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1. 发明申请

US20140166159A1 LA(FE,SI)13-BASED MAGNETIC REFRIGERATION MATERIAL PREPARED FROM INDUSTRIAL-PURE MISCHMETAL AS THE RAW MATERIAL AND PREPARATION AND USE THEREOF 审中-公开
标题翻译： LA（FE，SI）13种基于制造工艺的磁性制冷材料作为原料，其制备和使用
公开(公告)号：US20140166159A1
公开(公告)日：2014-06-19
申请号：US14232084
申请日：2012-07-13
申请人： Ling Chen , Fengxia Hu , Jing Wang , Lifu Bao , Yingying Zhao , Baogen Shen , Jirong Sun , Huayang Gong
发明人： Ling Chen , Fengxia Hu , Jing Wang , Lifu Bao , Yingying Zhao , Baogen Shen , Jirong Sun , Huayang Gong
IPC分类号： H01F1/01
摘要： The invention provides a La(Fe,Si)13-based magnetic refrigeration material prepared from industrial-pure mischmetal as the raw material, wherein the industrial-pure mischmetal is impurity-containing and naturally proportionated La—Ce—Pr—Nd mischmetal or LaCe alloy which, as the intermediate product during rare earth extraction, is extracted from light rare earth ore. The invention further provides the preparation method and use of the material, wherein the preparation method comprises the steps of smelting and annealing industrial-pure mischmetal as the raw material to prepare the La(Fe,Si)13-based magnetic refrigeration material. The presence of impurities in the industrial-pure mischmetal has no impact on the formation of the 1:13 phase, the presence of the first-order phase-transition property and metamagnetic behavior, and thus maintains the giant magnetocaloric effect of the magnetic refrigeration material. The preparation of La(Fe,Si)13-based magnetic refrigeration material from industrial-pure mischmetal reduces the dependency on high-purity elementary rare earth raw material; lowers the cost for manufacturing the material; and thus plays an important role in development of the magnetic refrigeration application of materials.
摘要翻译：本发明提供了一种以工业纯小米混合物为原料制备的La（Fe，Si）13系磁致冷材料，其中工业纯稀土金属含杂质，天然成比例的La-Ce-Pr-Nd混合稀土或LaCe 作为稀土提取中的中间产物，从轻稀土矿中提取出来的合金。本发明还提供了该材料的制备方法和用途，其中制备方法包括冶炼和退火工业纯混合稀土作为原料制备La（Fe，Si）13基磁性制冷材料的步骤。工业纯混合稀土中杂质的存在对1:13相的形成，一阶相变特性和反磁性行为的存在没有影响，从而保持了磁致冷材料的巨磁热效应。从工业纯小麦粉中制备La（Fe，Si）13磁性制冷材料减少了对高纯度稀土原料的依赖; 降低制造材料的成本; 从而在材料的磁致冷应用开发中起着重要的作用。

2. 发明申请

US20150047371A1 BONDED La(Fe,Si)13-BASED MAGNETOCALORIC MATERIAL AND PREPARATION AND USE THEREOF 审中-公开
标题翻译：粘结La（Fe，Si）13基磁性材料及其制备及其应用
公开(公告)号：US20150047371A1
公开(公告)日：2015-02-19
申请号：US14359685
申请日：2012-05-17
申请人： Fengxia Hu , Ling Chen , Lifu Bao , Jing Wang , Baogen Shen , Jirong Sun , Huayang Gong
发明人： Fengxia Hu , Ling Chen , Lifu Bao , Jing Wang , Baogen Shen , Jirong Sun , Huayang Gong
IPC分类号： H01F1/01 , F25B21/00
CPC分类号： H01F1/015 , F25B21/00 , F25B2321/002
摘要： Provided is a high-strength, bonded La(Fe, Si)13-based magnetocaloric material, as well as a preparation method and use thereof. The magnetocaloric material comprises magnetocaloric alloy particles and an adhesive agent, wherein the particle size of the magnetocaloric alloy particles is less than or equal to 800 μm and are bonded into a massive material by the adhesive agent; the magnetocaloric alloy particle has a NaZn13-type structure and is represented by a chemical formula of La1-xRx(Fe1-p-qCopMnq)13-ySiyAα, wherein R is one or more selected from elements cerium (Ce), praseodymium (Pr) and neodymium (Nd), A is one or more selected from elements C, H and B, x is in the range of 0≦x≦0.5, y is in the range of 0.8≦y≦2, p is in the range of 0≦p≦0.2, q is in the range of 0≦q≦0.2, α is in the range of 0≦α≦3.0. Using a bonding and thermosetting method, and by means of adjusting the forming pressure, thermosetting temperature, and thermosetting atmosphere, etc., a high-strength, bonded La(Fe, Si)13-based magnetocaloric material can be obtained, which overcomes the frangibility, the intrinsic property, of the magnetocaloric material. At the same time, the magnetic entropy change remains substantially the same, as compared with that before the bonding. The magnetic hysteresis loss declines as the forming pressure increases. And the effective refrigerating capacity, after the maximum loss being deducted, remains unchanged or increases.
摘要翻译：提供高强度的La（Fe，Si）13基磁热材料及其制备方法和用途。磁热材料包括磁热合金颗粒和粘合剂，其中磁热合金颗粒的颗粒尺寸小于或等于800μm，并通过粘合剂粘合成块状材料; 磁热合金颗粒具有NaZn13型结构，并且由La1-xRx（Fe1-p-qCopMnq）13-ySiyAα的化学式表示，其中R是选自元素铈（Ce），镨（Pr）和钕（Nd），A是选自元素C，H和B中的一种或多种，x在0和nlE的范围内; x和nlE; 0.5，y在0.8和nlE的范围内; y和nlE; 2，p在 0＆nlE; p＆nlE; 0.2，q在0和nlE的范围内; q＆nlE; 0.2，α在0＆lt; nEE;α＆nlE; 3.0的范围内。使用粘结和热固化方法，通过调整成型压力，热固化温度和热固性气氛等，可以获得高强度的La（Fe，Si）13基磁热材料，克服了易磁性，内在性质，磁热材料。同时，与接合前相比，磁熵变保持基本相同。随着成形压力的增加，磁滞损耗下降。扣除最大损失后的有效制冷量保持不变或增加。

3. 发明授权

US10096411B2 Bonded La(Fe,Si)13-based magnetocaloric material and preparation and use thereof 有权
公开(公告)号：US10096411B2
公开(公告)日：2018-10-09
申请号：US14359685
申请日：2012-05-17
申请人： Fengxia Hu , Ling Chen , Lifu Bao , Jing Wang , Baogen Shen , Jirong Sun , Huayang Gong
发明人： Fengxia Hu , Ling Chen , Lifu Bao , Jing Wang , Baogen Shen , Jirong Sun , Huayang Gong
IPC分类号： B22F1/00 , B22F3/02 , H01F1/01 , F25B21/00
摘要： Provided is a high-strength, bonded La(Fe, Si)13-based magnetocaloric material, as well as a preparation method and use thereof. The magnetocaloric material comprises magnetocaloric alloy particles and an adhesive agent, wherein the particle size of the magnetocaloric alloy particles is less than or equal to 800 μm and are bonded into a massive material by the adhesive agent; the magnetocaloric alloy particle has a NaZn13-type structure and is represented by a chemical formula of La1-xRx(Fe1-p-qCopMnq)13-ySiyAα, wherein R is one or more selected from elements cerium (Ce), praseodymium (Pr) and neodymium (Nd), A is one or more selected from elements C, H and B, x is in the range of 0≤x≤0.5, y is in the range of 0.8≤y≤2, p is in the range of 0≤p≤0.2, q is in the range of 0≤q≤0.2, α is in the range of 0≤α≤3.0. Using a bonding and thermosetting method, and by means of adjusting the forming pressure, thermosetting temperature, and thermosetting atmosphere, etc., a high-strength, bonded La(Fe, Si)13-based magnetocaloric material can be obtained, which overcomes the frangibility, the intrinsic property, of the magnetocaloric material. At the same time, the magnetic entropy change remains substantially the same, as compared with that before the bonding. The magnetic hysteresis loss declines as the forming pressure increases. And the effective refrigerating capacity, after the maximum loss being deducted, remains unchanged or increases.

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