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    • 4. 发明专利
    • DE602006010675D1
    • 2010-01-07
    • DE602006010675
    • 2006-01-31
    • MITSUI CHEMICALS INC
    • KANEKO KAZUYOSHIHIROSE TOSHIYUKIYAMAOKA HIROYASUGOTO KENICHIHASEGAWA AKIRA
    • C08L45/00C08K3/00C08L9/00C08L23/00C08L23/26C08L25/02C08L65/00H05K1/03
    • A cyclic olefin resin composition which can be suitably used as a material for a substrate having low permittivity, low dielectric tangent, low water absorbability, excellent heat resistance, and the like, and a substrate obtained from the resin composition are provided. In particular, there is provided a novel cyclic olefin resin composition that can be suitably used as a material for a substrate for high frequency circuit dealing with high frequency signal transmission. The cyclic olefin resin composition comprises (A) 5 to 95 parts by weight of a cyclic olefin polymer having a glass transition temperature of 60 to 200°C and (B) 5 to 95 parts by weight of a flexible copolymer, prepared by polymerizing at least two monomers selected from the group consisting of an olefin compound, a diene compound and an aromatic vinyl hydrocarbon compound, and having a glass transition temperature of 0°C or below. The cyclic olefin resin composition further comprises, based on 100 parts by weight of total amount of the components (A) and (B), (D) 0.01 to 5 parts by weight of a radical initiator and (E) 0 to 5 parts by weight of a polyfunctional compound having in its molecule two or more radically polymerizable functional groups.
    • 9. 发明专利
    • Thermoplastic elastomer composition, molded body using the same and use
    • 热塑性弹性体组合物,使用它们的模制体和使用
    • JP2014181266A
    • 2014-09-29
    • JP2013055695
    • 2013-03-18
    • Mitsui Chemicals Inc三井化学株式会社
    • KANEKO KAZUYOSHI
    • C08L23/00C08J9/04C08L57/00C08L91/00
    • PROBLEM TO BE SOLVED: To provide a thermoplastic elastomer composition capable of preventing the formation eye mucus at extrusion molding, the resulting molded product having excellent external appearance, and suitable for providing a molded product with favorable mechanical properties.SOLUTION: A thermoplastic elastomer composition formed by crosslinking at least a part of olefinic rubber (A) is formed by dynamically crosslinking a mixture containing the olefinic rubber (A), an olefinic resin (B) having the melting point (Tm) of 70 to 200°C, and a propylene α-olefin random copolymer (C) satisfying the following (1) to (3). (1) The content of propylene is 70 mol% or more and less than 90 mol%. (2) A ratio Mw/Mn of a weight average molecular weight Mw to a number average molecular weight Mn is 3.5 or less. (3) The melting point (Tm) is less than 70°C.
    • 要解决的问题:为了提供能够防止在挤出成型时形成眼睛粘液的热塑性弹性体组合物,所得到的模制品具有优异的外观,并且适于提供具有良好机械性能的模制产品。解决方案:形成热塑性弹性体组合物 通过交联使至少一部分烯烃橡胶(A)通过动态交联含有烯烃橡胶(A),熔点(Tm)为70〜200℃的烯烃树脂(B)和丙烯 满足以下(1)〜(3)的α-烯烃无规共聚物(C)。 (1)丙烯含量为70摩尔%以上且小于90摩尔%。 (2)重均分子量Mw与数均分子量Mn的比Mw / Mn为3.5以下。 (3)熔点(Tm)小于70℃。