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    • 2. 发明专利
    • FI930098A
    • 1994-07-12
    • FI930098
    • 1993-01-11
    • MARC FINANCE LTD OYKETTUNEN PTUOTEKEHITYS OY TAMLINK
    • KETTUNEN PENTTILEPISTOE T K
    • C23C14/08C30B29/62
    • A method for producing fibrous monocrystals, i.e. whiskers, of high-temperature superconductive ceramics in their best superconductive crystal directions, thereby in the main avoiding the production of non-superconductive fibres and also the effect which decreases the superconductivity due to relatively weak superconductive crystal directions. Whiskers are produced by means of physical gas-phase coatings (physical vapour deposition = PVD), for example using radiofrequency magnetron sputtering (RF magnetron sputtering) or by means of chemical gas-phase coatings (chemical vapour deposition = CVD). The growth underlayer, i.e. the substrate, employed is a ceramic monocrystal surface in accordance with the (100) orientation, a ceramically coated metal surface or a smoothed or polished metal surface. It is typical of the latter alternative that the coating which is formed on the metal surface initially grows in a relatively weak superconductive crystal direction but then alters its growth to the best superconductive crystal direction and is at the same time transformed into whiskers.
    • 4. 发明专利
    • FI930100A
    • 1994-07-12
    • FI930100
    • 1993-01-11
    • MARC FINANCE LTD OYKETTUNEN PTUOTEKEHITYS OY TAMLINK
    • KETTUNEN PENTTILEPISTOE T K
    • H01Q17/00H05K9/00H05K39/14
    • Microscopic or macroscopic magnetic shield which is based on the use of such mono-crystalline whiskers as are obtained from high-temperature superconducting ceramics in their superconducting crystal directions. Whiskers form the superconducting part of the shield and an electrically insulating ceramic, polymer, intermetal or a metal which is a poor conductor forms its matrix which holds the whiskers together. Where the matrix or part thereof is a liquid polymer at the start of production, the shield can be painted or sprayed onto the surface of the piece which is to be protected and can solidify there to form a layer of a suitable thickness. The situation is similar when a ceramic suspension is used as an initial material for the matrix, but in this case the solidification of the matrix must be carried out by sintering. Various composite constructions containing superconducting whiskers can be used as magnetic shields, to remove electromagnetic interference and to make the shielded part invisible to radar, assuming that the temperature of the composite is suitable for making the whiskers superconductive.