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1. 发明专利

DE69630260D1 未知
公开(公告)号：DE69630260D1
公开(公告)日：2003-11-13
申请号：DE69630260
申请日：1996-05-24
申请人： MITSUI CHEMICALS INC
发明人： MURAKAMI HIDETATSU , OMORI SATOSHI , WAKATSURU KENJI
IPC分类号： C08G69/26 , C08G69/28 , C08G69/32
摘要： A process for producing an aromatic polyamide which comprises: (a) a dicarboxylic acid component which consists of 30-100 mol% of terephthalic acid and optionally 0-70 mol% of at least one dicarboxylic acid other than terephthalic acid, and (b) a diamine component which consists of 50-100 mol% of an aliphatic alkylenediamine of 4-25 carbons and optionally 0-50 mol% of at least one alicyclic diamine of 3-25 carbons, said process comprising a first step of performing melt reaction of said dicarboxylic acid with said diamine, thereby giving a low molecular weight condensate having an intrinsic viscosity Ä eta Ü of 0.05-0.6 dl/g, a second step of subjecting it to solid phase polymerization, thereby giving an aromatic polyamide precursor having an intrinsic viscosity Ä eta Ü of 0.5-1.0 dl/g, and a third step of subjecting it to melt polymerization, thereby giving an aromatic polyamide having a desired intrinsic viscosity Ä eta Ü of 0.8-2.5 dl/g. This process permits the industrial production of high molecular weight aromatic polyamides in an economical and efficient manner.

2. 发明专利

DE60024652T2 未知
公开(公告)号：DE60024652T2
公开(公告)日：2006-06-22
申请号：DE60024652
申请日：2000-08-09
申请人： MITSUI CHEMICALS INC
发明人： MURAKAMI HIDETATSU , OKADA KEIJI , KAWASAKI MASAAKI , ICHINO KOTARO
IPC分类号： C08F210/02 , B60C1/00 , C08F210/18 , C08L21/00 , C08L23/08
摘要： A tire provided with a tire tread made from a rubber composition comprising (A) a random copolymer based on non-conjugated cyclic polyene comprising structural units originated from one or more alpha -olefins (A1) and originated from one or more non-conjugated cyclic polyene (A2), the said random copolymer having a content of the structural unit(s) originated from one or more alpha -olefins (A1) in the range of 93 to 70 mole %; a content of the structural unit originated from one or more non-conjugated cyclic polyene (A2) in the range of 7 to 30 mole %; an intrinsic viscosity Ä eta Ü , determined in decalin at 135 DEG C, in the range of 0.01 to 20 dl/g; a glass transition temperature (Tg) of not higher than 40 DEG C; and an iodine value in the range of 50 to 150, and (B) a rubber based on diene, in a weight proportion of äthe random copolymer based on non-conjugated cyclic polyene (A)ü versus äthe rubber based on diene (B)ü in the range from 60/40 to 0.1/99.9 exhibits a superior braking performance and, compatible therewith, a superior driving fuel cost aspect.

3. 发明专利

DE69901076D1 未知
公开(公告)号：DE69901076D1
公开(公告)日：2002-05-02
申请号：DE69901076
申请日：1999-05-28
申请人： MITSUI CHEMICALS INC
发明人： MAEDA KEN , YASUDA MASAAKI , FUJITA TERUNORI , OKADA KEIJI , KAMIMURA MAKOTO , TAKIMOTO KAZUYUKI , MURAKAMI HIDETATSU , KAWASAKI MASAAKI , WATANABE KEIJI
IPC分类号： C07C2/04 , C07C11/21 , C08F236/22
摘要： A novel and useful linear triene compound represented by the following formula (1) is co-polymerized with an alpha -olefin to obtain an ethylenically unsaturated copolymer which is superior in weatherability, heat resitance and fastness to ozone, together with superior scorch stability and vulcanizability at high velocity. in which R , R , R , R , R and R stand each, independently of each other, for hydrogen atom or an alkyl having 1 - 3 carbon atoms, R represents an alkyl having 1 - 3 carbon atoms and n is an integer of 0 - 5, with the proviso that each of R s or of R s may be identical with or different from each other, respectively, when n is 2 or greater.

4. 发明专利

DE69611599T2 未知
公开(公告)号：DE69611599T2
公开(公告)日：2001-06-13
申请号：DE69611599
申请日：1996-10-24
申请人： MITSUI CHEMICALS INC
发明人： OGO YOSHIMASA , MURAKAMI HIDETATSU , OOUCHI KUNIHIRO , SUDOU MASARU , AMIMOTO YOSHIKATSU , OMORI SATOSHI , WAKATSURU KENJI , HAYASHI RYUICHI , NOZAKI MASAHIRO
IPC分类号： C08G69/26 , C08G69/36 , C08K3/22 , C08K5/03 , C08K5/136 , C08L77/06 , C08L23/26 , C08L51/00 , C08L25/18 , C08K7/02
摘要： The semiaromatic polyamide of the invention comprises 40 to 90 % by mol of (A) recurring units derived from terephthalic acid and an aliphatic diamine of 4 to 12 carbon atoms, 0 to 50 % by mol of (B) recurring units derived from isophthalic acid and an aliphatic diamine of 4 to 12 carbon atoms, 0 to 60 % by mol of (C) recurring units derived from an aliphatic dicarboxylic acid of 4 to 18 carbon atoms and an aliphatic diamine of 4 to 12 carbon atoms and 0 to 50 % by mol of (D) recurring units derived from a lactam or an aminocarboxylic acid of 6 to 20 carbon atoms, and has a content of boiling water-soluble components (MO components) of not more than 0.25 % by weight. The semiaromatic polyamide has a low content of the MO components, so that mold contamination hardly brought about in the molding process, and also molded articles of good heat resistance can be produced.

5. 发明专利

DE60120930D1 未知
公开(公告)号：DE60120930D1
公开(公告)日：2006-08-03
申请号：DE60120930
申请日：2001-07-24
申请人： MITSUI CHEMICALS INC
发明人： MURAKAMI HIDETATSU , TAKAHASHI MAMORU , IKENAGA SHIGENOBU
IPC分类号： C08F210/02 , C08F4/659 , C08F4/6592 , C08F210/16 , C08L23/02 , C08L23/08
摘要： The ethylene copolymer of the invention is a copolymer (A-1) of ethylene and an alpha -olefin of 3 to 20 carbon atoms and has the following properties: (a) the melt index (MI2) at 190 DEG C under a load of 2.16 kg is in the range of 0.0001 to 1000 g/10 min, (b) the density is not more than 0.899 g/cm , (c) the relationship between a vinyl group amount and MI2 of the polymer satisfies the following expression (c) : (vinyl group amount : number of vinyl groups/1000 carbon atoms) ≤ 0.018038+0.003259xlog(MI2) and (d) the relationship between a vinylidene group amount and MI2 of the polymer satisfies the following expression (d) : (vinylidene group amount: number of vinylidene groups/1000 carbon atoms) ≤ 0.018038+0.003259xlog(MI2) The ethylene copolymer has a melt index, a density, a vinyl group amount and a vinylidene group amount in the specific ranges, and hence the copolymer is excellent in mechanical properties, molding processability, heat stability in the molding process and heat aging resistance.. The ethylene copolymer of the invention can be used for various molded products, particularly films and sheets, resin modifiers, and elastomeric products.

6. 发明专利

DE60024652D1 未知
公开(公告)号：DE60024652D1
公开(公告)日：2006-01-12
申请号：DE60024652
申请日：2000-08-09
申请人： MITSUI CHEMICALS INC
发明人： MURAKAMI HIDETATSU , OKADA KEIJI , KAWASAKI MASAAKI , ICHINO KOTARO
IPC分类号： B60C1/00 , C08F210/02 , C08F210/18 , C08L21/00 , C08L23/08
摘要： A tire provided with a tire tread made from a rubber composition comprising (A) a random copolymer based on non-conjugated cyclic polyene comprising structural units originated from one or more alpha -olefins (A1) and originated from one or more non-conjugated cyclic polyene (A2), the said random copolymer having a content of the structural unit(s) originated from one or more alpha -olefins (A1) in the range of 93 to 70 mole %; a content of the structural unit originated from one or more non-conjugated cyclic polyene (A2) in the range of 7 to 30 mole %; an intrinsic viscosity Ä eta Ü , determined in decalin at 135 DEG C, in the range of 0.01 to 20 dl/g; a glass transition temperature (Tg) of not higher than 40 DEG C; and an iodine value in the range of 50 to 150, and (B) a rubber based on diene, in a weight proportion of äthe random copolymer based on non-conjugated cyclic polyene (A)ü versus äthe rubber based on diene (B)ü in the range from 60/40 to 0.1/99.9 exhibits a superior braking performance and, compatible therewith, a superior driving fuel cost aspect.

7. 发明专利

DE10297606T5 未知
公开(公告)号：DE10297606T5
公开(公告)日：2004-12-09
申请号：DE10297606
申请日：2002-12-26
申请人： MITSUI CHEMICALS INC
发明人： OKADA KEIJI , MURAKAMI HIDETATSU , HAKUTA TAKASHI , KAWASAKI MASAAKI
IPC分类号： C08F210/02 , C08F210/06 , C08F210/16 , C08F210/18 , C08L23/08 , C09J123/08 , C09D123/08
摘要： A silicon-containing olefin copolymer is provided which comprises (a) a constituent unit derived from -CH 2 -CH 2 - such as ethylene, (b) a constituent unit derived from -CH 2 -CHR- where R is a hydrocarbon group of 1 to 18 carbon atoms, and (c) a constituent unit containing a specific silicon-containing group. A silicon-containing olefin copolymer is also provided which is obtainable by co-polymerizing ethylene, an a-olefin of 3 to 20 carbon atoms and a specific silicon-containing ethylene monomer.

8. 发明专利

DE69901076T2 未知
公开(公告)号：DE69901076T2
公开(公告)日：2002-11-14
申请号：DE69901076
申请日：1999-05-28
申请人： MITSUI CHEMICALS INC
发明人： MAEDA KEN , YASUDA MASAAKI , FUJITA TERUNORI , OKADA KEIJI , KAMIMURA MAKOTO , TAKIMOTO KAZUYUKI , MURAKAMI HIDETATSU , KAWASAKI MASAAKI , WATANABE KEIJI
IPC分类号： C07C2/04 , C07C11/21 , C08F236/22
摘要： A novel and useful linear triene compound represented by the following formula (1) is co-polymerized with an alpha -olefin to obtain an ethylenically unsaturated copolymer which is superior in weatherability, heat resitance and fastness to ozone, together with superior scorch stability and vulcanizability at high velocity. in which R , R , R , R , R and R stand each, independently of each other, for hydrogen atom or an alkyl having 1 - 3 carbon atoms, R represents an alkyl having 1 - 3 carbon atoms and n is an integer of 0 - 5, with the proviso that each of R s or of R s may be identical with or different from each other, respectively, when n is 2 or greater.

9. 发明专利

ID22621A 未知
公开(公告)号：ID22621A
公开(公告)日：1999-12-02
申请号：ID999904
申请日：1999-05-28
申请人： MITSUI CHEMICALS INC
发明人： MAEDA KEN , YASUDA MASAAKI , FUJITA TERUNORI , OKADA KEIJI , KAMIMURA MAKOTO , TAKIMOTO KAZUYUKI , MURAKAMI HIDETATSU , KAWASAKI MASAAKI , WATANABE KEIJI
IPC分类号： C07C2/04 , C07C11/21 , C08F236/22 , C08F210/18 , C08F210/14
摘要： A novel and useful linear triene compound represented by the following formula (1) is co-polymerized with an alpha -olefin to obtain an ethylenically unsaturated copolymer which is superior in weatherability, heat resitance and fastness to ozone, together with superior scorch stability and vulcanizability at high velocity. in which R , R , R , R , R and R stand each, independently of each other, for hydrogen atom or an alkyl having 1 - 3 carbon atoms, R represents an alkyl having 1 - 3 carbon atoms and n is an integer of 0 - 5, with the proviso that each of R s or of R s may be identical with or different from each other, respectively, when n is 2 or greater.

10. 发明专利

JP2006299065A ETHYLENE-α-OLEFIN-NONCONJUGATED POLYENE COPOLYMER, COPOLYMER COMPOSITION AND ITS USE 有权
标题翻译：乙烯-α-烯烃非共轭多烯共聚物，共聚物组合物及其用途
公开(公告)号：JP2006299065A
公开(公告)日：2006-11-02
申请号：JP2005122184
申请日：2005-04-20
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： IKENAGA SHIGENOBU , OKADA KEIJI , SHIRATA TAKASHI , NAGAI MITSUKO , SENBON HIRONARI , NAGAHASHI KOJI , MURAKAMI HIDETATSU , KAWASAKI MASAAKI
IPC分类号： C08F210/18 , C08F4/68 , C08K5/5419 , C08L23/08 , C09D7/12 , C09D123/00 , C09D123/08 , C09D145/00 , C09J11/06 , C09J123/00 , C09J123/08 , C09J145/00 , C09K3/10
摘要： PROBLEM TO BE SOLVED: To provide an ethylene-α-olefin-nonconjugated polyene copolymer that imparts a crosslinked product excellent in mechanical strengths such as tensile behavior, and when used as a plasticizer for a polymer such as a rubber, supplies superior processability, mechanical strengths of the crosslinked product and rubber elasticity (permanent compression strain), and to provide a crosslinkable copolymer composition comprising it and use thereof. SOLUTION: This copolymer comprises an ethylene unit, a 3-20C α-olefin unit and a nonconjugated polyene unit represented by formula [I] or [II], in which a weight ratio of the ethylene unit to the olefin unit is 40/60-95/5, V is 0.01-20 when the total weight of the polyene unit is V wt.%, limiting viscosity [η] (in decalin at 135°C) is 0.01-2.0 dl/g, and Mw/Mn is within a range of following formula (P): 2+0.05×V×[η]≤Mw/Mn≤2+4.8×V×[η] (P). The crosslinkable copolymer composition and its use is provided. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供赋予机械强度如拉伸性能优异的交联产物的乙烯-α-烯烃 - 非共轭多烯共聚物，并且当用作聚合物如橡胶的增塑剂时，提供优异的加工性，交联产物的机械强度和橡胶弹性（永久性压缩应变），以及提供包含它的可交联共聚物组合物及其用途。解决方案：该共聚物包含乙烯单元，3-20Cα-烯烃单元和由式[I]或[II]表示的非共轭多烯单元，其中乙烯单元与烯烃单元的重量比为 40 / 60-95 / 5，当多烯单元的总重量为V重量％时，V为0.01-20，特性粘度[η]（在135℃的萘烷中）为0.01-2.0dl / g，Mw / Mn在下述式（P）的范围内：2 + 0.05×V×[η]≤Mw/Mn≤2+ 4.8×V×[η]（P）。提供了交联性共聚物组合物及其用途。版权所有（C）2007，JPO＆INPIT

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