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1. 发明授权

US5910464A Catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂
公开(公告)号：US5910464A
公开(公告)日：1999-06-08
申请号：US3928
申请日：1998-01-07
申请人： Luigi Resconi , Maurizio Galimberti , Fabrizio Piemontesi , Floriano Guglielmi , Enrico Albizzati
发明人： Luigi Resconi , Maurizio Galimberti , Fabrizio Piemontesi , Floriano Guglielmi , Enrico Albizzati
IPC分类号： C08F4/64 , C08F4/6592 , C08F10/02 , C08F110/02 , C08F110/06 , C08F210/02 , C08F210/16 , C08F210/18 , C08F4/42
CPC分类号： C08F10/02 , C08F110/02 , C08F110/06 , C08F210/02 , C08F210/16 , C08F210/18 , C08F4/65925 , C08F4/65927 , Y10S526/943
摘要： A catalyst for the polymerization of olefins comprises the product obtained by contacting:(A) a titanium, zirconium or hafnium mono- or bis-cyclopentadienyl compound, this latter optionally containing a bridging group which links the two cyclopentadienyl compounds;(B) an alkyl aluminium wherein at least one alkyl is different from a straight alkyl; and(C) water.The molar ratio aluminium/water is higher than 1:1 and lower than 100:1.
摘要翻译：用于烯烃聚合的催化剂包括通过使（A）钛，锆或铪单 - 或双 - 环戊二烯基化合物接触获得的产物，后者任选地含有连接两个环戊二烯基化合物的桥连基团; （B）烷基铝，其中至少一个烷基不同于直链烷基; 和（C）水。铝/水的摩尔比高于1：1且低于100：1。

2. 发明授权

US5585448A Process for the preparation of ethylene polymers and products obtained therefrom 失效
标题翻译：制备乙烯聚合物的方法及由其获得的产品
公开(公告)号：US5585448A
公开(公告)日：1996-12-17
申请号：US304379
申请日：1994-09-12
申请人： Luigi Resconi , Fabrizio Piemontesi , Maurizio Galimberti
发明人： Luigi Resconi , Fabrizio Piemontesi , Maurizio Galimberti
IPC分类号： C08F10/02 , C07F7/08 , C07F17/00 , C08F4/60 , C08F4/602 , C08F4/622 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/643
CPC分类号： C08F210/16 , C08F110/02 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： Homo- and copolymers of ethylene endowed with very high molecular weights and narrow molecular weight distributions are obtainable by carrying out the polymerization reaction in the presence of a metallocene-based catalyst wherein the metallocene is stereorigid and it is in its meso isomeric form.
摘要翻译：具有非常高分子量和窄分子量分布的乙烯的均聚物和共聚物可以通过在金属茂基催化剂存在下进行聚合反应，其中金属茂是立体刚性的并且是其内消旋异构形式。

3. 发明授权

US5886123A Elastomeric copolymers of ethylene with at least one alpha-olefin 失效
标题翻译：乙烯与至少一种α-烯烃的弹性共聚物
公开(公告)号：US5886123A
公开(公告)日：1999-03-23
申请号：US720537
申请日：1996-09-30
申请人： Luigi Resconi , Fabrizio Piemontesi , Maurizio Galimberti
发明人： Luigi Resconi , Fabrizio Piemontesi , Maurizio Galimberti
IPC分类号： C08F10/02 , C07F7/08 , C07F17/00 , C08F4/60 , C08F4/602 , C08F4/622 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F210/16
CPC分类号： C08F210/16 , C08F110/02 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： Homo- and copolymers of ethylene endowed with very high molecular weights and narrow molecular weight distributions are obtainable by carrying out the polymerization reaction in the presence of a metallocene-based catalyst wherein the metallocene is stereorigid and it is in its meso isomeric form.
摘要翻译：具有非常高分子量和窄分子量分布的乙烯的均聚物和共聚物可以通过在金属茂基催化剂存在下进行聚合反应，其中金属茂是立体刚性的并且是其内消旋异构形式。

4. 发明授权

US06403737B1 Elastomeric copolymers of ethylene with &agr;-olefins and process for their preparation 失效
标题翻译：乙烯与α-烯烃的弹性共聚物及其制备方法
公开(公告)号：US06403737B1
公开(公告)日：2002-06-11
申请号：US09694160
申请日：2000-10-24
申请人： Maurizio Galimberti , Luigi Resconi , Enrico Albizzati
发明人： Maurizio Galimberti , Luigi Resconi , Enrico Albizzati
IPC分类号： C08F442
CPC分类号： C08F210/16 , Y10S526/943 , C08F2/14 , C08F210/18 , C08F2500/03 , C08F2500/08 , C08F2500/17 , C08F2500/20 , C08F2500/21 , C08F210/08
摘要： A process for the preparation of amorphous copolymers of ethylene with &agr;-olefins and optionally minor amounts of polyenes are disclosed, which have the following characteristics: (A) the % by mole content of &agr;-olefin in the copolymer (%&agr;) and the ratio between the molar amount of &agr;-olefin diads and the molar content of &agr;-olefin in the copolymer (&agr;&agr;/&agr;) satisfy the following relationship: (%&agr;)−250 (&agr;&agr;/&agr;)≧10 (B) less than 2% of the CH2 groups in the polymeric chain are in sequences (CH2)n, wherein n is an even number. These copolymers are obtained by operating in the presence of particular metallocene-based catalysts having two fluorenyl groups joined together through a bridging group.
摘要翻译：公开了一种制备乙烯与α-烯烃和任选少量多烯的无定形共聚物的方法，其具有以下特征：（A）共聚物中α-烯烃的摩尔％摩尔％（％）和 α-烯烃二单元摩尔量与共聚物中α-烯烃的摩尔含量之比（αalpha/α）满足以下关系：（B）聚合物链中少于2％的CH 2基团为顺序（ CH2）n，其中n是偶数。这些共聚物通过在具有通过桥连基团连接在一起的两个芴基的特定茂金属基催化剂存在下操作而获得。

5. 发明授权

US6160071A Elastomeric copolymers of ethylene with .alpha.-olefins and process for their preparation 失效
标题翻译：乙烯与α-烯烃的弹性共聚物及其制备方法
公开(公告)号：US6160071A
公开(公告)日：2000-12-12
申请号：US876864
申请日：1997-06-16
申请人： Maurizio Galimberti , Luigi Resconi , Enrico Albizzati
发明人： Maurizio Galimberti , Luigi Resconi , Enrico Albizzati
IPC分类号： C08F4/642 , C08F4/42 , C08F4/60 , C08F10/00 , C08F210/16 , C08F210/18 , C08J5/00 , C08F10/04
CPC分类号： C08F210/16 , Y10S526/943 , C08F2/14 , C08F210/18 , C08F2500/03 , C08F2500/08 , C08F2500/17 , C08F2500/20 , C08F2500/21 , C08F210/08
摘要： Amorphous copolymers of ethylene with .alpha.-olefins and optionally minor amounts of polyenes are disclosed, having the following characteristics:(A) the % by mole content of .alpha.-olefin in the copolymer (%.alpha.) and the ratio between the molar amount of .alpha.-olefin diads and the molar content of .alpha.-olefin in the copolymer (.alpha..alpha./.alpha.) satisfy the following relationship:(%.alpha.)-250(.alpha..alpha./.alpha.).gtoreq.10(B) less than 2% of the CH.sub.2 groups in the polymeric chain are in sequences (CH.sub.2).sub.n, wherein n is an even number.These copolymers are obtainable by operating in the presence of particular metallocene-based catalysts having two fluorenyl groups joined together through a bridging group.
摘要翻译：公开了乙烯与α-烯烃和任选的少量多烯的无定形共聚物，具有以下特征：（A）共聚物中α-烯烃的摩尔％摩尔比（％α）和α的摩尔量之比 α-烯烃二烷基和α-烯烃在共聚物中的摩尔含量（αα/α）满足以下关系：（％α）-250（αα/α）> / = 10（B）小于聚合物链中的CH 2基团是（CH 2）n序列，其中n是偶数。这些共聚物可通过在具有通过桥连基团连接在一起的两个芴基的特定茂金属基催化剂存在下操作而获得。

6. 发明授权

US06448351B1 Elastomeric copolymers of ethylene with propylene and process for their preparation 失效
标题翻译：乙烯与丙烯的弹性共聚物及其制备方法
公开(公告)号：US06448351B1
公开(公告)日：2002-09-10
申请号：US09707645
申请日：2000-11-07
申请人： Maurizio Galimberti , Luigi Resconi , Enrico Albizzati
发明人： Maurizio Galimberti , Luigi Resconi , Enrico Albizzati
IPC分类号： C08F442
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65927 , Y10S526/943 , C08F210/06 , C08F2500/17 , C08F2500/21 , C08F2500/20
摘要： Amorphous copolymers of ethylene with propylene, and optionally with minor amounts of polyenes, have the following characteristics: (A) the % content by mole of propylene in the copolymer (%P) and the triads ratio EPE/(EPE+PPE+PPP) satisfy the following relationship: 0.01%P+EPE/(E?E+PPE+PPP)≧1 (B) less than 2% of the CH2 groups in the chain are in sequences (CH2)n, wherein n is an even number. These copolymers are obtainable by operating in the presence of particular metallocene catalysts having two fluorenyl groups joined together through a bridging group.
摘要翻译：乙烯与丙烯和任选少量多烯的无定形共聚物具有以下特征：（A）共聚物中的丙烯含量％（％P）和三元组比EPE /（EPE + PPE + PPP）满足以下关系：（B）链中少于2％的CH 2基团为（CH 2）n序列，其中n为偶数。这些共聚物可通过在具有两个芴基团体通过桥接组合在一起。

7. 发明授权

US5849653A Catalysts and processes for the polymerization of olefins 失效
标题翻译：催化剂和烯烃聚合方法
公开(公告)号：US5849653A
公开(公告)日：1998-12-15
申请号：US503948
申请日：1995-07-19
申请人： Tiziano Dall'Occo , Maurizio Galimberti , Luigi Resconi , Enrico Albizzati , Gianni Pennini
发明人： Tiziano Dall'Occo , Maurizio Galimberti , Luigi Resconi , Enrico Albizzati , Gianni Pennini
IPC分类号： C08F4/642 , C08F4/64 , C08F4/648 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/02 , C08F110/06 , C08F210/16
CPC分类号： C08F10/00 , C08F10/02 , C08F10/06 , C08F110/02 , C08F110/06 , C08F210/16 , C08F4/65912 , C08F4/65922 , Y10S526/943
摘要： Catalysts for the polymerization of olefins are disclosed, which comprise the reaction product of: (A) a bridged and/or substituted cyclopentadienyl compound of titanium, zirconium or hafnium; (B) an organometallic aluminum compound of the formula (II): Al(CH.sub.2 --CR.sup.4 R.sup.5 R.sup.6).sub.w R.sup.7.sub.y H.sub.z(II) wherein in the (CH.sub.2 --CR.sup.4 R.sup.5 R.sup.6) groups, which are the same or different, R.sup.4 is an alkyl, alkenyl or arylalkyl group having from 1 to 10 carbon atoms, R.sup.5 is an alkyl, alkenyl, aryl, arylalkyl or alkylaryl group having from 3 to 50 carbon atoms which is different from a straight alkyl or alkenyl group and, optionally, R.sup.4 and R.sup.5 fused together can form a ring having from 4 to 6 carbon atoms, R.sup.6 is hydrogen or an alkyl, alkenyl or arylalkyl group having from 1 to 10 carbon atoms, the R.sup.7 substituents, same or different, are alkyl, alkenyl, aryl, arylalkyl or alkylaryl radicals containing from 1 to 10 carbon atoms and, optionally, can contain Si or Ge atoms, w is 1, 2 or 3, z is 0 or 1, y=3-w-z; and (C) water. The molar ratio aluminum/water is comprised between 1:1 and 100:1. These catalysts show an improved activity with respect to known catalysts wherein an aluminum compound different from those of the above formula is used.
摘要翻译：公开了用于烯烃聚合的催化剂，其包含以下反应产物：（A）钛，锆或铪的桥连和/或取代的环戊二烯基化合物; （B）式（II）的有机金属铝化合物：Al（CH2-CR4R5R6）wR7yHz（Ⅱ）其中在相同或不同的（CH2-CR4R5R6）基团中，R4是烷基，烯基或芳基烷基具有1至10个碳原子，R 5是具有3至50个碳原子的烷基，烯基，芳基，芳基烷基或烷基芳基，其不同于直链烷基或烯基，并且任选地，R 4和R 5稠合在一起可以形成具有4至6个碳原子的环，R 6是氢或具有1至10个碳原子的烷基，链烯基或芳基烷基，相同或不同的R 7取代基是含1个碳原子的烷基，烯基，芳基，芳烷基或烷芳基至10个碳原子，并且任选地可以含有Si或Ge原子，w是1,2或3，z是0或1，y = 3-wz; 和（C）水。铝/水的摩尔比为1:1至100:1。这些催化剂相对于已知的催化剂显示出改善的活性，其中使用与上式不同的铝化合物。

8. 发明授权

US06221992B1 Elastomeric copolymers of ethylene with alpha-olefins and process for their preparation 失效
标题翻译：乙烯与α-烯烃的弹性共聚物及其制备方法
公开(公告)号：US06221992B1
公开(公告)日：2001-04-24
申请号：US08876865
申请日：1997-06-16
申请人： Maurizio Galimberti , Luigi Resconi , Enrico Albizzati
发明人： Maurizio Galimberti , Luigi Resconi , Enrico Albizzati
IPC分类号： C08F21006
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65927 , Y10S526/943 , C08F210/06 , C08F2500/17 , C08F2500/21 , C08F2500/20
摘要： Amorphous copolymers of ethylene with propylene, and optionally with minor amounts of polyenes, have the following characteristics: (A) the % content by mole of propylene in the copolymer (%P) and the triads ratio EPE/(EPE+PPE+PPP) satisfy the following relationship: 0.01%P+EPE/(EPE+PPE+PPP)≧1 (B) less than 2% of the CH2 groups in the chain are in sequences (CH2)n, wherein n is an even number. These copolymers are obtainable by operating in the presence of particular metallocene catalysts having two fluorenyl groups joined together through a bridging group.
摘要翻译：乙烯与丙烯和任选少量多烯的无定形共聚物具有以下特征：（A）共聚物中的丙烯含量％（％P）和三元组比EPE /（EPE + PPE + PPP）满足以下关系：0.01％P + EPE /（EPE + PPE + PPP）> = 1（B）链中CH2基团的2％以序列（CH2）n表示，其中n为偶数。这些共聚物可通过在具有通过桥连基团连接在一起的两个芴基的特定金属茂催化剂存在下操作而获得。

9. 发明授权

US6136932A Catalysts and processes for the polymerization of olefins 失效
标题翻译：催化剂和烯烃聚合方法
公开(公告)号：US6136932A
公开(公告)日：2000-10-24
申请号：US176188
申请日：1998-10-21
申请人： Tiziano Dall'occo , Maurizio Galimberti , Luigi Resconi , Enrico Albizzati , Gianni Pennini
发明人： Tiziano Dall'occo , Maurizio Galimberti , Luigi Resconi , Enrico Albizzati , Gianni Pennini
IPC分类号： C08F4/642 , C08F4/64 , C08F4/648 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/02 , C08F110/06 , C08F210/16 , C08F4/602
CPC分类号： C08F10/00 , C08F10/02 , C08F10/06 , C08F110/02 , C08F110/06 , C08F210/16 , C08F4/65912 , C08F4/65922 , Y10S526/943
摘要： Catalysts for the polymerization of olefins which comprise the reaction product of (a) a bridged and/or substituted cyclopentadienyl compound of titanium, zirconium, or hafnium; (b) an organometallic aluminum compound of formula Al(CH.sub.2 --CR.sup.4 R.sup.5 R.sup.6).sub.w R.sup.7.sub.y H.sub.z, wherein in the (CH.sub.2 --CR.sup.4 R.sup.5 R.sup.6) groups, which are the same or different, R.sup.4 is an alkyl, alkenyl or arylalkyl group having from 1 to 10 carbon atoms, R.sup.5 is an alkyl, alkenyl, aryl, arylalkyl or alkylaryl group having from 3 to 50 carbon atoms and, optionally, R.sup.4 and R.sup.5 can be fused together to form a ring having from 4-6 carbon atoms, R.sup.6 is hydrogen or an alkyl alkenyl or arylalkyl group having from 1 to 10 carbon atoms, the R.sup.7 substituents, the same or different, are alkyl, alkenyl, aryl, arylalkyl or alkylaryl radicals having from 1 to 10 carbon atoms and, optionally, can contain Si or Ge atoms, w is 1, 2 or 3, z is 0 or 1, and y=3-w-z; and (c) water. The molar ratio of aluminum to water is from 1:1 to 100:1. The catalysts show an improved activity with respect to known catalysts wherein an aluminum compound different from those of the invention are used.
摘要翻译：用于烯烃聚合的催化剂，其包含（a）钛，锆或铪的桥连和/或取代的环戊二烯基化合物的反应产物; （b）式A1（CH2-CR4R5R6）wR7yHz的有机金属铝化合物，其中在相同或不同的（CH2-CR4R5R6）基团中，R4是具有1至10个碳原子的烷基，烯基或芳基烷基 R 5是具有3至50个碳原子的烷基，烯基，芳基，芳基烷基或烷基芳基，并且任选地，R 4和R 5可以一起稠合形成具有4-6个碳原子的环，R 6是氢或烷基具有1-10个碳原子的链烯基或芳基烷基，相同或不同的R 7取代基是具有1-10个碳原子的烷基，烯基，芳基，芳基烷基或烷基芳基，并且任选地可以含有Si或Ge原子， w为1,2或3，z为0或1，y = 3-wz; 和（c）水。铝与水的摩尔比为1:1至100:1。相对于已知的催化剂，催化剂显示出改善的活性，其中使用不同于本发明的铝化合物。

10. 发明授权

US5565533A Process for preparing an ethylenic copolymer 失效
标题翻译：烯属共聚物的制备方法
公开(公告)号：US5565533A
公开(公告)日：1996-10-15
申请号：US471634
申请日：1995-06-06
申请人： Maurizio Galimberti , Luigi Resconi , Enrico Albizzati
发明人： Maurizio Galimberti , Luigi Resconi , Enrico Albizzati
IPC分类号： C08F4/642 , C08F2/04 , C08F2/18 , C08F4/659 , C08F4/6592 , C08F6/06 , C08F6/10 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/00 , C08F210/02 , C08F210/08 , C08F210/16 , C08F210/18
CPC分类号： C08F210/16 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/02 , C08F210/18 , C08F4/65912 , C08F4/65922 , Y10S526/943
摘要： A process for the preparation of an ethylene/1-butene or ethylene/1-butene/diene elastomer by slurry polymerization of the monomers in a polymerization medium consisting mainly of an excess of the 1-butene maintained in liquid form, performed in the presence of a catalyst based on a metallocene compound of Ti, Zr or Hf. This process is exempt from occurrence of reactor fouling and enables the recovery of the polymer without the use of steam as a stripping agent.
摘要翻译：通过在主要由过量的保持液态形式的1-丁烯组成的聚合介质中的单体的淤浆聚合制备乙烯/ 1-丁烯或乙烯/ 1-丁烯/二烯弹性体的方法在存在下进行的基于Ti，Zr或Hf的茂金属化合物的催化剂。该方法免于反应器结垢的发生，并且能够在不使用蒸汽作为汽提剂的情况下回收聚合物。

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