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    • 10. 发明专利
      DE102006009630A1 New silyl substituted anthracene compound useful in organic electronic devices e.g. organic electro luminescence device, organic field effect transistor, organic thin film transistor and organic light emitting transistor 未知
    • New silyl substituted anthracene compound useful in organic electronic devices e.g. organic electro luminescence device, organic field effect transistor, organic thin film transistor and organic light emitting transistor
    • DE102006009630A1
    • 2007-09-06
    • DE102006009630
    • 2006-03-02
    • MERCK PATENT GMBH
    • HEIL HOLGER , STOESEL PHILIPP , PARHAM AMIR , VESTWEBER HORST
    • C09K11/06 , H01L33/00
    • Silyl substituted anthracene compound (I) is new. Silyl substituted anthracene compound of formula (I) is new. Ar : 1-naphthyl or 9-anthryl group, in which one or two carbon atoms can be replaced by N and substituted with one or more of R 1> and/or N(Ar 1>) 2, where both remainders Ar 1> are connected by a single bond, O, S, N(R 1>) or C(R 1>) 2; R : (hetero)aromatic ring with 5-40C atoms, substituted with one or more of R 1> or N(Ar 1>) 2, where both remainders Ar 1> are connected by a single bond, O, S, N(R 1>) or C(R 1>) 2; Ar 1>(hetero)aromatic ring with 5-40C atoms, substituted with one or more of R 1>; Y 1>a bivalent group with 1-40C atoms, -O-, -S-, -NR 1>-, -P(=O)R 1>- or a single bond; R 1>alkyl-, alkoxy- or thioalkoxy with 1-40C atoms or branched or cyclic alkyl-, alkoxy- or thioalkoxy with 3-40C atoms (both substituted with one or more of R 3>, where one or more non-adjacent CH 2 groups are replaced by -R 3>C=CR 3>-, -C=C-, Si(R 3>) 2, Ge(R 3>) 2, Sn(R 3>) 2, C=O, C=S, C=Se, C=NR 3, -O-, -S-, -N(R 3>)- or -CONR 3>-, where one or more hydrogen atoms are replaced by F, Cl, Br, I, CN or NO 2), (hetero)aryl with 5-24C aromatic ring atoms (substituted with one or more of R 3>), (hetero)aryloxy with 5-24C aromatic ring atoms (substituted with one or more of R 3>), a combination out of two, three, four or five of these systems, Si(R 2>) 3 (preferred), F, Cl, Br, I, CN, N(R 3>) 2 or NO 2; either R 2>1-40C-alkyl, 3-40C-cyclic alkyl (where one or more adjacent CH 2 group can be bonded directly to the silicon, which can be replaced by -R 3>C=CR 3>-, -C?=C-, Si(R 3>) 2, Ge(R 3>) 2, Sn(R 3>) 2, C=O, C=S, C=Se, C=NR 3>, -O-, -S-, -N(R 3>)- or -CONR 3> and where one or more H atom can be replaced by F, Cl, Br, I, CN or NO 2), (hetero)aryl with 5-24 aromatic ring or (hetero)aryloxy (both are substituted by one or more R 3>); or two or more R 2>a mono or polycyclic ring system; R 3>H or 1-20C-hydrocarbon, which aliphatic or aromatic can be replaced by F; or R 3> (two or more) : mono-, polycyclic-, aliphatic- or aromatic ring system; n : 0-4; and m : 0-5. At least one variable of R 1> represents Si(R 2>) 3. Independent claims are included for: (1) the preparation of (I); (2) an organic electronic device comprising (I); and (3) an organic electroluminescence device comprising at least an emitting layer, at least an hole transport layer, hole injection layer, a hole blocking layer and/or electron transport layer, and (I). [Image].
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