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1. 发明申请

WO2001066499A1 CATALYSTS AND PROCESS FOR HYDROGENOLYSIS OF SUGAR ALCOHOLS TO POLYOLS 审中-公开
标题翻译：将蔗糖氢化成多元醇的催化剂和方法
公开(公告)号：WO2001066499A1
公开(公告)日：2001-09-13
申请号：PCT/US2001/000536
申请日：2001-01-08
申请人： MICHIGAN STATE UNIVERSITY , BATTELLE MEMORIAL INSTITUTE
发明人： CHOPADE, Shubham, P. , MILLER, Dennis, J. , JACKSON, James, E. , WERPY, Todd, A. , FRYE, John, G., Jr. , ZACHER, Alan, H.
IPC分类号： C07C29/00
CPC分类号： C07C29/00 , C07C29/60 , C07C31/202 , C07C31/205 , C07C31/225
摘要： The present invention provides a process for preparation of low molecular weight polyols from high molecular weight polyols in a hydrogenolysis reaction under elevated temperature and hydrogen pressure. The process comprises providing in a reaction mixture the polyols, a base, and a metal catalyst prepared by depositing a transition metal salt on an inert support, reducing the metal salt to the metal with hydrogen, and passivating the metal with oxygen, and wherein the catalyst is reduced with hydrogen prior to th e reaction. In particular, the process provides for the preparation of glycerol, propylene glycol, and ethylene glycol from sugar alohols such as sorbitol or xylitol. In a preferred process, the metal catalyst comprises ruthenium which is deposited on an alumina, titania, or carbon support, and the dispersion of the ruthenium on the support increases during the hydrogenolysis reaction.
摘要翻译：本发明提供了在升高的温度和氢气压力下在氢解反应中由高分子量多元醇制备低分子量多元醇的方法。该方法包括在反应混合物中提供多元醇，碱和通过在惰性载体上沉积过渡金属盐制备的金属催化剂，用氢将金属盐还原成金属，并用氧钝化金属，其中催化剂在反应之前用氢还原。特别地，该方法提供从糖醇如山梨糖醇或木糖醇制备甘油，丙二醇和乙二醇。在优选的方法中，金属催化剂包含沉积在氧化铝，二氧化钛或碳载体上的钌，并且在氢解反应期间钌在载体上的分散体增加。

2. 发明申请

WO2003035582A1 HYDROGENOLYSIS OF 6-CARBON SUGARS AND OTHER ORGANIC COMPOUNDS 审中-公开
标题翻译： 6碳糖和其他有机化合物的氢化
公开(公告)号：WO2003035582A1
公开(公告)日：2003-05-01
申请号：PCT/US2002/033982
申请日：2002-10-23
申请人： BATTELLE MEMORIAL INSTITUTE , MICHIGAN STATE UNIVERSITY , WERPY, Todd, A. , FRYE, John, G., Jr. , ZACHER, Alan, H. , MILLER, Dennis, J.
发明人： WERPY, Todd, A. , FRYE, John, G., Jr. , ZACHER, Alan, H. , MILLER, Dennis, J.
IPC分类号： C07B31/00
CPC分类号： C07C29/00 , B01J21/18 , B01J23/8896 , B01J37/0201 , B01J37/0205 , B01J37/0209 , B01J37/18 , C07C29/149 , C07C29/60 , Y02P20/52 , C07C31/205 , C07C31/225 , C07C31/202
摘要： Methods for hydrogenolysis are described which use a Re-containing multimetallic catalyst for hydrogenolysis of both C-O and C-C bonds. Methods and compositions for reactions of hydrogen over a Re-containing catalyst with compositions containing a 6-carbon sugar, sugar alcohol, or glycerol are described. It has been surprisingly discovered that reaction with hydrogen over a Re-containing multimetallic catalyst resulted in superior conversion and selectivity to desired products such as propylene glycol.
摘要翻译：描述了用于氢解的方法，其使用含Re多金属催化剂来氢解C-O和C-C键。描述了含氢催化剂与含有6-碳糖，糖醇或甘油的组合物的氢反应的方法和组合物。已经令人惊讶地发现与含氢多金属催化剂上的氢反应导致对所需产物如丙二醇的优异的转化率和选择性。

3. 发明授权

EP1440046B1 HYDROGENOLYSIS OF SUGARS, SUGAR ALCOHOLS AND GLYCEROL 有权
标题翻译：糖，糖醇和甘油的氢解
公开(公告)号：EP1440046B1
公开(公告)日：2017-05-03
申请号：EP02784244.2
申请日：2002-10-23
申请人： BATTELLE MEMORIAL INSTITUTE , MICHIGAN STATE UNIVERSITY
发明人： WERPY, Todd, A. , FRYE, John, G., Jr. , ZACHER, Alan, H. , MILLER, Dennis, J.
IPC分类号： C07B31/00 , C07C29/00
CPC分类号： C07C29/00 , B01J21/18 , B01J23/8896 , B01J37/0201 , B01J37/0205 , B01J37/0209 , B01J37/18 , C07C29/149 , C07C29/60 , Y02P20/52 , C07C31/205 , C07C31/225 , C07C31/202

4. 发明申请

WO2007146836A1 HYDROXYMETHYLFURFURAL REDUCTION METHODS AND METHODS OF PRODUCING FURANDIMETHANOL 审中-公开
标题翻译：羟丙基纤维素还原方法及其制备方法
公开(公告)号：WO2007146836A1
公开(公告)日：2007-12-21
申请号：PCT/US2007/070802
申请日：2007-06-08
申请人： BATTELLE MEMORIAL INSTITUTE , LILGA, Michael, A. , HALLEN, Richard, T. , WERPY, Todd, A. , WHITE, James, F. , HOLLADAY, Johnathan, E. , FRYE, John, G. , ZACHER, Alan, H.
发明人： LILGA, Michael, A. , HALLEN, Richard, T. , WERPY, Todd, A. , WHITE, James, F. , HOLLADAY, Johnathan, E. , FRYE, John, G. , ZACHER, Alan, H.
IPC分类号： C07D307/12 , C07D307/40
CPC分类号： C07D307/12 , C07D307/40
摘要： A method of reducing hydroxymethylfurfural (HMF) where a starting material containing HMF in a solvent comprising water is provided. H 2 is provided into the reactor and the starting material is contacted with a catalyst containing at least one metal selected from Ni, Co, Cu, Pd, Pt, Ru, Ir, Re and Rh, at a temperature of less than or equal to 250°C. A method of hydrogenating HMF includes providing an aqueous solution containing HMF and fructose. H 2 and a hydrogenation catalyst are provided. The HMF is selectively hydrogenated relative to the fructose at a temperature at or above 30°C. A method of producing tetrahydofuran dimethanol (THFDM) includes providing a continuous flow reactor having first and second catalysts and providing a feed comprising HMF into the reactor. The feed is contacted with the first catalyst to produce furan dimethanol (FDM) which is contacted with the second catalyst to produce THFDM.
摘要翻译：提供一种还原羟甲基糠醛（HMF）的方法，其中含有HMF的原料在包含水的溶剂中。 H 2被提供到反应器中，起始材料与含有选自Ni，Co，Cu，Pd，Pt，Ru，Ir，Re和Rh中的至少一种金属的催化剂接触，温度小于或等于250℃。氢化HMF的方法包括提供含有HMF和果糖的水溶液。 H 2 H 2和氢化催化剂。在30℃或更高的温度下，HMF相对于果糖选择性氢化。制备四氢呋喃二甲醇（THFDM）的方法包括提供具有第一和第二催化剂的连续流动反应器，并向反应器中提供包含HMF的进料。进料与第一催化剂接触以产生与第二催化剂接触以产生THFDM的呋喃二甲醇（FDM）。

5. 发明申请

WO2009029540A2 CHEMICAL PRODUCTION PROCESSES, SYSTEMS, AND CATALYST COMPOSITIONS 审中-公开
标题翻译：化学生产过程，系统和催化剂组合物
公开(公告)号：WO2009029540A2
公开(公告)日：2009-03-05
申请号：PCT/US2008/074090
申请日：2008-08-22
申请人： BATTELLE MEMORIAL INSTITUTE , PETERSON, Thomas, H. , HOLLADAY, Johnathan, E. , ZACHER, Alan, H. , GRAY, Michel, J. , WERPY, Todd, A. , WHITE, James, F.
发明人： PETERSON, Thomas, H. , HOLLADAY, Johnathan, E. , ZACHER, Alan, H. , GRAY, Michel, J. , WERPY, Todd, A. , WHITE, James, F.
IPC分类号： C07C45/52 , C07C47/22 , B01J27/16
CPC分类号： C07C45/52 , C07C49/17 , C07C47/22
摘要： Chemical production processes are provided that include exposing a reactant composition to a catalyst composition to form a product composition, with the reactant composition including a multihydric alcohol compound and the catalyst composition being effective to dehydrate at least a portion of the multihydric alcohol compound. Embodiments of the process provide that the reactant composition is exposed to the catalyst composition for less than about 0.25 seconds and/or that the catalyst is maintained at a temperature of from about 2800C to about 3200C. Processes utilizing a reactant composition including a multihydric alcohol compound and an inert compound are also provided.
摘要翻译：提供了化学生产方法，其包括将反应物组合物暴露于催化剂组合物以形成产物组合物，反应物组合物包含多元醇化合物，催化剂组合物有效地使至少一部分多元醇化合物脱水。该方法的实施方案提供反应物组合物暴露于催化剂组合物少于约0.25秒和/或催化剂保持在约2800℃至约3200℃的温度。还提供了利用包含多元醇化合物和惰性化合物的反应物组合物的方法。

6. 发明申请

WO2007089527A2 METHOD OF FORMING A DIANHYDROSUGAR ALCOHOL 审中-公开
标题翻译：形成二氢化AR醇的方法
公开(公告)号：WO2007089527A2
公开(公告)日：2007-08-09
申请号：PCT/US2007/001996
申请日：2007-01-25
申请人： BATTELLE MEMORIAL INSTITUTE , HOLLADAY, Johnathan , WERPY, Todd, A. , HU, Jianli , WANG, Yong , ZHANG, Xinjie
发明人： HOLLADAY, Johnathan , WERPY, Todd, A. , HU, Jianli , WANG, Yong , ZHANG, Xinjie
IPC分类号： C07D493/04
CPC分类号： C07D307/20 , C07D493/04 , Y02P20/127
摘要： The invention includes methods of producing dianhydrosugars. A polyol is reacted in the presence of a first catalyst to form a monocyclic sugar. The monocyclic sugar is transferred to a second reactor where it is converted to a dianhydrosugar alcohol in the presence of a second catalyst. The invention includes a process of forming isosorbide. An initial reaction is conducted at a first temperature in the presence of a solid acid catalyst. The initial reaction involves reacting sorbitol to produce 1 ,4-sorbitan, 3,6-sorbitan, 2,5-mannitan and 2,5-iditan. Utilizing a second temperature, the 1 ,4-sorbitan and 3,6-sorbitan are converted to isosorbide. The invention includes a method of purifying isosorbide from a mixture containing isosorbide and at least one additional component. A first distillation removes a first portion of the isosorbide from the mixture. A second distillation is then conducted at a higher temperature to remove a second portion of isosorbide from the mixture.
摘要翻译：本发明包括生产二脱水甘油糖的方法。多元醇在第一催化剂存在下反应形成单环糖。将单环糖转移到第二反应器中，在第二反应器中，在第二催化剂的存在下将其转化为二脱水甘油醇。本发明包括形成异山梨醇的方法。在固体酸催化剂存在下，在第一温度下进行初始反应。初始反应包括使山梨糖醇反应生成1,4-脱水山梨糖醇，3,6-脱水山梨糖醇，2,5-甘露聚糖和2,5-己烷。使用第二温度，将1,4-脱水山梨醇和3,6-脱水山梨醇转化为异山梨醇。本发明包括从含有异山梨醇和至少一种另外的组分的混合物中纯化异山梨醇的方法。第一蒸馏从混合物中除去第一部分的异山梨醇。然后在较高温度下进行第二次蒸馏以从混合物中除去第二部分的异山梨醇。

7. 发明授权

EP1558691B1 BIOBASED DEICING/ANTI-ICING FLUIDS 有权
标题翻译：生物材料为主的除冰/防冰剂
公开(公告)号：EP1558691B1
公开(公告)日：2011-10-26
申请号：EP03774969.4
申请日：2003-10-28
申请人： BATTELLE MEMORIAL INSTITUTE
发明人： SIMMONS, Kevin, L. , FRYE, John, G. , WERPY, Todd, A. , SAMUELS, William, D. , CONKLE, H., Nicholas , KUCZEK, Sara, F. , MONZYK, Bruce, F. , CHAUHAN, Satya, P.
IPC分类号： C09K3/18
CPC分类号： C09K3/185 , C09K3/18
摘要： A nontoxic deicing/anti-icing fluid includes a biobased freezing point depressant, a surfactant, an antioxidant, and water. The fluid has an LD50 greater than about 10,000 mg/L. Another deicing/anti-icing fluid includes a biobased freezing point depressant, a vinylpyrrolidone polymer having a molecular weight between about 10,000 and about 700,000, and water. Another deicing/anti-icing fluid includes a biobased freezing point depressant, a nonionic surfactant selected from the polyoxyalkylene ethers, an antioxidant, and water. Another deicing/anti-icing fluid includes a biobased freezing point depressant, a surfactant, a food grade material that functions as an antioxidant, and water. A further deicing/anti-icing fluid includes a biobased freezing point depressant, a material that functions as both a buffer and a freezing point depressant, and water.

8. 发明申请

WO2009029535A3 DEHYDRATION PROCESSES, SYSTEMS, AND CATALYST COMPOSITIONS 审中-公开
公开(公告)号：WO2009029535A3
公开(公告)日：2009-03-05
申请号：PCT/US2008/074079
申请日：2008-08-22
申请人： BATTELLE MEMORIAL INSTITUTE , PETERSON, Thomas, H. , WERPY, Todd, A. , ZACHER, Alan, H. , GRAY, Michel, J. , WHITE, James, F.
发明人： PETERSON, Thomas, H. , WERPY, Todd, A. , ZACHER, Alan, H. , GRAY, Michel, J. , WHITE, James, F.
IPC分类号： B01J27/185 , B01J27/186 , C07C45/52 , B01J8/00 , B01J23/755 , B01J23/89 , B01J23/94 , B01J23/96 , B01J37/12 , B01J37/14 , B01J38/00 , B01J38/12
摘要： Chemical production processes are provided that can include exposing a reactant composition to a catalyst composition to form a product composition. The reactant composition can include a multihydric alcohol compound and the product composition can include a carbonyl compound. The catalyst composition can include a metal effective to facilitate catalyst activation. Processes disclosed also include supplementing a dehydration catalyst with a promoter, and activating the supplemented catalyst in the presence of oxygen. Processes also include providing a supplemented dehydration catalyst to within a reactor, and exposing a multihydric alcohol compound to the dehydration catalyst, with the exposing forming coke within the reactor. Oxygen can be provided to the reactor to remove at least a portion of the coke.

9. 发明申请

WO2004058708A1 PROCESS FOR PRODUCING N-METHYL SUCCINIMIDE 审中-公开
标题翻译：生产N-甲基磺酰胺的方法
公开(公告)号：WO2004058708A1
公开(公告)日：2004-07-15
申请号：PCT/US2003/040106
申请日：2003-12-16
申请人： BATTELLE MEMORIAL INSTITUTE , WERPY, Todd, A. , FRYE, John, G., Jr. , WHITE, James, F. , HOLLADAY, Johnathan, E. , ZACHER, Alan, H.
发明人： WERPY, Todd, A. , FRYE, John, G., Jr. , WHITE, James, F. , HOLLADAY, Johnathan, E. , ZACHER, Alan, H.
IPC分类号： C07D207/40
CPC分类号： C07D207/404 , C07D207/267
摘要： The invention includes methods of processing an initial di-carbonyl compound by conversion to a cyclic compound. The cyclic compound is reacted with an alkyating agent to form a derivative having an alkylated ring nitrogen. The invention encompasses a method of producing an N-alkyl product. Amonia content of a solution is adjusted to produce a ratio of ammonia to di-carboxylate compound of from about 1:1 to about 1.5:1. An alkylating agent is added and the initial compound is alkylated and cyclized. The invention includes methods of making N-methyl pyrrolidinone (NMP). Aqueous ammonia and succinate is introduced into a vessel and ammonia is adjusted to provide a ratio of ammonia to succinate of less than 2:1. A methylating agent is reacted with succinate at a temperature of from greater than 100 °C to about 400 °C to produce N-methyl succinimide which is purified and hydrogenated to form NMP.
摘要翻译：本发明包括通过转化为环状化合物来处理初始二羰基化合物的方法。环状化合物与烷基化剂反应形成具有烷基化环氮的衍生物。本发明包括生产N-烷基产物的方法。调节溶液的阿莫尼亚含量以产生约1：1至约1.5：1的氨与二羧酸酯化合物的比例。加入烷基化剂并将该初始化合物烷基化并环化。本发明包括制备N-甲基吡咯烷酮（NMP）的方法。将氨水和琥珀酸钠引入容器中，并调节氨以提供小于2:1的氨与琥珀酸的比例。甲基化剂与琥珀酸盐在大于100℃至约400℃的温度下反应，生成N-甲基琥珀酰亚胺，将其纯化并氢化形成NMP。

10. 发明申请

WO2004039910A2 BIOBASED DEICING/ANTI-ICING FLUIDS 审中-公开
标题翻译： BIOBASED DEICING / ANTI-ICING FLUIDS
公开(公告)号：WO2004039910A2
公开(公告)日：2004-05-13
申请号：PCT/US2003/034181
申请日：2003-10-28
申请人： BATTELLE MEMORIAL INSTITUTE
发明人： SIMMONS, Kevin, L. , FRYE, John, G. , WERPY, Todd, A. , SAMUELS, William, D. , CONKLE, H., Nicholas , KUCZEK, Sara, F.
IPC分类号： C09K3/18
CPC分类号： C09K3/185 , C09K3/18
摘要： A nontoxic deicing/anti-icing fluid includes a biobased freezing point depressant, a surfactant, an antioxidant, and water. The fluid has an LD 50 greater than about 10,000 mg/L. Another deicing/anti-icing fluid includes a biobased freezing point depressant, a vinylpyrrolidone polymer having a molecular weight between about 10,000 and about 700,000, and water. Another deicing/anti-icing fluid includes a biobased freezing point depressant, a nonionic surfactant selected from the polyoxyalkylene ethers, an antioxidant, and water. Another deicing/anti-icing fluid includes a biobased freezing point depressant, a surfactant, a food grade material that functions as an antioxidant, and water. A further deicing/anti-icing fluid includes a biobased freezing point depressant, a material that functions as both a buffer and a freezing point depressant, and water.
摘要翻译：无毒除冰/防冰液包括生物基冰点降低剂，表面活性剂，抗氧化剂和水。该流体的LD 50大于约10,000mg / L。另一种除冰/防冰液包括生物基冰点降低剂，分子量约10,000至约700,000的乙烯基吡咯烷酮聚合物和水。另一种除冰/防冰液包括生物基冰点降低剂，选自聚氧化烯醚的非离子表面活性剂，抗氧化剂和水。另一种除冰/防冰液包括生物基冰点降低剂，表面活性剂，用作抗氧化剂的食品级材料和水。进一步的除冰/防冰液包括生物基冰点抑制剂，兼作缓冲剂和冰点抑制剂的物质以及水。

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