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1. 发明申请

WO1995011745A1 CATALYTIC REACTOR FOR ENDOTHERMIC REACTIONS 审中-公开
标题翻译：催化反应器的吸热反应
公开(公告)号：WO1995011745A1
公开(公告)日：1995-05-04
申请号：PCT/DE1994001293
申请日：1994-10-26
申请人： MANNESMANN AG , K.T.I. Group B.V. , GIACOBBE, Francesco
发明人： MANNESMANN AG , K.T.I. Group B.V.
IPC分类号： B01J08/06
CPC分类号： C01B3/384 , B01J8/062 , B01J2208/00495 , B01J2219/00157 , C01B2203/0811 , C01B2203/0816 , C01B2203/0844 , C01B2203/0866
摘要： A catalytic reactor for endothermic reactions is disclosed. The catalyst is located in a housing (13) made of refractory material, and at least a tubular catalyst vessel (10) is arranged inside the housing (13). In order to obtain a catalytic reactor that avoids thermal damages to the reactor vessel without requiring costly construction measures nor undesirable increases in the amounts of exhaust gasses, as well as the resulting inconveniences for the energy efficiency of the fuels used, several mutually spaced catalyst vessels (10) are arranged in the housing (13), a plurality of burners (15) is arranged in the housing (13) in such a way that the catalyst vessels (10) lie between the burners (15) and the flame area of the burners (15) lies in the area of the heat dissipators (16) in order to ensure a non-adiabatic combustion.
摘要翻译：本发明涉及一种用于吸热反应的催化反应器。催化剂位于从耐火材料壳体（13）形成的载体，其中，所述壳体（13）的至少一个管状催化剂容器（10）的内部布置。为了提供在其中避免了反应器容器的热损伤，而不主要建筑工作或在废气和所使用的燃料的能量利用率缺点的量不希望有的增加必须被考虑到催化反应器，本发明提出的是，在壳体（13）的每个彼此的多个催化剂容器（10）被布置在所述壳体间隔开（13）包括多个燃烧器（15）被布置在这样一种方式，燃烧器之间的催化剂容器（10）（15）位于与所述燃烧器的火焰区域（15），以确保在热分配器（16）的区域中的每个情况下，非绝热燃烧。

2. 发明申请

WO1994008905A1 PROCESS FOR TREATING INDUSTRIAL WASTE WATERS WITH LOW CONCENTRATIONS OF TOXIC ORGANIC POLLUTANTS 审中-公开
标题翻译：法工业废水中有毒有机污染物低浓度的治疗
公开(公告)号：WO1994008905A1
公开(公告)日：1994-04-28
申请号：PCT/DE1993001016
申请日：1993-10-19
申请人： MANNESMANN AG , K.T.I. Group B.V. , LEVEC, Janez , PINTAR, Albin
发明人： MANNESMANN AG , K.T.I. Group B.V.
IPC分类号： C02F01/72
CPC分类号： C02F11/08 , C02F1/26 , C02F1/283 , C02F1/725 , C02F9/00 , C02F2101/36
摘要： An effective process combines the adsorption of toxic organic pollutants of waste water on active coal, the desorption of the pollutants in boiling water and the oxidative decomposition of the desorbed pollutants in a dropping bed reactor.

3. 发明申请

WO1992007392A1 PROCESS AND INSTALLATION FOR THE COMBINED GENERATION OF ELECTRICAL AND MECHANICAL ENERGY 审中-公开
标题翻译：电力和机械能源的组合生成的过程和安装
公开(公告)号：WO1992007392A1
公开(公告)日：1992-04-30
申请号：PCT/DE1991000781
申请日：1991-09-30
申请人： MANNESMANN AG , K.T.I. Group B.V. , ASA B.V. , ANKERSMIT, Jan, Hendrik , HENDRIKS, Rudolf , BLOMEN, Leo, Jozef, Maria, Johannes
发明人： MANNESMANN AG , K.T.I. Group B.V. , ASA B.V.
IPC分类号： H01M08/06
CPC分类号： F02C6/18 , C01B3/34 , C01B2203/0233 , C01B2203/0405 , C01B2203/066 , C01B2203/0811 , C01B2203/0827 , C01B2203/0883 , C01B2203/141 , C01B2203/84 , F01K23/067 , H01M8/0612 , Y02E20/14 , Y02E20/18 , Y02P20/129
摘要： The invention relates to a process for the combined generation of electrical and mechanical energy from the oxidation of fuel, whereby a gas containing hydrogen is generated by the endothermal reaction of hydrocarbon compounds, a part of said gas is burned to provide a combustion gas, a gas containing oxygen is compressed and introduced into the burning stage and the energy from the expansion of the hot combustion gas is generated in at least one gas turbine. In addition, the combustion gas produced is used to heat the endothermal reaction indirectly. According to the invention, at least part of the hydrogen-containing gas produced to generate electrical energy is taken as the anode gas via a fuel cell system and the anode exhaust gas is used to generate the combustion gas.

4. 发明申请

WO1995022588A1 PROCESS FOR REDUCING COKING OF HEAT EXCHANGE SURFACES 审中-公开
标题翻译：一种用于减少热交换表面焦化
公开(公告)号：WO1995022588A1
公开(公告)日：1995-08-24
申请号：PCT/DE1995000281
申请日：1995-02-21
申请人： MANNESMANN AG , K.T.I. Group B.V. , ZIMMERMANN, Gerhard , ZYCHLINSKI, Wolfgang
发明人： MANNESMANN AG , K.T.I. Group B.V.
IPC分类号： C10G09/16
CPC分类号： C10G9/16 , Y10S585/95
摘要： A heat exchange surface in reactors and/or heat exchangers is disclosed for processing installations for hydrocarbons and other organic compounds at high temperatures in the gaseous phase. The metallic surfaces that come into contact with the organic substances are treated with a mixture of a silicon- and sulphur-containing product and of a dry gas stream that is inert to the silicon- and sulphur-containing product, at a temperature from 300 to 1000 DEG C for 0.5 to 12 hours. Also disclosed is a process for producing a catalytically inactivated metallic surface in chemical reactors and/or heat exchangers.
摘要翻译：本发明涉及一种在反应器和/或设备的热交换器的热交换表面，用于在气相中的高温下进行反应的烃和其他有机化合物。根据本发明，是那些与有机物质接触的金属表面与硅和含硫产物和干的混合物中，相对于所述硅和在300〜1000℃的温度下经过一段0.5至惰性气体产物流含硫处理12小时。本发明还涉及用于生产在化学反应器中和/或热交换器的催化失活的金属表面的方法。

5. 发明申请

WO1996031442A1 ARRANGEMENT AND PROCESS FOR OXIDIZING AN AQUEOUS MEDIUM 审中-公开
标题翻译： SYSTEM AND METHOD FOR氧化水介质中
公开(公告)号：WO1996031442A1
公开(公告)日：1996-10-10
申请号：PCT/DE1996000592
申请日：1996-03-27
申请人： MANNESMANN AG , K.T.I. Group B.V. , LEVEC, Janez
发明人： MANNESMANN AG , K.T.I. Group B.V.
IPC分类号： C02F11/08
CPC分类号： C02F11/08 , B01J10/002 , B01J19/006 , B01J19/18 , B01J19/1881 , B01J19/2435 , B01J2219/00777 , B01J2219/185 , Y10S210/908
摘要： The invention concerns an arrangement for oxidizing an aqueous medium containing organic and/or oxidizable inorganic substances at high temperature and high pressure. In a reactor the aqueous medium is exposed to oxygen in order to reduce the chemical oxygen requirement of the aqueous medium to a predetermined desired level. The arrangement comprises: a tubular reactor (1); at least one inlet for the introduction of the aqueous medium (2) and an oxygenous gas or an oxygen-releasing solution (3); means (4, 10, 11, 12) for dispersing bubbles of the gaseous oxygen in the aqueous medium; and at least one outlet for removing the treated aqueous medium (5) from the tubular reactor (1). The individual sections (I, II, III) are arranged one behind the other such that the degree of back-mixing of a downstream section (II, III) is in each case at most as great as the respective degree of back-mixing in the sections (II or III) upstream of the section (I or II), and at least in the section (II or III) which is the furthest downstream the degree of back-mixing is less than in the section (I) which is furthest upstream.
摘要翻译：本发明涉及一种系统，用于包含含有在升高的温度和升高的压力下，其中所述含水介质在反应器中的氧气加入到含水介质的化学需氧量到预定的期望电平暴露的有机和/或可氧化的无机物氧化水介质中减少与管式反应器（1），具有至少一个入口，用于引入水性介质（2）和一种含氧气体或氧释放溶液（3）中，用装置（4，10，11，12）用于分散从管式反应器中的水性介质的气态氧，并为经处理的含水介质（5）的取出至少一个出口的气泡的（1）。各个部分（I，II，III），其连接在另一个后面这样一种方式，即返混的下游段的程度（II，III）在每种情况下至多为作为各自的程度大的返混在相对（本条我或II）的上游部分（II或III）和至少在最下游部分（II或III），返混的程度小于在（最远的上游段I）。

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