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    • 7. 发明专利
    • DE602004008002T2
    • 2007-11-22
    • DE602004008002
    • 2004-09-14
    • MITSUBISHI GAS CHEMICAL COKAO CORP
    • KITAMURA MITSUHARUKOJIMA TAKASHIATAKA YOSHIHARUKUBOTA TOMOAKIKATO KINJIFUKUDA KAZUYUKI
    • C07C67/14C07C51/58C07C61/135C07C67/60C07C69/753
    • An object of the present invention is to provide a process for producing high purity tricycloÄ5. 2. 1. 0 Üdecane-2-carboxylic acid ester which has a small content of an unsaturated compound and which has an excellent fragrance and is useful as a perfume or a perfume component. In a process for producing tricycleÄ5. 2. 1. 0 Üdecane-2-carboxylic acid ester by reacting tricycleÄ5. 2. 1. 0 Üdeca-3-ene with carbon monoxide and alcohol in the presence of HF, carried out separately are (a) a step in which tricycleÄ5. 2. 1. 0 Üdeca-3-ene is reacted with carbon monoxide to produce acyl fluoride and (b) a step in which acyl fluoride obtained in the step described above is reacted with alcohol to produce an ester, whereby tricycloÄ5. 2. 1. 0 Üdecane-2-carboxylic acid ester having a small content of an unsaturated compound can be obtained at a high yield. Also, the reaction conditions at the step (a) described above are selected or a step for carrying out isomerization reaction of tricycloÄ5. 2. 1. 0 Üdecane-2-carboxylic fluoride obtained at the step (a) is interposed between the step (a) and the step (b), whereby capable of being efficiently produced is tricycleÄ5. 2. 1. 0 Üdecane-2-carboxylic acid ester having a structural ratio of 1.0 or more in exo-tricycloÄ5. 2. 1. 0 Üdecane-endo-2-carboxylic acid ester/endo-tricycloÄ5. 2. 1. 0 Üdecane-exo-2-carboxylic acid ester Further, the crude product of tricycloÄ5. 2. 1. 0 Üdecane-2-carboxylic acid ester thus obtained is subjected to contact treatment with specific glycol in the presence of an acid catalyst and then distilled, whereby high purity tricycloÄ5. 2. 1. 0 Üdecane-2-carboxylic acid ester which is reduced in impurity aldehyde and which is excellent in a fragrance can industrially advantageously be produced.