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1. 发明专利

CA2142568A1 MULTIMETAL OXIDE COMPOSITIONS 未知
公开(公告)号：CA2142568A1
公开(公告)日：1995-08-18
申请号：CA2142568
申请日：1995-02-15
申请人： MARTIN FRIEDRICH GEORG , TENTEN ANDREAS
发明人： MARTIN FRIEDRICH-GEORG , TENTEN ANDREAS
IPC分类号： C01G1/00 , B01J23/88 , B01J23/887 , B01J27/14 , B01J27/18 , B01J27/199 , B01J35/00 , C01G1/02 , C01G39/00 , C07B61/00 , C07C57/055 , B01J23/00 , C01B13/14 , C07C51/235
摘要： Multimetal oxide compositions having a two-phase structure and comprising molybdenum, hydrogen, one or more of the elements phosphorus, arsenic, boron, germanium and silicon, one or more of the elements niobium, tantalum and antimony and one or more of the elements copper, iron, cobalt, nickel, zinc, cadmium, manganese, magnesium, calcium, strontium and barium, and their use for the preparation of methacrylic acid by gas-phase catalytic oxidation.

2. 发明专利

CA2142564A1 MULTIMETAL OXIDE COMPOSITIONS 未知
公开(公告)号：CA2142564A1
公开(公告)日：1995-08-18
申请号：CA2142564
申请日：1995-02-15
申请人： MARTIN FRIEDRICH GEORG , HIBST HARTMUT , TENTEN ANDREAS
发明人： MARTIN FRIEDRICH-GEORG , HIBST HARTMUT , TENTEN ANDREAS
IPC分类号： C01G1/00 , B01J23/88 , B01J23/885 , B01J27/14 , B01J27/195 , B01J27/199 , B01J35/00 , C01G1/02 , C01G39/00 , C07B61/00 , C07C51/25 , C07C57/055 , B01J23/00 , C01B13/14 , C07C51/235
摘要： Multimetal oxide compositions having a two-phase structure and comprising molybdenum, hydrogen, one or more of the elements phosphorus, arsenic, boron, germanium and silicon, and copper, and their use for the preparation of methacrylic acid by gas-phase catalytic oxidation.

3. 发明专利

CA2142770A1 POLYMETAL OXIDE MATERIALS 未知
公开(公告)号：CA2142770A1
公开(公告)日：1995-08-23
申请号：CA2142770
申请日：1995-02-17
申请人： TENTEN ANDREAS , MARTIN FRIEDRICH GEORG , HIBST HARMUT , MAROSI LASZLO , KOHL VERONIKA
发明人： TENTEN ANDREAS , MARTIN FRIEDRICH-GEORG , HIBST HARMUT , MAROSI LASZLO , KOHL VERONIKA
IPC分类号： C01G53/00 , B01J23/00 , B01J23/88 , B01J23/885 , B01J23/887 , B01J27/199 , B01J35/00 , C01G39/02 , C07B61/00 , C07C51/25 , C07C57/055 , C01B13/14 , C01G1/02 , C07C51/235
摘要： Polymetal oxide materials which contain molybdenum, vanadium, one or more of the elements tungsten, niobium, tantalum, chromium and cerium as well as copper and have a two-phase structure were used for the preparation of acrylic acid from acrolein by gas-phase catalytic oxidation.

4. 发明申请

WO2007135104A8 PRODUCTION OF PHTHALIC ANHYDRIDE BY GAS PHASE OXIDATION OF O-XYLOL 审中-公开
标题翻译：通过邻二甲苯的气相氧化制备邻苯二甲酸酐
公开(公告)号：WO2007135104A8
公开(公告)日：2008-06-12
申请号：PCT/EP2007054841
申请日：2007-05-18
申请人： BASF SE , MACKEWITZ THOMAS , ROSOWSKI FRANK , TENTEN ANDREAS
发明人： MACKEWITZ THOMAS , ROSOWSKI FRANK , TENTEN ANDREAS
IPC分类号： C07D307/89
CPC分类号： C07D307/89 , C07C51/265 , C07C63/16
摘要： The invention relates to a method for producing phthalic anhydride by catalytic gas phase oxidation of o-xylol. According to said method, a gaseous mixture of o-xylol and an oxygen-containing gas is guided through at least two reaction zones in a main reactor, the temperature of said reaction zones being adjustable independently of each other, and is reacted to give a gaseous intermediate reaction product which contains unreacted o-xylol, phthalic anhydride reaction products with a lower oxidation state and phthalic anhydride, and the intermediate reaction product is introduced into a secondary reactor. The temperature in the reaction zones in the primary reactor is controlled in such a manner that the concentration of the unreacted o-xylol in the intermediate reaction product is at least 0.5% by weight. The method according to the invention allows an increase in total yield of phthalic anhydride without any or without substantial decrease in product quality.
摘要翻译：用于通过邻二甲苯，其中其将通过至少两个反应区，其是独立温度可控地转发所描述的，含有氧的气体邻二甲苯的气体混合物，并在主反应器的催化气相氧化制备邻苯二甲酸酐，于气态中间反应产物的方法反应含有未反应的邻二甲苯，邻苯二甲酸酐欠氧化产品和邻苯二甲酸酐，以及将所述中间反应产物分离成二级反应器，其特征在于，它调节在主反应器中的反应区的温度，即未转化的邻二甲苯中的中间反应产物中的浓度为至少0 ，5重量％（重量）。该方法允许增加邻苯二甲酸酐的总产没有或没有在产品质量上显著恶化。

5. 发明申请

WO0206199A2 METHOD FOR PRODUCING ACRYLIC ACID BY THE HETEROGENEOUSLY CATALYSED GAS-PHASE OXIDATION OF PROPANE 审中-公开
标题翻译： PROCESS生产丙烯酸的丙烷非均相催化气相氧化
公开(公告)号：WO0206199A2
公开(公告)日：2002-01-24
申请号：PCT/EP0108178
申请日：2001-07-16
申请人： BASF AG , BORGMEIER FRIEDER , TENTEN ANDREAS , HIBST HARTMUT , MUELLER ENGEL KLAUS JOACHIM , UNVERRICHT SIGNE , COX GERHARD
发明人： BORGMEIER FRIEDER , TENTEN ANDREAS , HIBST HARTMUT , MUELLER-ENGEL KLAUS JOACHIM , UNVERRICHT SIGNE , COX GERHARD
IPC分类号： B01J23/00 , B01J23/28 , B01J27/057 , B01J37/02 , C07B61/00 , C07C45/33 , C07C45/35 , C07C51/215 , C07C57/05 , C07C51/00
CPC分类号： B01J23/002 , B01J23/28 , B01J27/0576 , B01J37/0232 , B01J2523/00 , C07C51/215 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , C07C57/04
摘要： The invention relates to a method for producing acrylic acid by the heterogeneously catalysed gas-phase oxidation of propane on a multi-metal oxide mass, said mass containing the elements Mo, V, Te and/or Sb and having a specific X-ray diffractogram.
摘要翻译：一种生产丙烯酸的通过丙烷的非均相催化气相氧化在含有元素Mo，V，Te和/或Sb，以及具有特定的Röntgendiffraktogram多金属氧化物材料的方法。

6. 发明申请

WO2007135102A2 PRODUCTION OF PHTHALIC ANHYDRIDE BY GAS PHASE OXIDATION OF o-XYLOL IN A PRIMARY AND A SECONDARY REACTOR 审中-公开
标题翻译：制备通过邻二甲苯的气相氧化邻苯二甲酸酐IN头部和Nachreaktor
公开(公告)号：WO2007135102A2
公开(公告)日：2007-11-29
申请号：PCT/EP2007054839
申请日：2007-05-18
申请人： BASF AG , MACKEWITZ THOMAS , ROSOWSKI FRANK , TENTEN ANDREAS
发明人： MACKEWITZ THOMAS , ROSOWSKI FRANK , TENTEN ANDREAS
IPC分类号： C07D307/89
CPC分类号： C07D307/89 , C07C51/265 , C07C63/16
摘要： The invention relates to a method for producing phthalic anhydride by catalytic gas phase oxidation of o-xylol. According to said method, a gaseous mixture of o-xylol and an oxygen-containing gas is reacted in a primary reactor to give a gaseous intermediate reaction product which contains unreacted o-xylol, phthalic anhydride reaction products with a lower oxidation state and phthalic anhydride, the reaction heat produced in the primary reactor being at least partially carried off by indirect cooling with a heat exchange medium, and introducing the intermediate reaction product to a secondary reactor. The concentration of the unreacted o-xylol in the intermediate reaction product is at least 1% by weight, and the sum of the concentrations of phthalic anhydride of the lower oxidation state in the intermediate reaction product is at least 0.5% by weight. The method according to the invention allows an increase in total yield of phthalic anhydride without any or without substantial decrease in product quality.
摘要翻译：公开了一种用于由邻二甲苯，其包含邻二甲苯的含氧气体中的主反应器中的气体混合物，并以气态中间反应产物，其包含未转化的邻二甲苯，邻苯二甲酸酐欠氧化产物反应的催化气相氧化制备邻苯二甲酸酐的方法和邻苯二甲酸酐，所述一个至少部分地耗散由间接冷却用载热介质，并导入中间反应产物分离成二级反应器在主反应器的反应热产生的热。未反应的邻二甲苯中的中间反应产物中的浓度为至少1重量％，邻苯二甲酸酐产品欠氧化浓度的在中间反应产物中的总和为至少0.5重量％。该方法允许增加邻苯二甲酸酐的总产没有或没有在产品质量上显著恶化。

7. 发明申请

WO0232571A9 CATALYST COMPRISING A SUPPORT AND A CATALYTICALLY ACTIVE OXIDE MATERIAL APPLIED TO THE SURFACE OF THE SUBSTRATE 审中-公开
标题翻译：催化剂包含载体体和在承载体，应用催化活性氧化物的表面
公开(公告)号：WO0232571A9
公开(公告)日：2003-11-06
申请号：PCT/EP0111909
申请日：2001-10-16
申请人： BASF AG , BORGMEIER FRIEDER , TENTEN ANDREAS , HIBST HARTMUT
发明人： BORGMEIER FRIEDER , TENTEN ANDREAS , HIBST HARTMUT
IPC分类号： B01J27/057 , B01J37/02 , C07B61/00 , C07C45/33 , C07C45/35 , C07C51/215 , C07C57/05 , B01J23/28 , B01J35/02
CPC分类号： C07C45/33 , C07C45/35 , Y10S502/514 , C07C47/22
摘要： The invention relates to a shell catalyst whose active material shell is a multimetal oxide that contains the elements Mo, V and Te and/or Sb. The invention further relates to the use of said shell catalyst for gas-phase catalytic oxidation of propane to acrylic acid.
摘要翻译：涂层催化剂其活性组合物是含有元素Mo，V，Te和/或Sb和使用Schaloenkatalysators来gasphasenkatalyschen丙烷氧化成丙烯酸的多金属氧化物。

8. 发明申请

WO0141924A3 OXIDATIVE REACTIONS USING MEMBRANES THAT SELECTIVELY CONDUCT OXYGEN 审中-公开
标题翻译：氧化反应使用混合氧检测膜
公开(公告)号：WO0141924A3
公开(公告)日：2001-10-25
申请号：PCT/EP0012497
申请日：2000-12-11
申请人： BASF AG , BITTERLICH STEFAN , VOSS HARTWIG , HIBST HARTMUT , TENTEN ANDREAS , VOIGT INGOLF , PIPPARDT UTE
发明人： BITTERLICH STEFAN , VOSS HARTWIG , HIBST HARTMUT , TENTEN ANDREAS , VOIGT INGOLF , PIPPARDT UTE
IPC分类号： C07D307/60 , B01D69/04 , B01D69/06 , B01D69/12 , B01D71/02 , B01J20/28 , B01J23/00 , B01J23/34 , B01J27/198 , B01J35/02 , B01J35/06 , C07B41/00 , C07B61/00 , C07C5/48 , C07C45/35 , C07C45/38 , C07C51/215 , C07C51/25 , C07C51/265 , C07C253/24 , C07C253/26 , C07C253/28 , C07D307/89 , C07C45/33 , C07C45/34
CPC分类号： C07C51/265 , B01J23/002 , B01J23/34 , B01J35/065 , B01J2523/00 , C07B41/00 , C07C5/48 , C07C45/35 , C07C45/38 , C07C51/215 , C07C51/252 , C07C253/24 , C07C253/26 , C07C253/28 , C07C2521/02 , C07C2521/10 , C07C2523/02 , C07C2523/04 , C07C2523/08 , C07C2523/10 , C07C2523/14 , C07C2523/34 , Y02P20/52 , C07C11/02 , C07C47/22 , C07C47/04 , C07C57/145 , C07C57/04 , C07C63/16 , B01J2523/23 , B01J2523/24 , B01J2523/72 , C07C255/51 , C07C255/08
摘要： The invention relates to reaction membranes that contain a selective oxidation catalyst disposed on a ceramic membrane that selectively conducts oxide ions and that is composed of (Sr1-xCax)1-yAyMn1-zBzO3- delta , wherein A represents Ba, Pb, Na, K, Y, an element of the lanthanide group or a combination of these elements, B represents Mg, Al, Ga, In, Sn, an element of the 3d or 4d period or a combination of these elements, x is a number of from 0.2 to 0.8, y is a number of from 0 to 0.4, z is a number of from 0 to 0.6 and delta is a number that results from the principle of electroneutrality on the basis of x, y and z. The inventive reaction membranes are suitable for use in oxidative reactions of hydrocarbons in which oxygen is used.
摘要翻译：本申请描述了包含在混合传导，所述组合物的氧化物离子选择性陶瓷膜的（Sr 1-x的Ca x）的1-yAyMn1-zBzO3-增量，其中A为Ba，铅，钠，钾，Y，镧系元素组或一的元件的选择氧化催化剂反应膜这些元素的组合，B表示镁，铝，镓，铟，锡，所述3D或4D期间或这些元素的组合的元素，x是从0.2到0.8的数，y是一个数字是从0至0.4，z是从0到0.6，和delta是一个数字，这导致的X，Y和z的术语从电中性原则的遵守情况。这些反应膜可以有利地用于使用氧的烃的氧化反应中。

9. 发明专利

CA2171417A1 PREPARATION OF ACROLEIN, ACRYLIC ACID OR A MIXTURE THEREOF FROM PROPANE 未知
公开(公告)号：CA2171417A1
公开(公告)日：1996-09-11
申请号：CA2171417
申请日：1996-03-08
申请人： HEFNER WERNER , MACHHAMMER OTTO , NEUMANN HANS PETER , TENTEN ANDREAS , RUPPEL WILHELM , VOGEL HERBERT
发明人： HEFNER WERNER , MACHHAMMER OTTO , NEUMANN HANS-PETER , TENTEN ANDREAS , RUPPEL WILHELM , VOGEL HERBERT
IPC分类号： C07C47/22 , C07B61/00 , C07C5/333 , C07C11/06 , C07C45/33 , C07C45/35 , C07C51/215 , C07C51/25 , C07C57/04 , C07C57/05 , C07C57/055
摘要： In a process for preparing acrolein, acrylic acid or a mixture thereof from propane, propane is partially dehydrogenated to propylene in a first stage, the product gas mixture resulting therefrom is, after separating off hydrogen and water vapor, used as feed to an oxidation reactor, the propylene formed in the dehydrogenation is partially oxidized in the oxidation reactor using molecular oxygen in the presence of non-dehydrogenated propane as inert diluent gas to give acrolein, acrylic acid or a mixture thereof and the propane present in the product gas mixture of the partial oxidation is subsequently recirculated to the dehydrogenation stage A.

10. 发明专利

CA2171416A1 CONTINUOUS HETEROGENEOUSLY CATALYZED GAS-PHASE PARTIAL OXIDATION OF AN ORGANIC COMPOUND 未知
公开(公告)号：CA2171416A1
公开(公告)日：1996-09-11
申请号：CA2171416
申请日：1996-03-08
申请人： HEFNER WERNER , MACHHAMMER OTTO , NEUMANN HANS PETER , TENTEN ANDREAS , RUPPEL WILHELM , VOGEL HERBERT
发明人： HEFNER WERNER , MACHHAMMER OTTO , NEUMANN HANS-PETER , TENTEN ANDREAS , RUPPEL WILHELM , VOGEL HERBERT
IPC分类号： C07B35/04 , C07B41/06 , C07B41/08 , C07C27/00 , C07C45/32 , C07C45/35 , C07C47/22 , C07C51/235 , C07C51/25 , C07C51/265 , C07C57/05 , C07D301/08 , C07C46/02 , C07D303/04 , C07C255/08 , C07C50/18 , C07C253/24 , C07C5/48 , C07D307/60 , C07D307/89
摘要： In a process for the continuous heterogeneously catalyzed gasphase partial oxidation of an organic compound in an oxidation reactor, whose feed gas mixture comprises, apart from the organic compound to be partially oxidized and molecular oxygen as oxidant, at least one diluent gas which is essentially inert under the conditions of the heterogeneously catalyzed gas-phase partial oxidation, where the essentially inert diluent gas consists partly of combustible gases, after passage through the oxidation reactor, the combustible constituents of the inert diluent gas present in the product gas stream leaving the oxidation reactor are not recirculated to the heterogeneously catalyzed gas-phase partial oxidation, but are put to further use for the purposes of another chemical reaction.

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