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1. 发明授权

US5731261A Process for the preparation of mixed porous silica-alumina oxides in a spherical form 失效
标题翻译：用于制备球形混合多孔二氧化硅 - 氧化铝氧化物的方法
公开(公告)号：US5731261A
公开(公告)日：1998-03-24
申请号：US642897
申请日：1996-05-06
申请人： Luigi Balducci , Raffaele Ungarelli , Paolo Chiurlo
发明人： Luigi Balducci , Raffaele Ungarelli , Paolo Chiurlo
IPC分类号： C01B13/32 , C01F7/02 , B01J32/00 , C01B33/00 , C04B35/185
CPC分类号： C01B13/328 , C01F7/02 , C01P2004/03 , C01P2004/32 , C01P2004/61 , C01P2004/84 , C01P2006/12 , C01P2006/14 , C01P2006/16
摘要： The present invention relates to a process for the preparation of mixed porous oxides with a spherical morphology and the oxides themselves thus obtained. This process consists in emulsifying, in an acid environment, a mixed sol with a dispersing medium, gelifying the microemulsion thus formed by contact with an alkaline solution and subjecting the gel obtained to thermal aging in the presence of the emulsifying liquid and gelation base of the sol or in a water medium, under controlled conditions of pH and temperature. The above mixed oxides can be widely applied as carriers for catalysts or as precursors of ceramic materials.
摘要翻译：本发明涉及一种制备具有球形形态的混合多孔氧化物和由此获得的氧化物本身的方法。该方法包括在酸性环境下，将具有分散介质的混合溶胶乳化，将由此形成的微乳液与碱溶液接触，使所得到的凝胶在乳化液和凝胶化基质的存在下进行热老化溶胶或在水介质中，在pH和温度的控制条件下。上述混合氧化物可广泛用作催化剂载体或作为陶瓷材料的前体。

2. 发明授权

US06288004B1 Activation method of titanium silicalite 有权
标题翻译：钛硅沸石的活化方法
公开(公告)号：US06288004B1
公开(公告)日：2001-09-11
申请号：US09305281
申请日：1999-05-05
申请人： Luigi Balducci , Raffaele Ungarelli , Daniele Bianchi , Maria Angela Mantegazza , Roberto Bagatin
发明人： Luigi Balducci , Raffaele Ungarelli , Daniele Bianchi , Maria Angela Mantegazza , Roberto Bagatin
IPC分类号： B01J2989
CPC分类号： C07C249/04 , B01J29/89 , C07C37/60 , C07D301/12 , Y02P20/52 , Y02P20/582 , C07C39/04 , C07C39/08
摘要： A method is described for improving the catalytic performances of titanium silicalite having formula (I) by the activation of the catalyst (I) in an aqueous medium with hydrogen peroxide, in the presence of precursors of fluoride ions or anionic species containing fluorine. The activated catalyst (I) is particularly useful in oxidation processes with hydrogen peroxide of organic substrates and, in particular, in hydroxylation reactions of aromatic compounds, amoximation reactions of carbonyl compounds, epoxidation reactions of olefinic compounds and oxidation reactions of nitrogenated compounds.
摘要翻译：描述了一种通过在具有氟离子或含氟阴离子物质的前体的存在下，通过在具有过氧化氢的水性介质中活化催化剂（I）来改善式（I）的钛硅沸石的催化性能的方法。活化的催化剂（I）特别适用于有机底物的过氧化氢的氧化过程，特别是芳族化合物的羟基化反应，羰基化合物的肟化反应，烯烃化合物的环氧化反应和含氮化合物的氧化反应。

3. 发明授权

US5965476A Silica/zeolite composite materials in spherical form and process for their preparation 失效
标题翻译：二氧化硅/沸石复合材料球形及其制备方法
公开(公告)号：US5965476A
公开(公告)日：1999-10-12
申请号：US801593
申请日：1997-02-14
申请人： Luigi Balducci , Raffaele Ungarelli , Cristina Tonini
发明人： Luigi Balducci , Raffaele Ungarelli , Cristina Tonini
IPC分类号： B01J29/04 , B01J29/06 , B01J29/70 , B01J29/80 , B01J29/89 , C01B37/00 , C01B39/02 , C07C37/60 , B01J32/00
CPC分类号： C07C37/60 , B01J29/80 , B01J29/89 , B01J29/7007 , Y02P20/52
摘要： The present invention relates to silica/zeolite composite materials in spherical form and the process for their preparation which occurs by the dispersion of submicronic particles of titanium silicalite, beta zeolite, or mixtures of beta zeolite with titanium silicalite, in a silica sol synthesized by acid hydrolysis of silicon alkoxides; the hybrid sol thus obtained, subjected to emulsification and gelation techniques in organic mediums, produces these materials in a spherical form with an average diameter of between 20 and 150 .mu.m and containing up to 70% by weight of titanium silicalite, beta zeolite or mixtures of titanium silicalite/beta zeolite.The materials of the invention, having a high mechanical resistance and characterized by a surface area of between 300 and 800 m.sup.2 /g, are applied as catalysts; in particular, those consisting of titanium silicalite or mixtures of titanium silicalite/beta zeolite are advantageously used in oxidation reactions of organic compounds with hydrogen peroxide.
摘要翻译：本发明涉及球形二氧化硅/沸石复合材料及其制备方法，其通过在硅酸钠溶液中分解而制得的二氧化硅/沸石复合材料，其通过将钛硅沸石，β沸石的亚微米级颗粒或β-沸石与钛硅沸石的混合物分散在由硅酸硅烷醇盐的水解; 由此获得的在有机介质中进行乳化和凝胶化技术的混合溶胶将这些材料制成球形，平均直径为20至150μm，并含有至多70重量％的钛硅沸石，β沸石或混合物的钛硅质岩/β沸石。本发明的具有高机械性能并且表征面积在300-800m2 / g之间的材料被用作催化剂; 特别是由钛硅沸石或钛硅沸石/β沸石的混合物组成的有机化合物与过氧化氢的氧化反应有利地使用。

4. 发明授权

US6133487A Process for the oxidation of aromatic compounds to hydroxyaromatic compounds 有权
标题翻译：芳香族化合物氧化成羟基芳族化合物的方法
公开(公告)号：US6133487A
公开(公告)日：2000-10-17
申请号：US176316
申请日：1998-10-22
申请人： Raffaele Ungarelli , Luigi Balducci , Daniele Bianchi
发明人： Raffaele Ungarelli , Luigi Balducci , Daniele Bianchi
IPC分类号： B01J29/03 , C07B61/00 , C07C37/60 , C07C39/02 , C07C39/04 , C07C39/08 , C07C39/12
CPC分类号： C07C37/60 , C07C41/26 , Y02P20/52
摘要： An improved process is described for the synthesis of hydroxylated aromatic compounds by means of the oxidation of an aromatic substrate with hydrogen, peroxide in an organic solvent, in the presence of synthetic zeolites, wherein the improvement consists in the fact that the organic solvent is selected from compounds having general formula (I) ##STR1## wherein: R.sub.1, R.sub.2, R.sub.3 and R.sub.4, the same or different, represent a hydrogen atom or an alkyl group with from 1 to 4 carbon atoms or from compounds having general formula (II) ##STR2## wherein R and R', the same or different, represent an alkyl radical with from 1 to 4 carbon atoms.
摘要翻译：描述了通过在合成沸石存在下，通过在有机溶剂中用氢气，过氧化物氧化芳族底物来合成羟化芳族化合物的改进方法，其中改进在于选择有机溶剂来自具有通式（I）的化合物，其中：R 1，R 2，R 3和R 4相同或不同，表示氢原子或具有1至4个碳原子的烷基或具有通式（II）的化合物，其中R和 R'相同或不同，表示具有1至4个碳原子的烷基。

5. 发明授权

US6103209A Process for preparing porous spherical silica xerogels 失效
标题翻译：制备多孔球形二氧化硅干凝胶的方法
公开(公告)号：US6103209A
公开(公告)日：2000-08-15
申请号：US628978
申请日：1996-04-08
申请人： Luigi Balducci , Raffaele Ungarelli
发明人： Luigi Balducci , Raffaele Ungarelli
IPC分类号： C04B38/00 , C01B33/16 , C01B33/12
CPC分类号： C01B33/163
摘要： Process for preparing porous spherical silica particles substantially consisting in emulsifying an acidic silica sol in a dispersing media, gelifying the microdrops of the sol in the emulsified state and submitting the resulting gel to thermal treatment in the presence of the emulsifier liquid and of sol gelation base.
摘要翻译：制备多孔球状二氧化硅颗粒的方法，其基本上包括在分散介质中乳化酸性二氧化硅溶胶，使乳化状态下的溶胶的微滴凝胶化，并将所得凝胶在乳化剂液体和溶胶凝胶基质存在下进行热处理。

6. 发明授权

US5780004A Process for the preparation of mixed silica-zirconia sols and mixed oxides obtained in spherical form 失效
标题翻译：用于制备球形混合氧化硅 - 氧化锆溶胶和混合氧化物的方法
公开(公告)号：US5780004A
公开(公告)日：1998-07-14
申请号：US672038
申请日：1996-06-26
申请人： Luigi Balducci , Raffaele Ungarelli , Fabio Garbassi
发明人： Luigi Balducci , Raffaele Ungarelli , Fabio Garbassi
IPC分类号： B01J21/08 , B01J35/10 , B01J37/03 , C01B33/141 , C01B33/148 , C01G25/02
CPC分类号： B01J37/033 , B01J21/08 , B01J37/036 , B01J35/10
摘要： A process for the preparation of mixed silica-zirconia sols and mixed oxides in spherical form, comprising mixing a silicon alkoxide with a solution of an inorganic zirconium salt in a low molecular weight polyol and subjecting the intermediate thus formed to acid hydrolysis in a water medium.
摘要翻译：一种用于制备球形混合二氧化硅 - 氧化锆溶胶和混合氧化物的方法，包括将硅醇盐与无机锆盐溶液在低分子量多元醇中混合，并使由此形成的中间体在水介质中酸解。

7. 发明授权

US5043483A Process for the alkylation of phenols 失效
标题翻译：苯酚烷基化方法
公开(公告)号：US5043483A
公开(公告)日：1991-08-27
申请号：US276634
申请日：1988-11-28
申请人： Loris Sogli , Raffaele Ungarelli , L. Lawrence Chapoy
发明人： Loris Sogli , Raffaele Ungarelli , L. Lawrence Chapoy
IPC分类号： B01J27/02 , B01J27/16 , C07B61/00 , C07C27/00 , C07C37/14 , C07C39/12 , C07C67/00
CPC分类号： C07C37/14
摘要： Process for the alkylation of phenols comprising reacting a phenol with a vinyl-aromatic hydrocarbon in the presence of an acidic catalyst and of a solvent.

8. 发明授权

US4734533A Process for the preparation of (2,2)-paracyclophane and derivatives thereof 失效
标题翻译：（2,2） - 对环磷烷及其衍生物的制备方法
公开(公告)号：US4734533A
公开(公告)日：1988-03-29
申请号：US940772
申请日：1986-12-12
申请人： Raffaele Ungarelli , Maurizio A. Beretta , Alessandro Malacrida , Loris Sogli
发明人： Raffaele Ungarelli , Maurizio A. Beretta , Alessandro Malacrida , Loris Sogli
IPC分类号： B01J31/00 , B01J31/02 , C07B61/00 , C07C1/00 , C07C1/32 , C07C13/70 , C07C17/00 , C07C17/26 , C07C17/263 , C07C25/18 , C07C67/00 , C07C13/28
CPC分类号： C07C1/323 , C07C17/263 , C07C2103/92
摘要： Process for the preparation of (2,2)-paracyclophane or derivatives thereof by the Hofmann elimination of p.-methylbenzyltrimethylammonium hydroxide or derivatives thereof, in an aqueous solution of an alkali metal hydroxide, wherein said elimination is carried out in the presence of a ketone of the formula:Ch.sub.3 --CO--CH.sub.2 --R (I)wherein R is hydrogen, a halogen, or an alkyl-carboxylic group.
摘要翻译：在碱金属氢氧化物的水溶液中通过霍夫曼消除对甲基苄基三甲基氢氧化铵或其衍生物来制备（2,2） - 对环烷烃或其衍生物的方法，其中所述消除在酮，其具有式：Ch 3 -CO-CH 2 -R（I）其中R是氢，卤素或烷基 - 羧基。

9. 发明授权

US4675462A Process for the preparation of (2,2)-paracyclophane 失效
标题翻译：（2,2） - 对环磷烷的制备方法
公开(公告)号：US4675462A
公开(公告)日：1987-06-23
申请号：US924274
申请日：1986-10-29
申请人： Raffaele Ungarelli , Maurizio A. Beretta , Loris Sogli
发明人： Raffaele Ungarelli , Maurizio A. Beretta , Loris Sogli
IPC分类号： B01J23/70 , B01J27/00 , B01J27/055 , B01J27/122 , B01J27/128 , B01J31/00 , B01J31/04 , C07B61/00 , C07C1/00 , C07C1/32 , C07C13/70 , C07C67/00 , C07C2/72
CPC分类号： C07C1/323 , C07C2103/92
摘要： A process for the preparation of (2,2)-paracyclophane by conversion of p.methylbenzyltrimethylammonium halide to the corresponding hydroxide and by Hofmann elimination from p.methylbenzyltrimethylammonium hydroxide, wherein both reactions are carried out in the same aqueous solution of an alkaline hydroxide and in the presence of a copper or iron compound.
摘要翻译：通过将对甲基苄基三甲基铵卤化物转化为相应的氢氧化物并通过从甲基苄基三甲基氢氧化铵中去除霍夫曼消除来制备（2,2） - 对环烷酸的方法，其中两个反应在碱性氢氧化物的相同水溶液中进行，在铜或铁化合物的存在下。

10. 发明授权

US4956484A Process for producing a silane or siloxane compound containing a cycloalkyl ring 失效
标题翻译：制备含有环烷基环的硅烷或硅氧烷化合物的方法
公开(公告)号：US4956484A
公开(公告)日：1990-09-11
申请号：US163948
申请日：1988-03-03
申请人： Francesco Gementi , Loris Sogli , Raffaele Ungarelli
发明人： Francesco Gementi , Loris Sogli , Raffaele Ungarelli
IPC分类号： B01J25/02 , C07B61/00 , C07F7/08 , C07F7/18
CPC分类号： C07F7/0801 , C07F7/1892
摘要： A process for producing a silane or siloxane compound containing at least one cycloalkyl ring by hydrogenation of a corresponding derivative containing at least one aromatic ring in the presence of a Raney nickel catalyst modified with chromium.

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