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    • 3. 发明专利
    • AT503816T
    • 2011-04-15
    • AT07707333
    • 2007-01-24
    • MITSUI CHEMICALS INC
    • YASUI SHIGEYUKIOTA SEIJISAKUMA TAKASHI
    • C09J151/06B32B27/32C08F255/02C08L51/06C09J123/12C09J123/16C09J123/26
    • An object of the present invention is to provide polypropylene adhesive excellent in both initial adhesion and adhesion after heat history; and a laminate excellent in adhesion and heat resistance. Provided is a polypropylene-based adhesive having an MFR of 2.7 g/10min or higher as measured at 230°C under a load of 2.16 kg, comprising a composition which contains 5-95 parts by weight of (A) an isotactic polypropylene, 95-5 parts by weight of (B) a propylene/ethylene random copolymer, and 0-40 parts by weight of (C) an ethylene/propylene random copolymer, wherein 100 parts by weight of the composition is graft modified with 0.001-5 parts by weight of an unsaturated carboxylic acid and/or a derivative thereof, and wherein (B) is characterized by the following (i) to (iii): (i) the propylene/ethylene random copolymer (B) contains 60-90 mol% units derived from propylene and 10-40 mol% units derived from ethylene; (ii) the melting point (Tm) as measured with a differential scanning calorimeter is in the range of 40-120°C; and (iii) the molecular weight distribution (Mw/Mn) as determined by gel permeation chromatography (GPC) is in the range of 1.0-3.0.
    • 4. 发明专利
    • DE60141777D1
    • 2010-05-20
    • DE60141777
    • 2001-09-07
    • MITSUI CHEMICALS INC
    • IMUTA JUNICHIKASHIWA NORIOOTA SEIJIMORIYA SATORUNOBORI TADAHITOMIZUTANI KAZUMI
    • C08F210/02C08F4/659C08F4/6592C08F210/00C08F210/06C08F210/08C08F210/14C08F210/16C08F290/00C08L23/00
    • The present invention is intended to provide a polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit represented by the following formula (1) and a constituent unit represented by the following formula (4), and optionally a constituent unit represented by the following formula (5), having a molecular weight distribution (Mw/Mn) of not more than 3, and having an intensity ratio of T±² to T±± (T±²/T±±), as determined from a 13 C-NMR spectrum of said copolymer, of not more than 1.0: wherein R 1 is a hydrogen atom or a straight-chain or branched aliphatic hydrocarbon group of 1 to 18 carbon atoms; R 5 is a hydrocarbon group; R 6 is a hetero atom or a group containing a hetero atom; r is 0 or 1; Z is a polymer segment obtained by any one of anionic polymerization, ring-opening polymerization and polycondensation; W is a hydroxyl group or an epoxy group; p is an integer of 1 to 3, q is 0, 1 or 2, and p+q ‰ 3; when p is 2 or 3, each -O-Z may be the same or different, and in this case, if r is 0, -O-Z may be bonded to the same or different atom of R 5 , and if r is 1, -O-Z may be bonded to the same or different atom of R 6 ; when q is 2, each W may be the same or different, and in this case, if r is 0, W may be bonded to the same or different atom of R 5 , and if r is 1, W may be bonded to the same or different atom of R 6 ; in case of p‰¥1 and q‰¥1, if r is 0, W and -O-Z may be bonded to the same or different atom of R 5 , and if r is 1, W and -O-Z may be bonded to the same or different atom of R 6 ; m is 0 or 1; n is an integer of 1 to 3; and when n is 2 or 3, each W may be the same or different, and in this case, if m is 0, W may be bonded to the same or different atom of R 6 , and if m is 1, W may be bonded to the same or different atom of R 7 . The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.
    • 8. 发明专利
    • DE60124829D1
    • 2007-01-11
    • DE60124829
    • 2001-09-07
    • MITSUI CHEMICALS INC
    • IMUTA JUNICHIKASHIWA NORIOOTA SEIJIMORIYA SATORUNOBORI TADAHITOMIZUTANI KAZUMI
    • C08F210/02C08F4/659C08F4/6592C08F210/00C08F210/06C08F210/08C08F210/14C08F210/16C08L23/00
    • The present invention is intended to provide a polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit represented by the following formula (1) and a constituent unit represented by the following formula (4), and optionally a constituent unit represented by the following formula (5), having a molecular weight distribution (Mw/Mn) of not more than 3, and having an intensity ratio of T±² to T±± (T±²/T±±), as determined from a 13 C-NMR spectrum of said copolymer, of not more than 1.0: wherein R 1 is a hydrogen atom or a straight-chain or branched aliphatic hydrocarbon group of 1 to 18 carbon atoms; R 5 is a hydrocarbon group; R 6 is a hetero atom or a group containing a hetero atom; r is 0 or 1; Z is a polymer segment obtained by any one of anionic polymerization, ring-opening polymerization and polycondensation; W is a hydroxyl group or an epoxy group; p is an integer of 1 to 3, q is 0, 1 or 2, and p+q ‰ 3; when p is 2 or 3, each -O-Z may be the same or different, and in this case, if r is 0, -O-Z may be bonded to the same or different atom of R 5 , and if r is 1, -O-Z may be bonded to the same or different atom of R 6 ; when q is 2, each W may be the same or different, and in this case, if r is 0, W may be bonded to the same or different atom of R 5 , and if r is 1, W may be bonded to the same or different atom of R 6 ; in case of p‰¥1 and q‰¥1, if r is 0, W and -O-Z may be bonded to the same or different atom of R 5 , and if r is 1, W and -O-Z may be bonded to the same or different atom of R 6 ; m is 0 or 1; n is an integer of 1 to 3; and when n is 2 or 3, each W may be the same or different, and in this case, if m is 0, W may be bonded to the same or different atom of R 6 , and if m is 1, W may be bonded to the same or different atom of R 7 . The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.
    • 9. 发明专利
    • POLAR GROUP-CONTAINING OLEFIN COPOLYMER, PROCESS FOR PREPARING THE SAME, THERMOPLATIC RESIN COMPOSITION CONTAINING THE COPOLYMER, AND USES THEREOF
    • SG102636A1
    • 2004-03-26
    • SG200105472
    • 2001-09-07
    • MITSUI CHEMICALS INC
    • IMUTA JUNICHIKASHIWA NORIOOTA SEIJIMORIYA SATORUNOBORI TADAHITOMIZUTANI KAZUMI
    • C08F4/659C08F4/6592C08F210/00C08F210/02C08F210/06C08F210/08C08F210/14C08F210/16C08F210/04C08F216/02C08F216/12C08F220/64
    • The present invention is intended to provide a polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit represented by the following formula (1) and a constituent unit represented by the following formula (4), and optionally a constituent unit represented by the following formula (5), having a molecular weight distribution (Mw/Mn) of not more than 3, and having an intensity ratio of T±² to T±± (T±²/T±±), as determined from a 13 C-NMR spectrum of said copolymer, of not more than 1.0: wherein R 1 is a hydrogen atom or a straight-chain or branched aliphatic hydrocarbon group of 1 to 18 carbon atoms; R 5 is a hydrocarbon group; R 6 is a hetero atom or a group containing a hetero atom; r is 0 or 1; Z is a polymer segment obtained by any one of anionic polymerization, ring-opening polymerization and polycondensation; W is a hydroxyl group or an epoxy group; p is an integer of 1 to 3, q is 0, 1 or 2, and p+q ‰ 3; when p is 2 or 3, each -O-Z may be the same or different, and in this case, if r is 0, -O-Z may be bonded to the same or different atom of R 5 , and if r is 1, -O-Z may be bonded to the same or different atom of R 6 ; when q is 2, each W may be the same or different, and in this case, if r is 0, W may be bonded to the same or different atom of R 5 , and if r is 1, W may be bonded to the same or different atom of R 6 ; in case of p‰¥1 and q‰¥1, if r is 0, W and -O-Z may be bonded to the same or different atom of R 5 , and if r is 1, W and -O-Z may be bonded to the same or different atom of R 6 ; m is 0 or 1; n is an integer of 1 to 3; and when n is 2 or 3, each W may be the same or different, and in this case, if m is 0, W may be bonded to the same or different atom of R 6 , and if m is 1, W may be bonded to the same or different atom of R 7 . The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.