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    • 5. 发明申请
    • ULTRAVIOLET RADIATION CURABLE ACRYLATE PRESSURE-SENSITIVE ADHESIVE COMPOSITIONS
    • 紫外线辐射固化丙烯酸酯压敏胶粘剂组合物
    • WO1993020164A1
    • 1993-10-14
    • PCT/US1993002528
    • 1993-03-19
    • MINNESOTA MINING AND MANUFACTURING COMPANY
    • MINNESOTA MINING AND MANUFACTURING COMPANYALI, Mahfuza, B.BABU, Gaddam, N.ZIMMERMAN, Patrick, G.
    • C09J04/06
    • C08F287/00C09J4/06
    • Crosslinked networks of (meth)acrylate (co)polymers, and a method of making the networks, are provided in which a photoiniferter-derived homopolymer, random copolymer or block copolymer is dissolved in a compatible monomer mixture along with a radiation-sensitive photoinitiator and crosslinker. The polymer-monomer mixture is coated onto a suitable web and cured via ultraviolet radiation to yield a crosslinked network resulting from polymerization of monomers along with incorporation of the active photoiniferter polymer. The networks exhibit excellent adhesive properties. When the photoiniferter polymer is a homopolymer, a random copolymer or an AB-type diblock copolymer, a pressure-sensitive adhesive results. When the photoiniferter polymer is a homopolymer or a random copolymer, the resulting adhesive exhibits excellent vibration-damping characteristics. When the photoiniferter polymer is an ABA-type triblock copolymer, a structural adhesive is obtained.
    • 提供(甲基)丙烯酸酯(共)聚合物的交联网络,以及制备网络的方法,其中将光引发剂衍生的均聚物,无规共聚物或嵌段共聚物与辐射敏感的光引发剂一起溶解在相容的单体混合物中, 交联剂。 将聚合物 - 单体混合物涂覆到合适的纤维网上并通过紫外线辐射固化,得到由单体聚合产生的交联网络以及掺入活性光引发剂聚合物。 网络表现出优异的粘合性能。 当光引发剂聚合物是均聚物,无规共聚物或AB型二嵌段共聚物时,产生压敏粘合剂。 当光引发剂聚合物是均聚物或无规共聚物时,所得粘合剂表现出优异的减振特性。 当光引发剂聚合物是ABA型三嵌段共聚物时,获得结构粘合剂。