOITO TOMOAKIYARIMIZU KAZUHIROOHSHIMIZU KAORUODOI MASAAKI
    • C08L23/08C08F210/16C08K5/14C09K3/10H01L31/048
    • H01L31/0481C08K3/013C08K5/0041C08K5/14C08L23/0807Y02E10/50C08F210/16C08F210/14C08F2500/08C08F2500/12
    • Provided is an encapsulating material for solar cell which is capable of suppressing the leakage of the encapsulating material for solar cell and the contamination of a manufacturing apparatus during the manufacturing of a solar cell module, furthermore, suppresses the cracking of solar cell elements, and also has excellent long-term reliability. The encapsulating material for solar cell of the present invention is an encapsulating material for solar cell including an ethylene/±-olefin copolymer and an organic peroxide having a one-minute half-life temperature in a range of 100°C to 170°C. In addition, the complex viscosity of the encapsulating material for solar cell, which is measured through solid viscoelasticity measurement under conditions of a measurement temperature range of 25°C to 150°C, a frequency of 1.0 Hz, a rate of temperature increase of 10°C/minute, and a shear mode, has the minimum value (· *1 ) of the complex viscosity at a temperature in a range of 100°C to lower than 135°C, the minimum value (· *1 ) of the complex viscosity is in a range of 6.0×10 3 Pa·s to 4.0×10 4 Pa·s, the complex viscosity (· *2 ) of the encapsulating material for solar cell at 150°C is in a range of 2.0×10 4 Pa·s to 1.0×10 5 Pa·s, and the content of the organic peroxide in the encapsulating material for solar cell is in a range of 0.1 parts by weight to 3 parts by weight with respect to 100 parts by weight of the ethylene/±-olefin copolymer. In addition, an encapsulating material for a back surface of a solar cell which includes the ethylene/±-olefin copolymer as a component and does not easily sneak into a solar cell element is also included in the scope of the present invention.
    • 本发明提供一种能够抑制太阳能电池用封装材料的泄漏和太阳能电池模块制造时的制造装置的污染的太阳能电池用封装材料,进一步抑制太阳能电池元件的破裂, 具有良好的长期可靠性。 本发明的太阳能电池用封装材料是包含乙烯/α-烯烃共聚物和1分钟半衰期在100℃〜170℃的有机过氧化物的太阳能电池用封装材料。 另外,通过在25℃〜150℃的测定温度范围,1.0Hz的频率,10℃以下的温度范围内的固体粘弹性测定来测定太阳能电池用封装材料的复合粘度 ℃/分钟,剪切模式在100℃至低于135℃的温度下具有复数粘度的最小值(·* 1),最小值(·* 1)为 复数粘度在6.0×10 3 Pa·s〜4.0×10 4 Pa·s的范围内,150℃下的太阳能电池用封装材料的复数粘度(·* 2)为2.0×10 4Pa·s〜1.0×10 5 Pa·s,太阳能电池用封装材料中的有机过氧化物的含量相对于100重量份的上述重量份为0.1重量份〜3重量份 乙烯/α-烯烃共聚物。 另外,在本发明的范围内,还包括用于太阳能电池的背面的包封材料,该包装材料包括乙烯/α-烯烃共聚物作为组分并且不容易潜入太阳能电池元件。