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1. 发明授权

US3875126A Production of alpha-olefin polymers 失效
标题翻译： ALPHA-OLEFIN聚合物的生产
公开(公告)号：US3875126A
公开(公告)日：1975-04-01
申请号：US32308073
申请日：1973-01-12
申请人： MITSUBISHI PETROCHEMICAL CO
发明人： TASHIRO KIJURO , YOKOYAMA MASUZO , KITAGAWA SADAO , MASUKAWA SHOICHI
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F10/00 , C08F15/04 , C08F3/02 , C08F19/02
CPC分类号： C08F10/00 , Y10S526/906 , C08F4/609 , C08F4/656 , C08F4/657 , C08F4/651
摘要： An Alpha -olefin is polymerized with another monomer through the use of a catalyst system prepared by combining: (I) a solid composition prepared by milling titanium trichloride in the presence of modifier, which is a halohydrocarbon, a silicon compound represented by the general formula SiXm'' Y4 m'' , where X'' is a halogen, Y'' is hydrogen, an alkyl group, an aryl group, an aralkyl group, an alkaryl group, or an alkoxyl group, and m is zero or the integer 1, 2, 3, or 4 (exclusive of SiH4), or a halogen compound of a specific metal; (II) an organoaluminum compound; and (III) a cycloheptatriene compound, including salts of tropylium.

2. 发明授权

US5276093B1 Resin molding 失效
标题翻译：树脂成型
公开(公告)号：US5276093B1
公开(公告)日：1996-12-10
申请号：US82846092
申请日：1992-01-31
申请人： MITSUBISHI PETROCHEMICAL CO
发明人： KITAGAWA SADAO , KUMANO YUTA
IPC分类号： C08L9/00 , C08L23/08 , C08L23/10 , C08L53/00
CPC分类号： C08L23/10 , C08L9/00 , C08L23/0869 , C08L53/00 , C08L2555/40 , Y10T428/24994 , Y10T428/25 , Y10T428/251 , Y10T428/31696 , Y10T428/31855 , Y10T428/31938 , C08L2666/04 , C08L2666/24

3. 发明授权

US5196270B1 Coated resin molding 失效
标题翻译：涂层树脂成型
公开(公告)号：US5196270B1
公开(公告)日：1996-06-25
申请号：US61248890
申请日：1990-11-14
申请人： MITSUBISHI PETROCHEMICAL CO
发明人： KITAGAWA SADAO , KUMANO YUTA
IPC分类号： C08L9/00 , C08L23/08 , C08L23/10 , C08L53/00 , B32B5/02 , B32B27/32
CPC分类号： C08L23/10 , C08L9/00 , C08L23/0869 , C08L53/00 , C08L2555/40 , Y10T428/25 , Y10T428/251 , Y10T428/27 , Y10T428/31696 , Y10T428/31855 , Y10T428/31938 , C08L2666/04 , C08L2666/24

4. 发明专利

DE2950437A1 未知
公开(公告)号：DE2950437A1
公开(公告)日：1980-06-26
申请号：DE2950437
申请日：1979-12-14
申请人： MITSUBISHI PETROCHEMICAL CO
发明人： KITAGAWA SADAO , OKADA ISAO , SAITO TERUO
IPC分类号： C08F4/00 , C08F4/02 , C08F4/44 , C08F4/60 , C08F4/64 , C08F10/00
摘要： This invention relates to a process for producing an alpha -olefin polymer having a high stereoregularity in a high yield by polymerizing alpha -olefin in the presence of a catalyst composed of solid catalyst component (I) prepared by contacting (A) magnesium halide, (B) aromatic carboxylic acid ester, (C) halogen compound of titanium, and (D) siloxyaluminum compound with each other, and (II) an organometallic compound of a metal of Group I to III in the Periodic Table.

5. 发明专利

DE2818642A1 未知
公开(公告)号：DE2818642A1
公开(公告)日：1978-11-02
申请号：DE2818642
申请日：1978-04-27
申请人： MITSUBISHI PETROCHEMICAL CO
发明人： KITAGAWA SADAO , OKADA ISAO , SAITO TERUO , YOKOYAMA MASUZO , MASUKAWA SHOICHI , WATANABE YOSHIHISA , IMANARI MAKOTO
IPC分类号： C08F10/00
摘要： A process for producing olefin polymers comprising contacting an ethylenically unsaturated monomer comprising at least one olefin monomer with a catalyst system comprising a combination of a catalyst component I and a catalyst component II as described hereunder: Catalyst component I A solid product obtained by contacting the following constituents (a), (b) and (c) or (a), (b), (c) and (d) together: (a) A solid reaction product of a magnesium compound containing a hydroxyl group attached to magnesium and an organoaluminum compound represented by the formula RnAlX3-n wherein R represents a hydrocarbon residue having from 1 to 20 carbon atoms, X represents a halogen atom and n represents a number of greater than zero but not greater than 1.5, i.e. 0

6. 发明专利

DE2059723A1 未知
公开(公告)号：DE2059723A1
公开(公告)日：1971-06-16
申请号：DE2059723
申请日：1970-12-04
申请人： MITSUBISHI PETROCHEMICAL CO
发明人： KITAGAWA SADAO
IPC分类号： C08F2/00 , C08F4/68 , C08F10/00 , C08F1/56
摘要： 1336319 Olefin polymerization catalyst MITSUBISHI PETROCHEMICAL CO Ltd 1 Dec 1970 [8 Dec 1969] 56953/70 Heading C3P Polymers of high crystallinity are obtained by polymerizing α-olefins in the presence of a catalyst comprising (i) a compound of a transition metal of Group IV, V or VI: (ii) an organometallic compound of a metal of Group I, II or III; and (iii) a tropylium (including substituted tropylium or fused ring-tropylium) salt. The catalyst components may be mixed in any order and, for example, (ii) and (iii) may be aged together before the addition of (i). The poly. merization of propylene is described, using heptane as the dispersion medium or dispersing the catalyst on preformed polypropylene and carrying out the polymerization in the gas phase. In the examples the catalyst components are (i) TiCl 3 , (ii) Et 3 Al, Et 2 AlCl or (i-Pr) 2 AlCl, and (iii) various tropylium salts. A comparative example describes the use of triphenylmethyl chloride instead of the tropylium salt.

7. 发明专利

DE3021273A1 未知
公开(公告)号：DE3021273A1
公开(公告)日：1981-01-08
申请号：DE3021273
申请日：1980-06-06
申请人： MITSUBISHI PETROCHEMICAL CO
发明人： KITAGAWA SADAO , OKADA ISAO
IPC分类号： C08F2/38 , C08F210/02 , C08F210/06 , C08F210/18

8. 发明专利

DE2301052A1 未知
公开(公告)号：DE2301052A1
公开(公告)日：1973-07-26
申请号：DE2301052
申请日：1973-01-10
申请人： MITSUBISHI PETROCHEMICAL CO
发明人： TASHIRO KIJURO , YOKOYAMA MASUZO , KITAGAWA SADAO , MASUKAWA SHOICHI
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F10/00 , C08F3/02
摘要： 1411144 Olefin polymerization catalysts MITSUBISHI PETROCHEMICAL CO Ltd 15 Jan 1973 [14 Jan 1972] 1984/73 Heading C3P α-Olefins are polymerized by contacting them with a catalyst system prepared by combining I, a solid prepared by milling TiCl 3 in the presence of at least one modifier selected from (a) halohydrocarbons including perhalogenated hydrocarbons, (b) halides of Se, Te, Sb, Cr, Au, Pb, V or Ge and (c) compounds of the formula where X is halogen, Y is H or an alkyl, aryl, aralkyl, alkaryl or alkoxy group and m is 0-4 but excluding SiH 4 ; II, an organo aluminium compound and III, acycloheptatriene compound. The olefin may be ethylene, propylene or butene or mixtures thereof. The TiCl 3 may be prepared by reduction of TiCl 4 with, e.g. H 2 , Ti or a silicon compound. The organo aluminium compound may be the product of reacting an aluminium hydride or organo compound with a diene. The polymerization may be carried out in bulk or in the presence of an solvent. Extensive lists of cycloheptatriene compounds are specified and claimed including tropones, tropolones, and tropylium salts. In the examples propylene is polymerized in the presence of polypropylene and in the presence or absence of hydrogen using a catalyst in which I is TiCl 3 , produced by reduction of TiCl 4 with Ti, which has been milled with TeCl 4 , SiCl 4 , CCl 4 , hexachlorocyclopentadiene, hexachlorobenzene, 1,5- dichloropentane or benzyl chloride, II is AlEt 3 or AlEt 2 Cl and III is tropylium tetrachloride aluminate, methyltropyl ether, tropyl chloropentene, tropyl chlorocyclopentene, N,N-dimethyl amino tropylidene, methoxyethyl tropylether, ditropyl or tropone or in comparative examples hexamethyl phosphortriamide. Reference has been directed by the Comptroller to Specification 1,336,319.

9. 发明专利

FR2393010A1 未知
公开(公告)号：FR2393010A1
公开(公告)日：1978-12-29
申请号：FR7812663
申请日：1978-04-28
申请人： MITSUBISHI PETROCHEMICAL CO
发明人： KITAGAWA SADAO , OKADA ISAO , SAITO TERUO , YOKOYAMA MASUZO , MASUKAWA SHOICHI , WATANABE YOSHIHISA , IMANARI MAKOTO
IPC分类号： C08F10/00 , C08F4/16
摘要： A process for producing olefin polymers comprising contacting an ethylenically unsaturated monomer comprising at least one olefin monomer with a catalyst system comprising a combination of a catalyst component I and a catalyst component II as described hereunder: Catalyst component I A solid product obtained by contacting the following constituents (a), (b) and (c) or (a), (b), (c) and (d) together: (a) A solid reaction product of a magnesium compound containing a hydroxyl group attached to magnesium and an organoaluminum compound represented by the formula RnAlX3-n wherein R represents a hydrocarbon residue having from 1 to 20 carbon atoms, X represents a halogen atom and n represents a number of greater than zero but not greater than 1.5, i.e. 0

10. 发明专利

JPH06345931A PRODUCTION OF THERMOPLASTIC ELASTOMER 失效
公开(公告)号：JPH06345931A
公开(公告)日：1994-12-20
申请号：JP13753593
申请日：1993-06-08
申请人： MITSUBISHI PETROCHEMICAL CO
发明人： KYO TAKESHI , BABA MITSUSHIGE , KITAGAWA SADAO
IPC分类号： C08F265/04 , C08F265/00 , C08L33/04 , C08L33/08
摘要： PURPOSE:To obtain a thermoplastic elastomer which is resistant to heat and oil and has improved compression set and flowability. CONSTITUTION:A thermoplastic elastomer comprising 55-97wt.% cross-linked acrylic rubber having a glass transition point of 0 deg.C or lower and 45-3wt.% methacrylic ester-maleimide copolymer having a glass transition point of 110 deg.C or higher is produced in two steps: the first step wherein an acrylic ester is polymerized in a water-base emulsion in the presence of a plasticizer together with a polyfunctional monomer having at least two ethylenically unsatd. bonds in the molecule, giving a cross-linked acrylic rubber latex; and the second step wherein a methacrylic ester and a maleimide are copolymerized in the presence of this latex obtd.

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