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    • 1. 发明授权
    • Imaging element comprising solubilized collagen gelatin and hardener
    • 成像元件包括溶解的胶原明胶和硬化剂
    • US06573037B1
    • 2003-06-03
    • US10158656
    • 2002-05-30
    • Lloyd A. LoboHwei-Ling YauJames S. HonanPaul T. Hahm
    • Lloyd A. LoboHwei-Ling YauJames S. HonanPaul T. Hahm
    • G03C1047
    • G03C1/047G03C1/005G03C1/30
    • An imaging element is described comprising one or more hydrophilic colloid layers which include gelatin as a film forming binder which has been chemically crosslinked with a gelatin hardener, wherein at least 20% of the gelatin of at least one of the one or more hydrophilic colloid layers comprises a gelatin prepared from hydrolysis of ossein using sodium or potassium hydroxide, and the gelatin is chemical crosslinked with a gelatin hardener at a level from 70 to 120 effective &mgr;mole hardener per gram of gelatin. Improvements are obtained in the wet mechanical strength of an imaging element comprising gelatin as a binder, without needing to increase the amount of chemical crosslinker with respect to the gelatin. The invention further enables the use of relatively low molecular weight gelatins without compromising the wet mechanical strength of imaging elements and without needing to increase the amount of crosslinker relative to the amount of gelatin. The invention also enables the selective improvement in the wet mechanical properties of layers with a high ratio of non-binder materials to binder without substantially increasing the amount of chemical crosslinker.
    • 描述了一种成像元件,其包含一个或多个亲水胶体层,其包括明胶作为成膜粘合剂,其已经用明胶固化剂化学交联,其中至少20%的一种或多种亲水胶体层中的至少一种的明胶 包括使用氢氧化钠或氢氧化钾从骨胶原水解制备的明胶,明胶与明胶固化剂进行化学交联,每克明胶的水平为70至120有效的莫美尔硬化剂。 在包含明胶作为粘合剂的成像元件的湿机械强度方面获得了改进,而不需要相对于明胶增加化学交联剂的量。 本发明还使得能够使用相对低分子量的明胶,而不会影响成像元件的湿机械强度,并且不需要相对于明胶量增加交联剂的量。 本发明还能够以非粘合剂材料与粘合剂的高比率选择性地提高层的湿机械性能,而基本上不增加化学交联剂的量。
    • 5. 发明授权
    • Coating fluid for imaging element comprising solubilized collagen gelatin colloidal dispersion
    • 用于成像元件的涂布液包括溶解的胶原明胶胶体分散体
    • US06706467B2
    • 2004-03-16
    • US10158651
    • 2002-05-30
    • Andrew M. HoweRichard W. ConnellyJames S. HonanLloyd A. Lobo
    • Andrew M. HoweRichard W. ConnellyJames S. HonanLloyd A. Lobo
    • G03C1407
    • G03C1/047C08K3/36C08K7/16C08L33/00C08L89/06C08L2205/18C09D189/06C09H3/00C09H5/00C08L2666/02
    • An aqueous coating fluid is described comprising gelatin at a concentration of at least 1 wt % and a colloidal particle dispersed material phase at a volume fraction of at least 0.01, wherein at least 20% of the gelatin comprises a gelatin prepared from hydrolysis of ossein using sodium or potassium hydroxide. The present invention enables increasing the concentrations of a coating fluid containing gelatin and dispersed sub-micron colloidal materials, reducing the size of the sub-micron colloidal materials in such a coating fluid, and/or including higher molecular weight gelatin in such a coating fluid without detrimentally increasing the viscosity of such fluids. The invention further enables reducing the viscosity of an aqueous coating fluid containing gelatin and dispersed insoluble colloidal material, without needing to reduce the concentration of gelatin or colloidal materials, increase the size of the sub-micron colloidal materials, and/or reduce the molecular weight of the gelatin. Each such advantage may be achieved either individually, or in combinations to varying extents, without the need to fundamentally change the composition of the materials in the coating fluid.
    • 描述了一种包含浓度至少为1重量%的明胶和体积分数至少为0.01的胶体颗粒分散材料相的含水涂布液,其中至少20%的明胶包含由骨胶原水解制备的明胶,其使用 氢氧化钠或氢氧化钾。 本发明能够增加含有明胶和分散的亚微米胶体材料的涂布液的浓度,减小这种涂布液中的亚微米胶体材料的尺寸,和/或在这种涂布液中包括较高分子量的明胶 而不会不利地增加这种流体的粘度。 本发明还可以降低包含明胶和分散的不溶性胶体材料的水性涂布液的粘度,而不需要降低明胶或胶体材料的浓度,增加亚微米胶体材料的尺寸和/或降低分子量 的明胶。 每个这样的优点可以单独地实现,也可以以不同程度的组合来实现,而不需要从根本上改变涂层流体中材料的组成。
    • 8. 发明授权
    • Method of forming polymer particles
    • 形成聚合物颗粒的方法
    • US07273570B2
    • 2007-09-25
    • US11178091
    • 2005-07-08
    • Stewart W. BlairLloyd A. LoboTomas G. McHugh
    • Stewart W. BlairLloyd A. LoboTomas G. McHugh
    • B29B9/10
    • B01F5/22B01J19/1887B01J2219/00094B01J2219/00096C08J3/16
    • The present invention is a method of manufacturing polymer particles. The method includes providing an oil in water emulsion, wherein the oil phase comprises a volatile solvent and at least one water insoluble polymer. The volatile solvent has a solubility of not more than 10% in water and the water insoluble polymer has a weight average molecular weight of at least 2000. The water insoluble polymer is soluble in the volatile solvent. The emulsion is supplied to a rotating surface of a rotating surface reactor. The temperature of the rotating surface is maintained at the boiling point of said solvent or greater. The rotating surface of the reactor spins at a speed sufficient to cause the emulsion to spread over the rotating surface as a continuously flowing thin film wherein a vapor phase containing the volatile solvent is removed. The water insoluble polymer particles are then collected as a slurry of polymer particles and water.
    • 本发明是制造聚合物颗粒的方法。 该方法包括提供水包油乳液,其中油相包含挥发性溶剂和至少一种水不溶性聚合物。 挥发性溶剂在水中的溶解度不超过10%,水不溶性聚合物的重均分子量至少为2000.水不溶性聚合物可溶于挥发性溶剂。 将乳液供给到旋转表面反应器的旋转表面。 旋转表面的温度保持在所述溶剂的沸点以上。 反应器的旋转表面以足以使乳液作为连续流动的薄膜扩散在旋转表面上的速度旋转,其中除去含有挥发性溶剂的气相。 然后将水不溶性聚合物颗粒作为聚合物颗粒和水的浆料收集。
    • 9. 发明授权
    • Process for the preparation of concentrated dye-water compositions
    • 浓缩染料 - 水组合物的制备方法
    • US06750002B2
    • 2004-06-15
    • US10058395
    • 2002-01-28
    • James E. NovakJeffrey S. BaugherDirk J. HasbergLloyd A. Lobo
    • James E. NovakJeffrey S. BaugherDirk J. HasbergLloyd A. Lobo
    • G03C1005
    • G03C1/005C09B67/0073C09B67/0084G03C1/12
    • A process for preparing a concentrated photographic spectral sensitizing dye-water composition which comprises adding an anionic sensitizing dye to an aqueous medium in the substantial absence of organic solvent, and agitating the combined dye and aqueous medium, wherein the anionic dye forms a liquid-crystalline dye phase in the aqueous medium and the agitation is performed in the presence of a nonionic surfactant having an HLB of less than 12 and an aqueous solubility at 25° C. of greater than 10 ppm, which nonionic surfactant is in the aqueous medium at a level of from 10 to 1000 ppm. In a specific embodiment of the invention, where the viscosity (at 0.1 s−1 shear rate) of the dye-water composition in the absence of the nonionic surfactant would be greater than 100 cp and especially where such viscosity would be greater than 500 cp, the surfactant is preferably present at a level sufficient to substantially reduce air entrainment during agitation of the dye-water composition.
    • 一种制备浓缩照相光谱增感染料 - 水组合物的方法,其包括在基本上不存在有机溶剂的情况下向阴离子增感染料添加阴离子敏化染料,并搅拌组合的染料和水性介质,其中阴离子染料形成液晶 在水性介质中的染料相和在HLB小于12的非离子表面活性剂和25℃下的水溶性在大于10ppm的情况下进行搅拌,该非离子表面活性剂在水性介质中为 水平为10〜1000ppm。 在本发明的一个具体实施方案中,其中在不存在非离子表面活性剂的情况下,染料 - 水组合物的粘度(0.1s -1剪切速率)将大于100cp,特别是在这种粘度将大于 500cp,表面活性剂优选以足以在搅拌染料 - 水组合物期间基本上减少空气夹带的水平存在。
    • 10. 发明授权
    • Coating fluid for imaging element comprising solubilized collagen gelatin and hardener
    • 用于成像元件的涂布液包括溶解的胶原明胶和硬化剂
    • US06589326B1
    • 2003-07-08
    • US10158681
    • 2002-05-30
    • Andrew M. HoweLloyd A. LoboGary L. Santee
    • Andrew M. HoweLloyd A. LoboGary L. Santee
    • G03C1047
    • G03C1/047C07K14/78C09D189/06G03C1/30
    • An aqueous coating fluid is described comprising gelatin at a concentration of at least 1 wt % and gelatin hardener at a level from 1-200 effective &mgr;mole hardener per gram of coating fluid, wherein at least 20% of the gelatin comprises a gelatin prepared from hydrolysis of ossein using sodium or potassium hydroxide. Relative improvements are obtained in reducing the rate of chemical gelation of a coating fluid containing gelatin and a hardener, without the need for chemically modifying functional groups of the gelatin. The invention further enables an increase in coating fluid concentration, increase in the fluid viscosity, reduction in the ratio of added anionic polymer to gelatin, and/or increase in the pH of a coating fluid containing gelatin and a hardener, without detrimentally increasing the rate of chemical gelation of the coating fluid. The invention also enables the inclusion of relatively more reactive hardeners in a coating fluid containing gelatin, and/or the inclusion of relatively higher molecular weight gelatin in a coating fluid containing hardener, without detrimentally increasing the rate of chemical gelation of the coating fluid. Each such advantage may be achieved either individually, or in combinations to varying extents.
    • 描述了一种水性涂布液,其包含浓度为至少1重量%的明胶和每克包衣液的1-200个有效莫莫尔固化剂的明胶硬化剂,其中至少20%的明胶包括由水解制备的明胶 使用氢氧化钠或氢氧化钾。 在降低含有明胶和硬化剂的涂布液的化学凝胶化速率的同时,可以获得相对的改进,而不需要化学改性明胶的官能团。 本发明还能够增加涂布液的浓度,增加流体粘度,降低加入的阴离子聚合物与明胶的比例和/或增加含有明胶和硬化剂的涂布液的pH,而不会不利地增加速率 的涂料液化学凝胶化。 本发明还能够在含有明胶的涂布液中包含相对更多的反应性硬化剂,和/或在含有硬化剂的涂布液中包含相对较高分子量的明胶,而不会不利地提高涂布液的化学凝胶化速率。 每个这样的优点可以单独实现,也可以以不同程度的组合来实现。