专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明申请

WO03031454A3 CATALYST SYSTEMS FOR ZIEGLER-NATTA PROPENE POLYMERISATION 审中-公开
标题翻译：催化剂体系齐格勒 - 纳塔丙烯聚合
公开(公告)号：WO03031454A3
公开(公告)日：2003-10-09
申请号：PCT/EP0210171
申请日：2002-09-11
申请人： MERCK PATENT GMBH , KOEHLER KATRIN , SCHUMANN HERBERT , WASSERMANN BIRGIT CORINNA , WASSERMANN WILFRIED , LANGE KATHARINA , DECHERT SEBASTIAN , HUMMERT MARKUS , SCHUTTE STEFAN , KAMINSKY WALTER , EISENHARDT ANDREA , HEUER BJOERN , LABAN ANDRE
发明人： KOEHLER KATRIN , SCHUMANN HERBERT , WASSERMANN BIRGIT CORINNA , WASSERMANN WILFRIED , LANGE KATHARINA , DECHERT SEBASTIAN , HUMMERT MARKUS , SCHUTTE STEFAN , KAMINSKY WALTER , EISENHARDT ANDREA , HEUER BJOERN , LABAN ANDRE
IPC分类号： C07F5/06 , C08F4/658 , C08F10/00
CPC分类号： C07F5/066
摘要： The invention relates to the use of nitrogenous aluminium organyl complexes of general formula (I) as co-catalysts in heterogeneous polymerisation reactions of propene. In said formula: R, R', R and R ' independently of one another represent branched or unbranched C1-C7 alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl or alkynyl; R represents unsubstituted, monoalkylated or polyalkylated and/or monofluorinated or polyfluorinated aromatic hydrocarbons from group (II); R and R independently of one another represent CH2, CF2 oder C(R )2; m stands for 0, 1 or 2; n stands for 0, 1 or 2; o stands for 0 or 1, all independently of one another. Said systems exhibit improved characteristics in terms of activity and stereoselectivity in comparison to conventional co-catalysts such as AlEt3 and can act simultaneously as co-catalysts and stereoselectivity promoters.
摘要翻译：本发明涉及以下通式的含氮有机铝配合物（I），其中R，R“ R <1>，R <1>”独立支链或无支链的C 1 -C 7 - 烷基，环烷基， - 烯基，环烯基，芳基或炔基; [R <2>或未取代的，单 - 或多 - 烷基化的和/或单独使用，或选自组（II）相乘，含氟芳香族烃; [R <3>，R <4>独立地是CH 2，CF 2或C（R <1>）2; m独立地为0，1，2; n为0，1，2; Ø0,1意味着在丙烯的非均相聚合反应中作为助催化剂。这里这些系统已经在相对于传统的助催化剂如AlEt.sub.3活性和立体选择性方面也可作为立体选择性启动子同时改善性质并且可以作为助催化剂的作用，而是。

2. 发明专利

DE50102701D1 未知
公开(公告)号：DE50102701D1
公开(公告)日：2004-08-05
申请号：DE50102701
申请日：2001-02-13
申请人： MERCK PATENT GMBH
发明人： KOEHLER KATRIN , POETSCH EIKE , SCHUMANN HERBERT , DECHERT SEBASTIAN , ARNOLD MANFRED , KNORR JANA , KAMINSKY WALTER , LABAN ANDRE
IPC分类号： C08F4/634 , C08F4/02 , C08F4/16 , C08F4/60 , C08F4/6392 , C08F4/64 , C08F4/68 , C08F4/685 , C08F10/00 , C08F110/02 , C08F110/06
摘要： Catalyst system contains an aluminum alkyl complex, magnesium chloride and/or silica as support, a catalyst selected from titanium and vanadium halides and internal and optionally also external donor(s). Catalyst system contains: (a) an aluminum alkyl complex of formula (I); (b) magnesium chloride (MgCl2) and/or silica (SiO2) as support; (c) a catalyst selected from titanium and vanadium halides; and (d) internal and optionally also external donor(s) selected from mono- and diester compounds, monoalkyltrialkoxysilanes of the formula RSi(OR)3 and dialkyldialkoxysilanes of formula R2Si(OR)2; R = 1-10 carbon (C) alkyl; X = NH, NH2 asterisk , NH-A asterisk , NH-SiA3 asterisk , N-A, NSiA3, N(A)2 asterisk , N(SiA3)2 asterisk , O, OSiA2, OA asterisk , OSiA3 asterisk , OAryl asterisk , S, SSiA2, SA asterisk , SSiA3 asterisk , PA, PSiA3, P(A)2 asterisk , P(SiA3)2 asterisk or a single bond; X = NH, N-A, NSiA3, O, OSiA2, S, SSiA2, PA or X complexed to Al(R )3 or a single bond; R , R = a bond, R , Si(A)3 or Si(A)2; Z = a bond or H bound to R ; Z = a bond or H bound to R and R ; A = 1-7 C alkyl, alkylidene or alkenylidene; aryl = phenyl, naphthyl, indenyl or fluorenyl; Hal = fluorine or chlorine; R = hydrogen; halogen if n = 0; A or Si(A)3 if X = O; R = A; CH2-CH=CH or CH2-CC if Z = H, o-phenylene-mono- or di-methylene or naphth-1,8-, -1,2- or -2,3-diyl; n, m, l = 0 or 1; q = 1 or 2. The full definitions are given in the DEFINITIONS (Full Definitions) Field. An Independent claim is also included for the preparation of a catalyst system for the polymerization of alpha -olefins or prochiral olefins from the cited components.

3. 发明专利

DE50209734D1 未知
公开(公告)号：DE50209734D1
公开(公告)日：2007-04-26
申请号：DE50209734
申请日：2002-09-11
申请人： MERCK PATENT GMBH
发明人： KOEHLER KATRIN , SCHUMANN HERBERT , WASSERMANN BIRGIT CORINNA , WASSERMANN WILFRIED , LANGE KATHARINA , DECHERT SEBASTIAN , HUMMERT MARKUS , SCHUTTE STEFAN , KAMINSKY WALTER , EISENHARDT ANDREA , HEUER BJOERN , LABAN ANDRE
IPC分类号： C07F5/06 , C08F4/658 , C08F10/00
摘要： The invention relates to the use of nitrogenous aluminium organyl complexes of general formula (I) as co-catalysts in heterogeneous polymerisation reactions of propene. In said formula: R, R', R 1 and R 1 ' independently of one another represent branched or unbranched C 1 -C 7 alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl or alkynyl; R 2 represents unsubstituted, monoalkylated or polyalkylated and/or monofluorinated or polyfluorinated aromatic hydrocarbons from group (II); R 3 and R 4 independently of one another represent CH 2 , CF 2 oder C(R 1 ) 2 ; m stands for 0, 1 or 2; n stands for 0, 1 or 2; o stands for 0 or 1, all independently of one another. Said systems exhibit improved characteristics in terms of activity and stereoselectivity in comparison to conventional co-catalysts such as AlEt 3 and can act simultaneously as co-catalysts and stereoselectivity promoters

4. 发明专利

AT356820T 未知
公开(公告)号：AT356820T
公开(公告)日：2007-04-15
申请号：AT02790284
申请日：2002-09-11
申请人： MERCK PATENT GMBH
发明人： KOEHLER KATRIN , SCHUMANN HERBERT , WASSERMANN BIRGIT CORINNA , WASSERMANN WILFRIED , LANGE KATHARINA , DECHERT SEBASTIAN , HUMMERT MARKUS , SCHUTTE STEFAN , KAMINSKY WALTER , EISENHARDT ANDREA , HEUER BJOERN , LABAN ANDRE
IPC分类号： C07F5/06 , C08F4/658 , C08F10/00
摘要： The invention relates to the use of nitrogenous aluminium organyl complexes of general formula (I) as co-catalysts in heterogeneous polymerisation reactions of propene. In said formula: R, R', R 1 and R 1 ' independently of one another represent branched or unbranched C 1 -C 7 alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl or alkynyl; R 2 represents unsubstituted, monoalkylated or polyalkylated and/or monofluorinated or polyfluorinated aromatic hydrocarbons from group (II); R 3 and R 4 independently of one another represent CH 2 , CF 2 oder C(R 1 ) 2 ; m stands for 0, 1 or 2; n stands for 0, 1 or 2; o stands for 0 or 1, all independently of one another. Said systems exhibit improved characteristics in terms of activity and stereoselectivity in comparison to conventional co-catalysts such as AlEt 3 and can act simultaneously as co-catalysts and stereoselectivity promoters

5. 发明专利

AT270308T 未知
公开(公告)号：AT270308T
公开(公告)日：2004-07-15
申请号：AT01102829
申请日：2001-02-13
申请人： MERCK PATENT GMBH
发明人： KOEHLER KATRIN , POETSCH EIKE , SCHUMANN HERBERT , DECHERT SEBASTIAN , ARNOLD MANFRED , KNORR JANA , KAMINSKY WALTER , LABAN ANDRE
IPC分类号： C08F4/634 , C08F4/02 , C08F4/16 , C08F4/60 , C08F4/6392 , C08F4/64 , C08F4/68 , C08F4/685 , C08F10/00 , C08F110/02 , C08F110/06
摘要： Catalyst system contains an aluminum alkyl complex, magnesium chloride and/or silica as support, a catalyst selected from titanium and vanadium halides and internal and optionally also external donor(s). Catalyst system contains: (a) an aluminum alkyl complex of formula (I); (b) magnesium chloride (MgCl2) and/or silica (SiO2) as support; (c) a catalyst selected from titanium and vanadium halides; and (d) internal and optionally also external donor(s) selected from mono- and diester compounds, monoalkyltrialkoxysilanes of the formula RSi(OR)3 and dialkyldialkoxysilanes of formula R2Si(OR)2; R = 1-10 carbon (C) alkyl; X = NH, NH2 asterisk , NH-A asterisk , NH-SiA3 asterisk , N-A, NSiA3, N(A)2 asterisk , N(SiA3)2 asterisk , O, OSiA2, OA asterisk , OSiA3 asterisk , OAryl asterisk , S, SSiA2, SA asterisk , SSiA3 asterisk , PA, PSiA3, P(A)2 asterisk , P(SiA3)2 asterisk or a single bond; X = NH, N-A, NSiA3, O, OSiA2, S, SSiA2, PA or X complexed to Al(R )3 or a single bond; R , R = a bond, R , Si(A)3 or Si(A)2; Z = a bond or H bound to R ; Z = a bond or H bound to R and R ; A = 1-7 C alkyl, alkylidene or alkenylidene; aryl = phenyl, naphthyl, indenyl or fluorenyl; Hal = fluorine or chlorine; R = hydrogen; halogen if n = 0; A or Si(A)3 if X = O; R = A; CH2-CH=CH or CH2-CC if Z = H, o-phenylene-mono- or di-methylene or naphth-1,8-, -1,2- or -2,3-diyl; n, m, l = 0 or 1; q = 1 or 2. The full definitions are given in the DEFINITIONS (Full Definitions) Field. An Independent claim is also included for the preparation of a catalyst system for the polymerization of alpha -olefins or prochiral olefins from the cited components.

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式